• Title/Summary/Keyword: hydration property

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Mechanical Properties of Cement Material for Energy-Foundation (EF) Structures

  • Park, Yong-Boo;Choi, Hang-Seok;Sohn, Jeong-Rak;Sim, Young-Jong;Lee, Chul-Ho
    • Land and Housing Review
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    • v.3 no.1
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    • pp.83-88
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    • 2012
  • In this study, physical characteristics of cement and/or concrete materials that are typically used for energy-foundation (EF) structures have been studied. The thermal conductivity and structural integrity of the cement-based materials were examined, which are commonly encountered in backfilling a vertical ground heat exchangers, cast-in-place concrete piles and concrete lining in tunnel. For this purpose the thermal conductivity and unconfined compression strength of cement-based materials with various curing conditions were experimentally estimated and compared. Hydration heat generated from massive concrete in the cast-in-place concrete energy pile was observed for 4 weeks to estimate its dissipation time in the underground. The hydration heat may mask the in-situ thermal response test (TRT) result performed in the cast-in-place concrete energy pile. It is concluded that at least two weeks are needed to dissipate the hydration heat in this case. In addition, a series of numerical analysis was performed to compare the effect of thermal property of the concrete material on the cast-in-place pile.

Study on Skin Elasticity Property between Face and Forearm according to the Environmental Change of Stratum Corneum (각질층 환경변화에 따른 얼굴과 하박내측 피부의 탄력 특성 비교연구)

  • Chang, Minyoul
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.4
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    • pp.455-463
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    • 2018
  • Skin elasticity has been known to be influenced by the change of dermal components such as collagen, elastic fiber, and glycosaminoglycans. However, it is unclear whether the uppermost epidermis may affect the mechanical characteristics of elasticity. In present study we tried to find the role of stratum corneum when determining the elastic property under skin bioengineering measurement with $Cutometer^{(R)}$. A total of 10 healthy volunteers aged 25-40 years were investigated by the parameters reflecting the skin elasticity from face and volar forearm. Within various ranges of suction pressure, R0 (=Uf), R7 (=Ur/Uf) and R8 (=Ua) were obtained to explore the depth-associated elasticity. In addition, these parameters were re-measured after the skin was fully hydrated. As results, we found that the measurement of depth-associated elasticity was possible as using various suction pressure. And the R7 parameter was significantly lower from face than those from forearm in before hydration (p < 0.05). Also, we found that the hydration of stratum corneum could affect skin elasticity. Especially, the R7 parameter at 300 mbar suction pressure of face skin showed significantly increased values than that of before hydration (p < 0.05). Interestingly, measured data from the face before and after hydration manifested relatively higher variation than from the forearm. These results suggest that it is possible to evaluate the skin elasticity considering the changes of stratum corneum and epidermis by using various suction pressure and skin hydration.

A Study on Influences of Waterproofing Admixtures for Concrete on Self-Healing Properties of Hardened Cement Paste (시멘트페이스트 경화체의 Self-Healing 특성에 미치는 구체방수재의 영향)

  • Kim, Jae-Young;Byun, Seung-Ho;Ma, Sang-Jun
    • Journal of the Korea Concrete Institute
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    • v.20 no.1
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    • pp.109-116
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    • 2008
  • This study was performed to get information of self-healing mechanism in cement system and the influence of waterproofing admixtures for concrete on self-healing property. For testing, cement paste specimens cured for 7, 14 and 28 days were prepared and crushed into plate-shape pieces. Screened specimens with thickness not more than 1mm were covered with wet rags and cured in a plastic container for 7 and 28 days. After stopping hydration process of the specimens by treatment with acetone, the surfaces of specimens have been contacted with wet rags were analyzed by XRD, DSC, SEM and EDX. The analysis results showed that cement paste has self-healing property and this property is mainly affected by water. Self-healing in cement system is more effective and faster at an early stage of hydration as there is enough content of unreacted cement to make an additional hydration in this period. The results of this study also showed that waterproofing admixtures for concrete have a considerable effect on self-healing of cement pastes; i.e., they improved self-healing effect of cement and, especially, the specimen using admixture C has shown a lot of needle-like or fibrous hydration products which are estimated as ettringite. It is supposed that these ettringite products are effective to enhance self-healing in cement system.

