• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 춘계 학술논문 발표대회
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• pp.230-231
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• 2017

The addition of a limestone filler(LF) to fill into the voids between cement and aggregate particles can reduce the cementitious paste volume. This paper aim to evaluate the influence of LF contents on the hydration kinetics and compressive strength. Hydration kinetics were evaluate using heat of hydration, ignition loss and thermal analysis. The heat of hydration was measured using Isothermal Calorimetry. The degree of hydration was measured using ignition loss. Hydration product analysis was carried out by Thermal Gravimetric and Differential Thermal Analysis. The results show that the addition of LF reduces not only the initial setting time and heat of hydration peak, also degree of hydration and rate of strength development at early age increase with the addition of LF. It can be concluded the LF fills the pore between cement particles due to formation of carboaluminate, which may accelerate the setting of cement pastes.

• 한국세라믹학회지
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• 제26권5호
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• pp.609-616
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• 1989

For the development of high durable portland cement, it was tested that the some physical properties of ordinary portland cements (OPC) treated with 0.3-1.5wt.% asphalt and 0.5-1.0wt.% carbon black. From the results, the contact angles of water against cements treated with more than 0.6wt.% asphalt were increased over 80 degrees, the initial and the final setting times of cement paste were delayed about 20min. according to the every 0.3wt.% increase of asphalt. The first and the second pick heights of the hydration curve of the cement were considerabely decreased and the induction period of that was increased. And so, the cumulative hydration heat of the cement which was treated with 0.6wt.% asphalt and 0.5wt.% carbon black was lower about 10cal/g than that of ordinary portland cement during 42 hydration times.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.315-316
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• 2009

본 연구에서는 초기재령 수화발열 특성과 자기수축 특성의 상관관계를 검토한 선행연구를 기초로, 수화발열상승속도 저감에 따른 고강도 매스 콘크리트의 자기수축 특성을 검토하고자 하였다. 수화발열 상승속도 저감을 위한 재료로서 잠열재를 사용하였으며, 잠열재 사용에 따른 초기재령 수화열 및 자기 수축 특성과 서로의 상관관계를 검토하였다.

• 한국세라믹학회지
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• 제43권3호
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• pp.156-161
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• 2006

Impedance spectroscopy was applied to the initial hydration of calcium phosphate bone cements in order to investigate the electrical/dielectric properties. Hydration or equivalently setting was monitored as a function of the amount of water and initial powder characteristics. Higher amounts of water produced more open microstructures, leading to higher conductivity and enhanced dielectric constant. The effects of the initial characteristics in the powder were investigated using bone cement powder prepared with and without granulation. Granulated powder exhibited a significant change in resistance and produced a higher dielectric constant than those of conventional powder. Through a simplified modeling, the effects of thickness in reaction products and pore sizes were estimated by the frequency-dependent impedance measurements. Furthermore, impedance spectroscopy was proven to be a highly reliable tool for evaluating the continuous change in pore structure occurring in calcium phosphate bone cements.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.123-127
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• 2005

EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

• 콘크리트학회논문집
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• 제20권5호
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• pp.593-600
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• 2008

본 연구에서는 초기재령 고강도콘크리트의 수화발열 및 자기수축 특성의 상관관계를 분석하기 위해 수화발열 및 자기수축의 초기특성을 대표할 수 있는 계수로서 수화발열상승구간 및 자기수축증가구간의 직선 기울기인 수화발열상승속도 및 자기수축증가속도를 설정하였으며, 이 두 계수는 통계적 수법을 활용하여 일정 범위의 결정계수를 갖는 회귀계수로 산정하였다. 또한 수화발열 특성과 자기수축 특성을 동시에 평가하기 위한 시험 방법으로서 기존의 간이단열온도상승시험을 보완한 시험 방법을 제안하였으며, 본 시험 방법을 통해 실험을 실시하여 실측데이터를 분석한 결과, 고강도콘크리트의 수화발열 및 자기수축에 대한 초기재령 특성을 수치적으로 나타내는 것이 가능하였으며 자기수축을 수화발열 특성을 나타내는 계수의 함수식으로 제시하는 것이 가능하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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• pp.645-648
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• 2008

