• Title/Summary/Keyword: hydration products

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Effects of Chloride Binding on the Cement Hydration at early ages (초기재령에 있어 시멘트 수화에 따른 염화물 고정화 효과)

  • 문소현;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.437-442
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    • 1999
  • Corrosion of steel reinforcment is the most significant factor of deterioration in reinforced concrete structures. Chloride ion is considered one of the most common culprits on the corrosion of steels in concrete. This study is effect of cement hydraulic degree on the chloride binding in hardened cement pastes. With increasing the cement hydration, cement products such as CSH and Ca(OH)2 were increased, and the part of added chloride were binded with them. With respect to A type, in first, the additional contents of chloride of 27.08mM/L in pore solution were reduced as 4.3mM/L at 3 days, 4.0mM/L at 7 days, 3.6mM/L at 28 days.

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Identification of Electrical Resistance of Fresh State Concrete for Nondestructive Setting Process Monitoring

  • Shin, Sung Woo
    • Journal of the Korean Society for Nondestructive Testing
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    • v.35 no.6
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    • pp.414-420
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    • 2015
  • Concrete undergoes significant phase changes from liquid to solid states as hydration progresses. These phase changes are known as the setting process. A liquid state concrete is electrically conductive because of the presence of water and ions. However, since the conductive elements in the liquid state of concrete are consumed to produce non-conductive hydration products, the electrical conductivity of hydrating concrete decreases during the setting process. Therefore, the electrical properties of hydrating concrete can be used to monitor the setting process of concrete. In this study, a parameter identification method to estimate electrical parameters such as ohmic resistance of concrete is proposed. The effectiveness of the proposed method for monitoring the setting process of concrete is experimentally validated.

Experiment Study on the Improvement of the Early-Age Strength of Fly Ash Concrete Using CSA (CSA를 사용한 플라이애시 콘크리트의 초기강도 개선을 위한 실험연구)

  • Park, Ji-Sun;Jeon, Chan-Soo
    • Korean Journal of Materials Research
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    • v.23 no.12
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    • pp.687-694
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    • 2013
  • This study was performed with an aim to improve the early-age strength of concrete containing fly ash, which is known to increase the long-age strength of concrete, reduce drying shrinkage, and enhance water tightness. The composition was partially substituted with calcium sulfoaluminate (CSA), from which ettringite is actively produced, in the early stages of hydration to verify its effect on improving the early-age strength and to determine the optimal mixing ratio. For this purpose, up to 30 % of the cement weight was substituted with fly ash, and the amount of CSA substitution was 8% of the fly ash weight. The mixtures were then fabricated into concrete specimens for compressive strength measurement and analysis of the correlation between the hydration products and the compressive strength.

Property Change of Cement Mortar Incorporating FA by Immerging Vegetable Oil (식물성 유지류에 침지된 FA 치환 시멘트 모르타르의 품질변화)

  • Baek, Cheol;Lee, Jae-Hyeon;Hwang, Chan-Woo;Han, In-Deok;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.147-148
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    • 2016
  • Generally, the vegetable oil contains glycerin esther and free fatty acid. When the vegetable oil reacts with concrete, the glycerin esther from oil induces saponification by reacting with and hydrolyzing calcium hydroxide from cement hydration. As a result of this saponification, it has been reported the expansion of concrete. although the free fatty acid from vegetable oil, as an acid, can decompose the concrete by producing soluble salt from calcium hydroxide or CSH, the hydration products of cement, there was no report on the harmful oil type for concrete. therefore, in this research, the property change of cement mortar incorporating fly ash was analyzed experimentally by immerging various types of vegetable oils.

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Expansion behavior of concrete containing different steel slag aggregate sizes under heat curing

  • Shu, Chun-Ya;Kuo, Wen-Ten
    • Computers and Concrete
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    • v.16 no.3
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    • pp.487-502
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    • 2015
  • This study investigated particle expansion in basic oxygen furnace slag (BOF) and desulfurization slag (DSS) after heat curing by using the volume method. Concrete hydration was accelerated by heat curing. The compressive strength, ultrasonic pulse velocity, and resistivity of the concrete were analyzed. Maximum expansion occurred in the BOF and DSS samples containing 0.30-0.60 mm and 0.60-1.18 mm particles, respectively. Deterioration was more severe in the BOF samples. In the slag aggregates for the complete replacement of fine aggregate, severe fractures occurred in both the BOF and DSS samples. Scanning electron microscopy revealed excess CH after curing, which caused peripheral hydration products to become extruded, resulting in fracture.

Fundamental Properties of Alkali Activated Slag Mortar with Different Activator Type (자극제의 종류에 따른 알칼리 활성화 슬래그 모르타르의 기초 특성)

  • An, Yang-Jin;Mun, Kyoung-Ju;Soh, Seung-Young;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.789-792
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    • 2006
  • The purpose of this study is to investigation the fundamental properties of alkali activated slag of type and concentration of alkali activator. In this paper sodium silicate, sodium carbonate and sodium hydroxide were used as alkaline activator and their concentration were 1, 3, 5 and 7 $Na_2O$ weight percent. The physical properties of alkali activated blast furnace slag cement mortar (AAS) were investigated by flow test and compressive strength. And the hydration properties of AAS characterized by X-ray diffraction and scanning electron microscope. Result show that Alkali activated slag mortar strengths were continuously increased with adding amount and ages. C-S-H were formed to be the main products up to 28days of hydration.