A Study on the Compressive Strength Property of Mortar with Fly Ash Using Water Eluted from Recycled Coarse Aggregates (용출수를 사용한 플라이애쉬 혼입 모르타르의 강도특성에 관한 연구)

  • Shin, Sang-Yeop;Jeong, Euy-Chang;Kim, Young-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.31-32
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    • 2013
  • ThThe purpose of this study is to investigate the compressive strength properties of fly ash using water eluted from recycled coarse aggregate. When fly ash come into contact with water, they have not a autonomously chemical reaction. But fly ash is a pozzolan reaction when fly ash come into contact with water and calcium hydroxide(Ca(OH)2) in alkaline environment. For that reason, if water eluted from recycled coarse aggregate use mixture water, fly ash is expected to reaction of pozzolan reaction property in early stage. According to the experimentation result, ICP-MS analysis showed water eluted from recycled coarse aggregate has a high alkali-ash value of pH of 12 and over. And mixing ratio 30% fly ash mortar using water eluted from recycled coarse aggregate showed a similar strength of plain mortar due to the pozzolan reaction. Also, poor strength in initial age, disadvantage of mortar using fly ash, can be improved as hydration in early age is expedited due to calcium hydroxide(Ca(OH)2) and unhydrated cement component eluted from recycled aggregate mortar.

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Finite Element Analysis on Heat of Hydration with Reinforcing Steel Bars (철근의 영향을 고려한 수화열 유한요소해석)

  • Yoon Dong-Yong;Yang Ok-Bin;Min Chang-Sik
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.43-49
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    • 2005
  • In the concrete structures, the magnitude and distribution of the temperature due to the heat of hydration are related to the thermal properties of each component composed of the concrete, the initial temperature, the type of formwork, and the ambient temperature of exposed surfaces. Even though the reinforcing steel bar has completely different thermal properties, it has been excluded. In the thermal analysis on the concrete structures. In this study, finite element analysis was performed on the concrete structures including the reinforcing steel in order to investigate their effect on temperature and stress distribution due to the heat of hydration. As the steel ratio increased, the maximum temperature and the internal-external temperature difference decreased by 32.5% and 10%, respectively. It is clear that the inclusion of reinforcing steel bars on the heat of hydration analysis is indispensable to obtain realistic solutions for the prediction of the maximum temperature and stresses

Recycling of Sludgewater containing Set-retarder (지연제 첨가에 의한 회수수의 재이용)

  • Song, Young-Jin;Daiki, Atarashi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.761-764
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    • 2008
  • Most of ready-mixed concrete plants have the problem of construction waste sludge, which pollutes environment and causes economic loss due to the discard and increasing the cost of concrete. Thus, a recycling of the cement sludge has been strongly desired as one of their solution. This research is to the study on the recycling of the cement sludge, especially the study on the hydration control by the sodium gluconate as a set-retarder. The set-retarder can delay the hydration of the cement included in the sludge water, so that the sludge water can be substituted with some of new cement without the property of the cement. And it invests the effect of the sodium gluconate to the hydration of the cement in suspension. The degree of hydration of cement may be controlled by adding the sodium gliconate. The hydration delay time is observed that depends on the concentration of residual sodium gloconate, not how long the cement has been hydrated before the addition of the sodium gluconate.

