• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.128-131
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• 2004

This paper is to investigate the mock up test results of mass concrete for transfer girder using setting time difference with super retarding agent(SRA) to reduce hydration heat. According to test results, the temperature history of plain concrete without placing lift had a steep rising curvature, and plain concrete had a big temperature difference between surface and middle section of mass concrete, which may result in occurrence of temperature crack. However, considering placing method B, because setting time of middle section concrete was retarded with an increase in SRA contents, higher hydration heat temperature was observed at surface section concrete compared with that at middle section concrete at early age, which can lower the possibility of hydration heat crack. In case of placing method C, although peak temperature of hydration heat was much lower, at early age, high crack occurrence possibility of the hydration heat attributable to the big temperature difference between middle section and bottom section of concrete was expected at bottom section concrete. Therefore, the structure above the ground like transfer girder is not applicable to consider the placing method C.

• Computers and Concrete
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• 제8권6호
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• pp.647-675
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• 2011

Our ability to predict hydration behavior is becoming increasingly relevant to the concrete community as modelers begin to link material performance to the dynamics of material properties and chemistry. At early ages, the properties of concrete are changing rapidly due to chemical transformations that affect mechanical, thermal and transport responses of the composite. At later ages, the resulting, nano-, micro-, meso- and macroscopic structure generated by hydration will control the life-cycle performance of the material in the field. Ultimately, creep, shrinkage, chemical and physical durability, and all manner of mechanical response are linked to hydration. As a way to enable the modeling community to better understand hydration, a review of hydration models is presented offering insights into their mathematical origins and relationships one-to-the-other. The quest for a universal model begins in the 1920's and continues to the present, and is marked by a number of critical milestones. Unfortunately, the origins and physical interpretation of many of the most commonly used models have been lost in their overuse and the trail of citations that vaguely lead to the original manuscripts. To help restore some organization, models were sorted into four categories based primarily on their mathematical and theoretical basis: (1) mass continuity-based, (2) nucleation-based, (3) particle ensembles, and (4) complex multi-physical and simulation environments. This review provides a concise catalogue of models and in most cases enough detail to derive their mathematical form. Furthermore, classes of models are unified by linking them to their theoretical origins, thereby making their derivations and physical interpretations more transparent. Models are also used to fit experimental data so that their characteristics and ability to predict hydration calorimetry curves can be compared. A sort of evolutionary tree showing the progression of models is given along with some insights into the nature of future work yet needed to develop the next generation of cement hydration models.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.127-132
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• 1994

This study attemps to investigate the influence of heat of hydration occured during hardening on the strength development of high strength concrete. The concrete design strengths of 500kg/$\textrm{cm}^2$ and 700kg/$\textrm{cm}^2$ were considered to simulated the square columns having $80\times80cm$ and $100\times100cm$, respectively. Both standard curing and field curing specimen were prepared at the specified ages, and the cores were drilled out from the structure. The thermal sensors were installed into the specimen to measure the heat of hydration process occurred during the hardening. This paper tries to uncover the relationship between the temperature history of the concrete and strength development. The correlation of core strength and specimen strength with curing condition is also discussed. Further research is desired to enlight the relationship between strength and heat of hydration of high strength concrete.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.301-304
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• 2003

Nowadays, hydration heat analysis using FEM is common in thermal crack control of concrete structure. Many kinds of general FEM programs for hydration heat analysis are used in practice. But there are some problems in this using. In this study hydration heat analysis of wall according to placement length are performed. In this results we could get two conclusions. First, general structures like wall having general geometry and construction condition have similar behavior. So it is not necessary to analysis thermal crack in every case. Second, the results of 2D analysis is possible to be applied instead of those of 3D analysis because the results of 2D analysis is similar to 3D analysis in long wall having about 15~18m or over length at 3m height.

• 한국세라믹학회지
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• 제43권3호
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• pp.156-161
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• 2006

Impedance spectroscopy was applied to the initial hydration of calcium phosphate bone cements in order to investigate the electrical/dielectric properties. Hydration or equivalently setting was monitored as a function of the amount of water and initial powder characteristics. Higher amounts of water produced more open microstructures, leading to higher conductivity and enhanced dielectric constant. The effects of the initial characteristics in the powder were investigated using bone cement powder prepared with and without granulation. Granulated powder exhibited a significant change in resistance and produced a higher dielectric constant than those of conventional powder. Through a simplified modeling, the effects of thickness in reaction products and pore sizes were estimated by the frequency-dependent impedance measurements. Furthermore, impedance spectroscopy was proven to be a highly reliable tool for evaluating the continuous change in pore structure occurring in calcium phosphate bone cements.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.95-100
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• 2003

The shrinkage of high strength/high performance concrete is very important property for the good working of a structure since it very often generates early age cracking due to thermal and autogenous shrinkage. Autogenous shrinkage occurs as a result of internal moisture depletion due to hydration and temperature-induced effects. The level of autogenous shrinkage occurring due to hydration also depends on temperature history at very early age. It is necessary that effect of temperature on autogenous shrinkage is investigated since the stress generated due to autogenous shrinkage is quantified. In this study, Effect of hydration heat evolution on autogenous shrinkage of high strength concretes with W/C=25-40% was investigated.