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Synthesis and Properties of Calcium Sulfoaluminate Type Expansive (칼슘설포알루미네이트계 팽창재의 제조 및 기초 물성)

  • 전준영;송종택
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.388-394
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    • 2000
  • The C4A3S clinker was prepared by the solid-state reaction. The mixture of raw materials; calcite, kaoline and gypsum, was fired at 135$0^{\circ}C$ for 1hr and cooled rapidly in air. C4A3S type expansive was made with C4A3S clinker, CaO and CaSO4. The cement replaced by 10 wt.% C4A3S type expansive was investigated by the measurement of the strength(compressive, tensile, flexural) and length change at various curing conditions. Hydration products were mainly ettringite, monosulfate and Ca(OH)2. The densification and the expansion due to the formation of ettringite during the hydration increased strength and reduced the drying shrinkage of hardened cement.

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Anti-aging Effect of Agarum cribrosum in UVA-irradiated Normal Human Epidermal Keratinocytes (자외선 조사에 의해 노화된 인간각질형성세포에서 구멍쇠미역 추출물의 항노화 효능)

  • Shim, Joong Hyun
    • Korean Journal of Pharmacognosy
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    • v.52 no.4
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    • pp.228-233
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    • 2021
  • This research was carried out to investigate the moisturizing effects of Agarum cribrosum extract on normal human epidermal keratinocytes (NHEKs). Moisturizing effects of A. cribrosum extract on NHEKs were measured by quantitative realtime RT-PCR to verify the gene expressions related to skin hydration, hyaluronic acid (HA)-ELISA to detect HA production, and cell viability assays. A. cribrosum extract increased the mRNA levels of the AQP3 and HAS2 genes and HA production in NHEKs. On the other hand, A. cribrosum extract decreased the mRNA level of the KRT1 and KRT10 genes known as differentiated keratinocyte marker in NHEKs. This research showed the moisturizing effects of A. cribrosum extract. The results indicate that A. cribrosum extract can be a potent functional ingredient for skin hydration and anti-aging products. Further study is warranted regarding the use of A. cribrosum extract to develop not only cosmetics but also food and medicine.

Evaluation of Hydration Effect on Human Skin by $^1H$ MRS at 14.1T

  • Choi Chi-Bong;Hong Sung-Tak;Choe Bo-Young;Woo Dong-Chul;Yoon Seong-Ik;Cho Ji-Hyun;Lee Chul-Hyun;Cheong Chae-Joon;Park Sang-Yong;Oh Chil-Hwan
    • Journal of the Korean Magnetic Resonance Society
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    • v.10 no.1
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    • pp.105-114
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    • 2006
  • Purpose: We achieved high resolution MR imaging and spectra of human skin in vitro with using a 14.1 T MRI/MRS system, and evaluated the hydration effect of various cosmetic products by measuring the skin's. moisture concentration. Materials and Methods: We used the Bruker 14.1 T MRI/MRS system with a vertical standard bore that was equipped with a DMX spectrometer gradient system (200 G/cm at a maximum 40 A), RF resonators (2, 5 and 10 mm) and Para Vision software. Spin echo and fast spin echo pulse sequences were employed for obtaining the high resolution MR images. The 3D-localized point resolved spectroscopy (PRESS) method was used to acquire the MR spectra. Results: The high resolution MR images and spectra of human skin in vitro were successfully obtained on a 14.1 T system. The water concentration of human skin after applying a moisturizer was higher than that before applying a moisturizer. Conclusions: The present study demonstrated that the high-resolution MR images and spectra of human skin from a high field NMR instrument could be applicable to evaluating the hydration state of the stratum corneum.

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The Effects of Snail Secretion Filtrate on the damaged skin barrier's recovery of the Atopic dermatitis (달팽이 점액이 아토피 피부염 환자의 피부장벽 회복에 미치는 영향)

  • Oh, Min-Jee;Park, Sung-Min;Kim, Hee-Taek
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.23 no.3
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    • pp.138-153
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    • 2010
  • Purposes : The object of present study is to detect the Effects of Snail Secretion Filtrate and Hyaluronic acid on the skin barrier's recovery of the Atopic dermatitis. Methods : A total of 20 patients who visited Semyung Hanny Oriental Medical Center from september 1st, 2009 to August 31th, 2010 were included in this study. In this study, they were treated with Snail Secretion Filtrate(experimental group) and Hyaluronic acid(control group). For 4 weeks gross examination, hematological examination and instrumentation through skin-ANBT equipment were made before and after the experiments to see how well the products for experimental group act against those for control group in recovering the damaged skin barriers by Atopic dermatitis. Results : 1. In the primary endpoint, SCORAD Index showed a statistically significant decline in both the control group and the experimental group. However, the experimental group showed greater statistical significance than the control group. 2. In the secondary endpoint index of skin hydration, both the control group and the experimental group did not show a statistically significant increase. However, the degree of skin hydration in the experimental group is greater than in the control group. 3. In global assessment of efficacy, it was higher in the experimental group than in the control group for both the subjects and the researchers. 4. To evaluate the safety of the products for the human body, hematological examination and hematological biochemical examination were conducted; both the control group and the experimental group showed no abnormal level. Therefore, the safety of the products, if used for so long a time, proved to be safe for the human body. 5. Product satisfaction was higher in the experimental group than in the control group. Conclusions : According to above experiments, Snail Secretion Filtrate was effective on the Atopic dermatitis.