• 제목/요약/키워드: hydrated

검색결과 492건 처리시간 0.055초

Effects of Curing Temperature on Autogenous Shrinkage, Relative Humidity, Pore Structure of Cement Pastes

  • Park Ki-Bong
    • 콘크리트학회논문집
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    • 제17권5호
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    • pp.853-856
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    • 2005
  • A low water/cement ratio leads to autogenous shrinkage of cement paste at an early age. This autogenous shrinkage is related to the change of relative humidity in the pore structure that is formed during the hydration process. The relationship between autogenous shrinkage and relative humidity change are relatively well defined today, but the effects of temperature on autogenous shrinkage, relative humidity, and pore structures have been studied less systematically. This study focused on correlating alterations of these properties of cement paste hydrated at constant temperatures of 20, 40, and $60^{\circ}C$. The test results clearly indicate that increasing curing temperature resulted in increased porosity, particularly for pores between 5 to 50 nm as measured by MIP, and increased autogenous shrinkages, as a consequence of a reduction of relative humidity at early ages.

사료 중의 곰팡이와 곰팡이 독소에 대한 문제점과 가능한 대책 (Problems and Possible Solutions about Feed Fungi and Mycotoxins)

  • 남기홍
    • 한국가금학회지
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    • 제21권2호
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    • pp.113-117
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    • 1994
  • Of the 200, 000 known species of molds, only 50 or 60 are known to be harmful to humans or livestock. Certain fungi that grow on grains and grasses can produce chemical substances called mycotoxins that adversely affect performance in poultry. There are several methods of preserving feed ingredients. The list includes: drying, antioxidants, mold inhibitors, organic acids, phosphates, cooking or toasting, fat extraction, blending and fermenting. Mold inhibitors are manufactured to inhibit mold growth and prevent the production of toxic substances. They are fungistats and not fungicides, that is, they only stop the growth of molds. Practical and cost-effective methods to detoxify mycotoxin containing feedstuffs are in great demand. 0.5% hydrated sodium calcium aluminosilicate added to the diet protected chicks from the deleterious effects of aflatoxin-contaminated feed. The dietary addition of antioxidants and methionine also significantly diminished the negative effects on body weight in chicks toxicated with 3.0 ppm aflatoxin B1.

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Electrochemical Response of Polymer Actuators using Finite Element Formulation and ANSYS/Emag

  • Kang, Sung-Soo
    • Journal of Advanced Marine Engineering and Technology
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    • 제34권3호
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    • pp.369-375
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    • 2010
  • The two-dimensional finite element formulation for the basic field equations governing electrochemical responses of ionic conducting polymer-metal composite(IPMC) actuators is proposed in the present study. Biaxial deformation of a platinum plated Nafion actuator having 4 electrodes is dominated by electro-osmosis of hydrated ions and self-diffusion of free water molecules. Some numerical studies for IPMC actuators with electric field are carried out in order to show the validity of the proposed formulation and electric field analysis for the initial condition of total charge distribution are conducted using commercial code ANSYS/Emag.

종이의 물성에 영향하는 섬유특성의 정량적 해석(II) (Quantitative Analysis of Pulp fiber Characteristics that Affect Paper Properties (II))

  • 이강진;박종문
    • 펄프종이기술
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    • 제32권2호
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    • pp.35-39
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    • 2000
  • Refining is very important process of fibers treatment for proper paper properties. An extent of refining is usually measured by freeness, although freeness gives complicated meanings. One of a direct way of studying the refining effects on pulp fibers is making photomicrographs of beaten fibers. The conventional microscopy like light microscopy(LM) and scanning electron microscopy(SEM) require to preserve the wet structure of pulp fibers morphologically since most of papermaking process is carried out almost entirely in water. Recently developed microscopy, especially confocal laser scanning microscopy(CLSM), offers the possibility of examining fully hydrated pulp fibers. Cross-sectional images of wet pulp fibers are also generated using optical sectioning by CLSM and image analysis in order to verify and quantify the extent of fiber wall swelling indicating the internal fibrillation. At low beating load such as 2.5 kgf, in the same freeness, breaking length is higher than that of high beating load such as 5.6 kgf. fiber wall thickness at low beating load is greater than that at high beating load. This result is accounted for the fact that internal fibrillation in the low beating load was high.

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Prediction of chloride binding isotherms for blended cements

  • Ye, Hailong;Jin, Xianyu;Chen, Wei;Fu, Chuanqing;Jin, Nanguo
    • Computers and Concrete
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    • 제17권5호
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    • pp.655-672
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    • 2016
  • A predictive model for chloride binding isotherms of blended cements with various supplementary cementitious materials (SCMs) was established in this work. Totally 560 data points regarding the chloride binding isotherms of 106 various cements were collected from literature. The total amount of bound chloride for each mixture was expressed a combinational function of the predicted phase assemblage and binding isotherms of various hydrated phases. New quantitative expressions regarding the chloride binding isotherms of calcium-silicate-hydrate (C-S-H), AFm, and hydrotalcite phases were provided. New insights about the roles of SCMs on binding capabilities of ordinary portland cements (OPC) were discussed. The proposed model was verified using separate data from different sources and was shown to be reasonably accurate.