• Bulletin of the Korean Chemical Society
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• 제11권2호
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• pp.144-149
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• 1990

Conformational free energy calculations using an empirical potential function (ECEPP/2) and the hydration shell model were carried out on the sulfonylurea herbicides of bensulfuron methyl (Londax) and metsulfuron methyl (Ally). The conformational energy was minimized from starting conformations which included possible combinations of torsion angles in the molecule. The conformational entropy of each conformation was computed using a harmonic approximation. To understand the hydration effect on the conformation of the molecule in aqueous solution, the hydration free energy of each group was calculated and compared each other. It was found that the low-free-energy conformations of two molecules in aqueous solution prefer the overall folded structure, in which an interaction between the carbonyl group of ester in aryl ring and the first amido group of urea bridge plays an important role. From the analysis of total free energy, the hydration and conformational entropy are known to be essential in stabilizing low-free-energy conformations of Londax, whereas the conformational energy is proved to be a major contribution to the total free energy of low-free-energy conformations of Ally.

• 콘크리트학회논문집
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• 제27권2호
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• pp.177-184
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• 2015

시멘트를 대체하여 고로슬래그 미분말을 건설재료로 대량으로 활용하기 위해서는 잠재수경성을 향상시켜 조기강도를 개선시킬 수 있는 적절한 활성화제가 필요하다. 이 연구에서는 경석고와 황산나트륨을 이용하여 하이볼륨 고로슬래그 시멘트의 수화특성에 대한 연구를 수행하였다. 수화특성을 평가하기 위해 고로슬래그 미분말을 전체 바인더의 80%로 고정하였으며, 나머지 20%를 시멘트와 활성화제로 구성하였다. 경석고와 황산나트륨의 치환율(1~7%)에 따른 응결, 압축강도, 미소수화열 및 미세구조 특성을 시멘트만을 사용한 경우와 비교하여 분석하였다. 이 연구에서는 경석고와 황산나트륨을 활성화제로 사용한 경우, 하이볼륨 고로슬래그 미분말의 조기 수화특성을 향상을 위해 필요한 $SO_3$ 함량을 전체 바인더 중량대비 약 3~5% 제안하였다.

• 한국축산식품학회지
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• 제18권1호
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• pp.35-41
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• 1998

The objective of this study was to examine the changes of physical properties by additions of different kinds of stabilizers milk proteins concentration, when stored at 4$^{\circ}C$ or 20$^{\circ}C$ for yoghurt. the results were summarized as follows: 1. Addition of 2% carboxyl methyl cellulose and carrageenan, gelation 0.4%, pectin and starch 0.6%, and carrageenan & pectin 0.8% in the manufacture of yoghurt increased the viscosity, water-holding capacity and protein hydration of yoghurt. 2. Addition of 3% skim milk powder, Ca-caseinate or Na-caseinate 0.6% increased the viscosity, water-holding capacity and protein hydration of yoghurt. 3. Twenty five percent of evaporation of milk promoted to build up the optimal structure of the micelles of yoghurt and improved viscosity, water-holding capacity and protein hydration of yoghurt. 4. Addition of stabilizers to yoghurt showed an increase of viscosity, water-holding capacity and protein hydration when compared with non-addition of stabilizers to yoghurt at 4$^{\circ}C$, 20$^{\circ}C$ storage for 12hrs, 96hrs followed by the decrease of it.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.481-484
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• 2008

콘크리트 구조물의 온도균열은 타설 초기 시멘트의 수화열에 의한 온도상승 및 강하에 따라 생기는 체적변화가 내부 또는 외부적으로 구속을 받아 발생하는 것으로, 댐과 같은 매스콘크리트 구조물일수록 온도균열 발생가능성은 높아진다. 성덕 다목적댐은 경상북도 청송군에 건설 중인 중력식 다목적 댐으로, 분할 타설고 설정 및 수화열계측을 통한 균열유무 조사 등의 목적으로 가물막이댐 시험시공이 이루어졌다. 본 연구는 성덕 다목적댐 가물막이댐의 수화열 해석을 수행하여 분할 타설고에 따른 수화열 비교, 수화열에 의한 온도균열 발생 유무, 현장 계측 결과 값과의 비교 분석을 하고자 한다.열 비교, 수화열에 의한 온도균열 발생 유무, 현장 계측 결과 값과의 비교 분석을 하고자 한다.