• Korean Chemical Engineering Research
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• v.46 no.3
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• pp.451-464
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• 2008

Three-phase inverse fluidized bed has been widely adopted with its increasing demand in the fields of bioreactor, fermentation process, wastewater treatment process, absorption and adsorption processes, where the fluidized or suspended particles are small or lower density comparing with that of continuous liquid phase, since the particles are frequently substrate, contacting medium or catalyst carrier. However, there has been little attention on the three-phase inverse fluidized beds even on the hydrodynamics. Needless to say, the information on the hydrodynamics and transport phenomena such as heat and mass transfer in the inverse fluidized beds has been essential for the operation, design and scale-up of various reactors and processes which are employing the three-phase inverse beds. In the present article, thus, the information on the three-phase inverse fluidized beds has been summarized and reorganized to suggest a pre-requisite knowledge for the field work in a sense of engineering point of view. The article is composed of three parts; hydrodynamics, heat and mass transfer characteristics of three-phase inverse fluidized beds. Effects of operating variables on the phase holdup, bubble properties and particle fluctuating frequency and dispersion were discussed in the section of hydrodynamics; effects of operating variables on the heat transfer coefficient and on the heat transfer model were discussed in the section of heat transfer characteristics ; and in the section of mass transfer characteristics, effects of operating variables on the liquid axial dispersion and volumetric liquid phase mass transfer coefficient were examined. In each section, correlations to predict the hydrodynamic characteristics such as minimum fluidization velocity, phase holdup, bubble properties and particle fluctuating frequency and dispersion and heat and mass transfer coefficients were suggested. And finally suggestions have been made for the future study for the application of three-phase inverse fluidized bed in several available fields to meet the increasing demands of this system.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.11
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• pp.634-640
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• 2017

Toxicity and fate assessment is necessary in the evaluation of the environmental, health and safety risks of engineered nanomaaterials (ENMs). Therefore, in order to ensure the reproducibility, reliability and relevance of ENMs toxicity results, stable and monomodal dispersion protocols in toxicity test media are needed. Zinc oxide nanoparticles (nZnO) are widely used in various products such as cosmetic products, paper, paints etc. In this study, nZnO dispersions in ecotoxicity test media were produced by following a series of steps of modified National Institute of Standards and Technology (NIST) Special publication 1200-5. In addition, natural organic matter (humic acid (HA)) was used as a stabilizing agent to disperse nZnO in the test media. The hydrodynamic diameters (HDD) of the nZnO in dispersion ranged between 150 and 200 nm according to the dynamic light scattering (DLS) measurement. Based on these dispersions in ecotoxicity test using ecological species (Oryzias latipes, Daphnia magna, Pseudokirchneriella subcapitata and Chironomusus riparius), dispersion protocol was found to have a considerable potential in ecotoxicity test of ENMs.

• Journal of the Korean Society of Groundwater Environment
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• v.1 no.2
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• pp.105-112
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• 1994

To investigate the migration behavior of contaminants in rocks. adsorption and diffusion experiments for Sr as a sorbing contaminant and for Cr-EDTA as a non-sorbing contaminant were carried out on granitic rocks. The Sr adsorption on separated minerals and crushed rocks tends to slightly increase with increasing pH. It also greatly decreases with the increase of ionic strength in NaCl solution. Among separated minerals, biotite and sericite have adsorbed much more amount of Sr than other rock-forming minerals, such as quartz, plagioclase, and potassic feldspar, because the specific surfaces and cation exchange capacities of phyllosilicates are generally much greater than those of the other rock-forming minerals. The intrinsic diffusion coefficients of Cr-EBTA for granitic rocks differ little from those of Sr. This indicates that they are independent of water-rock interactions. Experimental data show that the intrinsic diffusion coefficients are positively correlated with the porosities of the rocks. They are close to the theoretically predicted values, especially in pre-steady state diffusion region, with the increase of rock sample thickness.

• Journal of Soil and Groundwater Environment
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• v.13 no.5
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• pp.33-46
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• 2008

A series of three-dimensional numerical simulations using a generalized multidimensional hydrodynamic dispersion numerical model is performed to simulate effectively and to evaluate quantitatively impacts of fault existence on densitydependent groundwater flow and salt transport in coastal aquifer systems. A series of steady-state numerical simulations with calibration is performed first for an actual coastal aquifer system which contains a major fault. A series of steadystate numerical simulations is then performed for a corresponding coastal aquifer system which does not have such a major fault. Finally, the results of both numerical simulations are compared with each other and analyzed. The results of the numerical simulations show that the major fault produces hydrogeologically significant heterogeneity and true anisotropy in the actual coastal aquifer system, and density-dependent groundwater flow, salt transport, and seawater intrusion patterns in the coastal aquifer systems are intensively and extensively dependent upon the existence or absence of such a major fault. Especially, the major fault may act as a pathway for groundwater flow and salt transport along the direction parallel to its plane, while it may also behave as a barrier against groundwater flow and salt transport along the direction perpendicular to its plane.