Manufacture of Vanadium pentoxide and nickel sulfate from heavy oil fly ash

  • Park, Gyeong-Ho
    • 자원리싸이클링
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    • 제2권4호
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    • pp.23-26
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    • 1993
  • This work is carried out to develop the recovery process of vanadium as vanadium pentoxide and nickel as nickel sulphate from the leaching solution of heavy oil fly ash. First, sodium chlorate solution was added to the leaching solution to oxidize vanadium ions. With adjusting pH of the solution and heating, vanadium ions(V) is hydrated and precipitated as red cake of $V_2O_5$ from the solution. After recovering vanadium, nickel is recovered as ammonium nickel sulfate with crystallization process. From this nickel salt, nickel sulfate which meets the specifications for the electroplating industry can be produced economically. More than 85% of vana-dium and nickel in the fly ash are recovered in this process.

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Effect of polyolefin fibers on the permeability of cement-based composites

  • Hsu, Hui-Mi;Lin, Wei-Ting;Cheng, An
    • Computers and Concrete
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    • 제9권6호
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    • pp.457-467
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    • 2012
  • This study evaluates the permeability of cement-based composites, which are a mix of polyolefin fibers and silica fume. Test results indicate that permeability increases as the water/cementitious ratio increases. Silica fume in cement-based composites produced hydrated calcium silicate and filled the pores. However, permeability decreased as the addition of silica fume increased. Specimens containing polyolefin fibers also provided higher permeability resistance. The polyolefin fiber length did not have a significant effect on permeability. The decrease in the permeability is mainly due to the addition of silica fume and lower water/cementitious ratio. Addition of fibers marginally decreases the permeability. Incorporating polyolefin fiber and silica fume in composites achieved more significant decreases in permeability. The correlated test results reveal the interrelationship between them.

Soil cement의 응결과정에 따른 상변화 및 역학특성 (Study on the phase change and engineering properties of soil cement)

  • 김성필;장병욱;차경섭;원정윤
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2003년도 학술발표논문집
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    • pp.195-198
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    • 2003
  • A small amount of cement can be added to the soil with high water content to improve its engineering properties. It is difficult to point out the exact time when liquified state of soil is transformed into semi-plastic or plastic states when high water content soil is hydrated by cement. In this study fall cone penetration are used to explain the phase change and compactable status of soil cement. And engineering properties of soil cement compacted in plastic state are investigated. Results reveal that fall cone penetration depth of 1mm or less is judged to a compactable state of soil-cement. Permeability and CBR values of soil cement increased with mixing ratio increased.

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미가류 내열재 개발 (Development of Unvulcanized Insulator)

  • 이원복;손원경
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 1998년도 제11회 학술강연회논문집
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    • pp.30-30
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    • 1998
  • Solid rocket motor case의 internal insulator로 미가류 형태의 내열재에 적당하게 tacky성과 삭막 특성을 고려한 조성을 개발하여 시스템에 성공적으로 적용하였다. 개발된 내열재의 주요 조성으로는 base polymer로 EPDM과 CR을 80/20으로 blend하여 적용했으며, 삭막 특성 향상을 위해 아라미드 섬유인 Kevlar 29를 5 phrs, Hydrated silica인 Zeosil 155를 30phrs 적용하였다. 이와 같은 조성으로 제작된 내열재는 삭마시험, 인장시험, 열특성시험 등 각종 특성시험을 수행하여 시스템에 적용하기 위한 성능을 확인하고 공정에 적용하였다. ST-8 표준 모타에 적용하여 삭막시험한 결과 삭마율 0.21mm/sec를 얻었고, 추진기관 사용 온도인 -4$0^{\circ}C$-6$0^{\circ}C$ 온도 범위에서 기계적성질 값을 측정하여 성능 저하가 없는 안정된 값을 얻었으며, DSC로 Tg point 측정 결과 -55$^{\circ}C$로 나타나 저온특성이 우수한 EPDM 내열재 특성을 확인할 수 있었다.

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인공 진주 안료로서 염기성 질산비스무트에 관한 연구 (Properties of Bismuthoxynitrate as a Synthetic Pearl Pigment)

  • 이계주;유병설
    • 약학회지
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    • 제22권1호
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    • pp.22-26
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    • 1978
  • The purposes of this investigation were to study the characteristic properties of bismuthoxynitrate formed by hydrolysis of bismuthnitrate according to various reaction conditions and to propose the property difference between synthesized pearl pigment and bismuthsubnitrate as pharmaceuticals by means of X-ray diffraction, IR, DTA and TGA. The pearl pigment could be obtained by reaction of bismuth nitrate-diluted nitric acid solution with cold water (5.deg.) agitation at lower pH. The pearl pigment was BiO. NO$_{3}$. 2H$_{2}$O. in composition and crystalline form was thin plate of monoclinic system and its combination with water was assumed to be hydrated hydrous form between Bi-H$_{2}$O bond. On the other hand, bismuthsubnitrate was 5BiO.4NO$_{3}$.6H$_{2}$O in composition and crystalline form was pillar of rhombic system and the bond between Bi and H$_{2}$O molecules was assumed to be hydrous form. The different properties between two compounds in structure are presumed to be caused by the hydrolysing conditions of bismuthnitrate respectively.

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