본 연구에서는 초기재령 고강도 콘크리트의 수화발열 특성 및 자기수축 특성의 직접적인 상관관계를 분석하기 위한 기초연구로서, 우선 초기재령 콘크리트의 수화온도와 자기수축의 발현 특성을 정량적으로 표현할 수 있는 통계적 방법에 대해 고찰하였다. 우선 수화발열 특성 및 자기수축 특성을 표현할 수 있는 정량적인 계수로서 수화온도와 자기수축이 급격하게 증가하는 구간의 기울기인 수화발열상승속도와 자기수축증가속도를 설정하였으며, 이 두 계수는 통계적 수법을 활용하여 일정범위의 결정계수를 갖는 회귀계수로 산정하는 것으로 제안하였다. 또한 설정된 통계적 분석방법의 유효성을 검증하기 위해 실제 측정된 수화온도 및 자기수축 데이터를 분석하였으며, 그 결과 초기재령 고강도 콘크리트의 수화발열 특성 및 자기수축 특성을 보다 정량적으로 분석할 수 있었으며, 두 가지 특성의 상관관계를 정량적인 수치로 비교 분석하는 것이 가능하였다.

• 한국구조물진단유지관리공학회 논문집
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• 제26권5호
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• pp.95-102
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• 2022

최근, 전세계적으로 온실 가스의 저감에 관심이 높아지면서 건설 산업에서도 FA를 대량 치환하는 HVFAC의 사용을 위한 연구가 수행되고 있다. 시멘트의 수화도와 FA 반응도의 정량적인 측정은 HVFAC의 강도발현 메커니즘을 명확히 이해할 수 있게 한다. FA가 포함된 시멘트 페이스트의 수화 및 포졸란 반응은 매우 복잡하고 수화 생성물의 조성을 정확하게 결정할 수 없으므로 간단한 방법으로 반응도를 설명하는 것은 매우 어렵다. 따라서, 이 연구는 재령에 따른 하이볼륨 FA 시멘트의 수화 특성을 조사하였다. 시멘트의 수화도와 FA의 반응도는 재령에 따른 선택용해법과 페이스트의 비증발 수량을 통해 평가하였다. 또한 HVFA 모르타르 시편을 이용하여 연령에 따른 압축강도를 측정하였다. 실험결과 FA의 치환율이 증가할수록 시멘트의 수화도는 증가하나 FA의 반응성은 감소하는 것으로 나타났다.

• 한국건축시공학회지
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• 제4권4호
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• pp.79-86
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• 2004

The purpose of this study was the development of a recycling process to recover the hydraulic properties of hydration products which account for a large proportion of cementitious powder from concrete waste. This process was performed to recycle cementitious powder as recycle cement. Therefore, after the theoretical consideration of the properties of recycle process of recycled aggregates and cementitious powder, we investigated the hydraulic properties of cementitious powder under various temperature conditions in hardened mortar which was modeled on concrete waste. And we analyzed properties of chemical reactions of recycled cement with admixture materials such as Fly-Ash, Blast Furnace Slag As a result of the experiment, the most effective method to recover hydraulic properties of the cementitious powder from concrete waste was condition of burning at 700℃ for 120 minute. And it is shown that the fluidity of mortar was decreased rapidly when the burning temperature of recycle cement was increased. However, the compressive strength and fluidity were improved significantly when admixture materials such as Fly-Ash or Blast Furnace Slag was added.

• 한국세라믹학회지
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• 제24권3호
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• pp.289-295
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• 1987

The changes of physical properties of portland cement pastes and mortars were investigated by addition of sodium gluconate. Flow table experiment and viscosity measurement were took in order to find dispersing effect, and time-dependent changesof viscosity and rates of hydration heat evolution were carried out for the sake of finding retardation effect of hydration. And changes of physical properties of cement pastes and mortars were discussed by setting time, compressive strength and porosity.