• Journal of Soil and Groundwater Environment
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• v.22 no.3
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• pp.27-41
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• 2017

This study dealt with the characteristics and the interrelations of hydrogeological parameters such as hydraulic conductivity, dispersivity and effective porosity of unconsolidated sediments for providing the basic data necessary for the planning of the management and preservation of groundwater quality in the Nakdong River Delta of Busan City, Korea. Groundwater quality in this area has been deteriorated due to seawater intrusion, agricultural fertilizer and pesticide, industrial wastewater, and contaminated river water. The physical properties (grain size distribution, sediment type, sorting) and aquifer parameters (hydraulic conductivity, effective porosity, longitudinal dispersivity) were determined from grain size analysis, laboratory permeability test and column tracer test. Among 36 samples, there were 18 Sand (S), 7 Gravelly Sand (gS), 5 Silty Sand (zS), 5 Muddy Sand (mS), and 1 Sandy Silt (sZ). Hydraulic conductivity was determined through a falling head test, and ranged from $9.2{\times}10^{-5}$ to $2.9{\times}10^{-2}cm/sec$ (0.08 to 25.6 m/day). From breakthrough curves, dispersivity was calculated to be 0.35~3.92 cm. Also, effective porosity and average linear velocity were obtained through the column tracer test, and their values were 0.04~0.46 and 1.06E-04~6.49E-02 cm/sec, respectively. Statistical methods were used to understand the interrelations among aquifer parameters of hydraulic conductivity, effective porosity and dispersivity. The relation between dispersivity and hydraulic conductivity or effective porosity considered the sample length, because dispersivity was affected by experimental scale. The relations between dispersivity and hydraulic conductivity or effective porosity were all in inverse proportion for all long and short samples. The reason was because dispersivity was in inverse proportion to the groundwater velocity in case of steady hydrodynamic dispersion coefficient, and groundwater velocity was in proportion to the hydraulic conductivity or effective porosity. This study also elucidated that longitudinal dispersivity was dependent on the scale of column tracer test, and all hydrogeological parameters were low to high values due to the sand quantity of sediments. It is expected that the hydrogeological parameter data of sediments will be very useful for the planning of groundwater management and preservation in the Nakdong River Delta of Busan City, Korea.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.6
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• pp.742-750
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• 2020

The flow noise generated by hull appendages is directly related to the performance of the sonar in terms of self-noise and induces a secondary noise source through interaction with the propeller and rudder. Thus, the noise in the near field should be analyzed accurately. However, the acoustic analogy method is an indirect method that is not used to simulate the propagation of an acoustic signal directly; therefore, diffraction, reflection, and scattering characteristics cannot be considered, and near-field analysis is limited. In this study, the propagation process of flow noise in water was directly simulated by using the lattice Boltzmann method. The lattice Boltzmann method could be used to analyze flow noise by simulating the collision and streaming processes of molecules, and it is suitable for noise analysis because of its compressibility, low dissipation rate, and low dispersion rate characteristics. The flow noise source was derived using Reynolds-averaged Navier-Stokes equations for the hull appendages, and the propagation process of the flow noise was directly simulated using the lattice Boltzmann method by applying the developed flow-acoustic boundary conditions. The derived results were compared with Ffowcs Williams-Hawkings results and hydrodynamic pressure results based on the receiver location to verify the usefulness of the lattice Boltzmann method within the near-field range in comparison with other techniques.

• Journal of Soil and Groundwater Environment
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• v.14 no.6
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• pp.53-64
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• 2009

Wetlands can remove organic contaminants, metals and radionuclides from wastewater through various biogeochemical mechanisms. In this study, a mathematical model was developed for simulating the fate and transport of chemical species in marsh wetland sediments. The proposed model is a one-dimensional vertical saturated model which is incorporated advection, hydrodynamic dispersion, biodegradation, oxidative/reductive chemical reactions and the effects from external environments such as the growth of plants and the fluctuation of water level due to periodic tides. The tidal effects causes periodic changes of porewater flow in the sediments and the evapotranspiration and oxygen supply by plant roots affect the porewater flow and redox condition on in the rhizosphere along with seasonal variation. A series of numerical experiments under hypothetical conditions were performed for simulating the temporal and spatial distribution of chemical species of interests using the proposed model. The fate and transport of a trace metal pollutant, chromium, in marsh sediments were also simulated. Results of numerical simulations show that plant roots and tides significantly affect the chemical profiles of different electron acceptors, their reduced species and trace metals in marsh sediments.