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Influence of Nano Silica Dispersant on Hydration Properties of Cementitious Materials (시멘트의 수화특성에 대한 유·무기 복합 나노실리카의 영향)

  • Kang, Hyun-Ju;Song, Myong-Shin;Park, Jong-Hun;Song, Su-Jae
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.510-515
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    • 2011
  • In this study, as a material used to replace silica fumes for high strength concrete, nano-silica compound with organic functional group for dispersion and with inorganic silica group that can cause a pozzolan reaction is synthesized, These nano silica compound is divided into IC, which is nano size $SiO_2$ with irregularly combined hydroxyl group and carboxyl group, and RC, which is nano size $SiO_2$ with regularly combined hydroxyl group and carboxyl group. The effects of these nano silica compound on the hydration of cement are reviewed. As a result, all of synthesized nano-silica compounds have excellent dispersion on the cement flow, we think that dispersion property is the effect of air entraining by synthesized nano-silica compounds. The result of the microstructure observation showed that the particle size of the synthesized nano-silica is smaller than silica fume and spread evenly among the cement particles. In initial The phenomenon of strength decreasing occurred due to delayed hydration reaction by the synthesized nano-silica with carboxyl(-COOH) and hydroxyl(-OH) functional group.

Experimental Study on Watertightness Properties of Concrete Using Fluosilicates Based Composite (규불화염계 복합 조성물을 사용한 콘크리트의 수밀특성에 관한 실험적 연구)

  • Joung, Won-Seoup;Park, Dong-Su;Kwon, Ki-Joo;Kim, Joung-Woo;Kim, Do-Soo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.429-432
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    • 2008
  • Large area members such as foundation concrete of underground structures in power plants have an effect on structural stability and durability of the structure due to danger of crack occurrence and shrinkage crack that occur owing to the difference of temperature by heat of hydration between inside and outside of the members at initial age. And a construction for waterproofness is performed additionally to protect marine structures from osmosis of seawater because the structures adjoin below the surface of sea. So, if a rise of the heat of hydration, crack, and corrosion of bars are controled effectively using a composite such as fluosilicate salt in concrete production process of a initial construction, expenses are cut down and construction hours are reduced by securing durability through improvement of watertightness. The property tests of adiabatic temperature by hydration are carried out at initial age about standard concrete and test concrete using a fluosilicate salt composite to evaluate an effect on improvement of watertightness for concrete structures in this study. And the experiments such as a permeability test of hardened concrete, a water absorption test, a compression strength test and a elongation test are carried out and the results from these are described.

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An Experimental Study on Workability for Practical Use of High-Performance Concrete (고성능 콘크리트의 실용화를 위한 시공특성에 관한 실험적 연구)

  • Yang, Keun-Hyeok;Lee, Young-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.1
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    • pp.139-146
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    • 2003
  • The special requirements of high-performance concrete(HPC) could be enhanced property over others such as compressive strength, durability, and construction practices. In order to satisfy these requirements a series of laboratory trial mixes and following mock-up test of reinforced concrete wall at field were performed in this study. The objective of this study was to quantitatively evaluate the workability, compressive strength, and the increased heat of hydration caused by the increase of the specific weight of cement according to various variables. Six example series designed about a minimum compressive strength of 500kgf/$\textrm{cm}^2$ at 28 days, and an approximately slump and slump flow of 25cm and 60cm respectively were tested. The selection process of the specific weight of water and the percentage of fly-ash transposition determined to be most suitable for the production of HPC is presented in the following paper.

A Study on Field Application of the Mass Concrete using Hydration Temperature-Reducing Binder - Focused on the Laboratory Test - (수화 온도 저감형 결합재를 이용한 매스콘크리트 현장적용에 관한 연구 - 실내시험 중심으로-)

  • Lee, Ji-Hwan;Lee, Jin-Woo;Park, Hee-Gon;Kang, Chang-Gu;Bae, Yeoun-Ki;Lee, Jae-Sam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.259-260
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    • 2010
  • This study is to investigate each mix property and physical properties and reduction properties of heat of hydration as basic experiment of reviewing the applicability of low calorific concrete.

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