• Journal of Soil and Groundwater Environment
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• v.14 no.6
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• pp.1-18
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• 2009

A series of three-dimensional numerical simulations using a generalized multidimensional hydrodynamic dispersion numerical model is performed to simulate effectively and to evaluate quantitatively impacts of urbanization on density-dependent groundwater flow and salt transport in a coastal aquifer system, Suyeong-Gu, Busan, Korea. A series of steady-state numerical simulations of groundwater flow and salt transport before urbanization with material properties of geologic formations, which are established by numerical modeling calibrations considering all the urbanization factors, is performed first without considering all the urbanization factors. A series of transient-state numerical simulations of groundwater flow and salt transport after urbanization is then performed considering the urbanization factors individually and all together. Finally, the results of both numerical simulations are compared with each other and analyzed. The results of the numerical simulations show that density-dependent groundwater flow, salt transport, and seawater intrusion in the coastal aquifer system are intensively and extensively impacted by the urbanization factors. Especially, these urbanization factors result in the changes of the total groundwater volume and salt mass in the coastal aquifer system. However, such impacts of each urbanization factor are not spatially uniform but locally different.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.707-711
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• 2007

낙동강과 밀양강의 합류지점에 위치한 김해시 딴섬 지역의 지표면하 $25{\sim}35\;m$ 구간에 형성되어 있는 고투수성 충적층 내 염소이온의 수리분산특성을 연구하기 위한 수렴흐름 추적자시험(convergent flow tracer test)이 수행되었다. 추적자로는 IW-1공과 IW-2공에서 각각 염소이온 5kg이 순간주입(instantaneous injection) 되었으며, PW공에서 일정한 양수율(2,500 m3 /day)로 채수하면서 염소이온농도를 관측하였다. 염소이온 주입 후 경과시간에 따른 염소이온농도 자료를 이용하여 농도이력곡선과 누적질량회수곡선이 산출되었으며, 관측된 염소이온농도의 정규분포를 검증하기 위한 일반통계분석이 수행되었다. 그리고, 농도이력의 증가/감소 구간에서의 함수를 추정하였으며, 두 시험에서 동일한 시간에 관측된 염소이온농도의 상관성이 분석되었다. 본 현장에서 수행된 추적자시험에 의한 종분산지수의 추정은 CATTI 코드(Sauty and Kinzelbach, 1992)에 의해 해석되었다. 추정된 종분산지수는 IW-1공과 PW공 구간에서는 0.4152 m, IW-2공과 PW공 구간에서는 0.4158 m 로서 매우 유사한 값으로 나타났다. 이는 추적자시험이 수행된 충적층에서의 용질이송이 방사상으로 비교적 균일함을 의미하는 것이다. 본 연구에서 수행된 추적자시험의 규모(2 m)를 Xu and Eckstein(1995)이 제시한 방정식에 대입하여 산정된 종분산지수는 0.0458 m 이었다. 이러한 결과는, 본 연구지역에서 수렴흐름 추적자시험에 의해 추정된 고투수성 충적층의 종분산지수가 일반적인 자연대수층에 비해 9.1배 정도 높다는 것을 의미한다. 이는 시험대수층의 투수성이 매우 높아 염소이온의 용질이송이 매우 빠르게 발생되었기 때문이다. 본 연구에서 추정된 종분산지수를 Gelhar et al.(1992)의 연구 결과와 비교 분석한 결과에서도 시험규모에 비해 매우 높은 수리분산이 발생된 것으로 나타났다. 그리고 염소이온의 확산면적을 추정하기 위해, 수렴흐름 추적자시험에 의한 종분산지수와 시험대수층의 평균선형유속을 이용하여 종분산계수를 구하였다. 현장에서 수행된 양수시험에 의한 평균선형유속 22.44 m/day와 평균 종분산지수 0.4155 m를 적용하여 산정된 종분산계수는 $9.32\;m^2/day$이었다. 따라서, 시험부지 내 충적층에서 일정한 양수율$(2,500\;m^3/day)$로 지하수를 개발할 시에 양수정 주변지역으로 유입되는 염소이온의 확산면적은 1일 $9.32\;m^2$ 정도일 것으로 나타났다.

• Journal of the Korean Society for Marine Environment & Energy
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• v.2 no.2
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• pp.20-30
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• 1999

To improve water quality particularly for sea bathers along the Fylde coastal zone near Blackpool, North West England, waste water from a sewage outfall is studied using a mathematical model. The explicit second order accurate central scheme and the third order accurate QUICKEST scheme are used to represent the diffusion terms and the advection terms of the advective-diffusion equation, respectively. Hydrodynamic model is run for a coarse and fine grid, of 1km and 200m, respectively, obtaining good agreement with measured data. Water quality model is then used to predict faecal coliform levels in the region for four different scenarios, including discharges from: - (i) Fleetwood outfall, (ii)River Ribble for summer condition, (iii)River Ribble for winter condition, and (iv)combined sewer overflows for the Blackpool and Fleetwood communities. Main findings from the simulations are:- (i) Fleetwood outfall has a negligible impact on the beaches with respect to pathogen levels; (ii) Discharge from River Ribble for both summer and winter conditions is predicted in the range of coliform levels 10 -500 counts/100ml along the beach at Lytham St. Annes; and (iii) The CSO effluent discharges are predicted not to advect out into offshore by stronger tidal currents.