• Restorative Dentistry and Endodontics
• /
• 제25권3호
• /
• pp.446-458
• /
• 2000

In this study, compressive strengths of three condensable composite resins(ALERT, SureFil, Solitaire), conventional hybrid composite resin(Z-100) and amalgam(HI-Aristaloy 21) according to the 6 types of cavity design(cylinder, trapezoidal, butt-joint, round bevel, long bevel and short bevel) were measured and appearance of fracture surfaces were observed with SEM, thus evaluated clinical applications of condensable composite resins according to the cavity designs. The results were as follows; 1. Compressive strengths according to experimental materials were the highest in SureFil, and Z-100, ALERT, Solitaire, HI-Aristaloy 21 in order. 2. SureFil showed the highest compressive strength(p<0.05). compressive strengths of ALERT and Solitaire were lower than that of Z-100, hybrid composite(p<0.05). 3. Compressive strengths according to specimen design were the highest in trapezoidal shape(p<0.05) and no significant difference was detected between other specimen designs. 4. The appearance of condensable composite resin under SEM was of a diverse configuration according to component of resin matrix, shapes of filler and surface treatments between resin and filler.

• Restorative Dentistry and Endodontics
• /
• 제25권3호
• /
• pp.359-370
• /
• 2000

The purpose of this investigation was to observe the viscoelastic properties of five commercial flowable(Aeliteflo, Flow it, Revolution, Tetric flow, Compoglass flow), three conventional hybrid(Z-100, Z-250, P-60) and two condensable(Synergy compact, SureFil) resin composites. A dynamic oscillatory shear test was done to evaluate the storage shear modulus (G'), loss shear modulus(G"), loss tangent(tan ${\delta}$) and complex viscosity(${\eta}^*$) of the resin composites as a function of frequency - dynamic frequency sweep test from 0.01 to 100 rad/s at $25^{\circ}C$ - by using Advanced Rheometric Expansion System(ARES). To investigate the effect on the viscosity of resin composites of filler volume fraction, the filler weight % and volume % were measured by means of Archimedes' principle using a pyknometer. The results were as follows 1. The complex viscosity ${\eta}^*$ of flowable resins was lower than that of hybrid resins and significant differences were observed between brands. The complex viscosity ${\eta}^*$ of condensable resins was higher than that of hybrid resins. The order of complex viscosity ${\eta}^*$ at ${\omega}$=10 rad/s was as follows, Surefil, Synergy compact, P-60, Z-250, Z-100, Aeliteflo, Tetric flow, Compoglass flow, Flow it, Revolution. The relative complex viscosity of flowable resins compared to Z-100 was 0.04~0.56 but Surefil was 30.4 times higher than that of Z-100. 2. The storage shear modulus G' and the loss shear modulus G" of flowable resins were lower than those of hybrid resins but those of condensable resins were higher. The patterns of the change of loss tangent, tan ${\delta}$, of resin composites with increasing frequency were significantly different between brands. The phase angles, ${\delta}$, ranged from $30.2{\sim}78.1^{\circ}$ at ${\omega}$=10 rad/s. 3. All composite resins represent pseudoplastic nature with increasing shear rate. 4. The complex shear modulus $G^*$ and the phase angle ${\delta}$ was represented by the frequency domain phasor form, $G^*({\omega})=G^*e^{i{\delta}}=G^*{\angle}{\delta}$. The locus of frequency domain phasor plots in a complex plane was a valuable method that represent the viscoelastic properties of composite resins. 5. There was no direct linear correlationship but a weak positive relation was observed between filler volume % or weight % and the viscosity of the resin composites.

• Restorative Dentistry and Endodontics
• /
• 제21권1호
• /
• pp.321-338
• /
• 1996

The purpose of this study was to evaluate the effect of moistening and air-drying of acid conditioned dentin and enamel on the marginal microleakage. In this study, Class V cavity were prepared on both buccal and lingual surface of sixty extracted human premolars with cementum margin. These specimens were randomly devided into three groups and three dentin adhesives(Scotchbond Multi-Purpose, All bond 2, Prisma Universal Bond 3) were applied to each group. The specimens in each group were subdevided into four groups (Wet/primed, Dry/primed, Wet/not primed, Dry/not primed) and the etched dentin and enamel surface were treated these four surface treatments prior to the placement of a bonding agent or adhesive. Wet/primed group was simply blot-dried with a damp facial tissue before primer placement ; Dry/primed group was air dried for 30 seconds before the placement of a primer ; Wet/not primed group and Dry/not primed group were not primed after blot dried and air dried for 30 seconds each group. The bonding agent and composite resin were applied for each group. All specimens were exposed to 500 cycle of thermal stress. Specimens were placed in a silver nitrate solution and then sectioned buccolingually through the center of the restoration. The dye penetrations of the specimens were observed with a stereo microscope. The statistical test were applied to the results using a one way analysis variance (ANOVA) and Duncan's multiple range test. The aspects of silver ion penetration into the resin/dentin interface were examined under scanning electron microscopy. The results were as follows. 1. In all groups, the enamel margin showed significantly lower leakage value than the cementum margin (p<0.05). 2. Regardless of various surface treatment and dentin adhesives, there was no significant difference at the enamel margins (p>0.05). 3. At the dentin margins, the leakage values of Dry/not primed group showed significantly higher than that of the other groups (p<0.05). The leakage values of Wet/primed group showed significantly lower than that of the other groups, but, there was no significant difference between Wet group and Dry group. 4. There was no significantly difference between the dentin adhesives regarding the surface treatments in all groups(p>0.05). 5. On the backscatterd scanning electron microscopy observation, the penetration of the silver ion occured at the bonding resin/dentin interface. In the Wet/primed group, resindentin hybrid zone and resin penetration into the dentin was observed. The resin tags were compactively formed to a thickness of $3\sim4{\mu}m$ at the upper part of dentinal tubules. In the Dry/primed group, the thickness of the hybrid zone and the diameter, depth of the resin tags diminished. In the Non-primed groups, the hybrid zone was not identified and few resin tag was observed. There was the gap formation in the resin/dentin interface.

• 한국응용과학기술학회지
• /
• 제28권3호
• /
• pp.359-366
• /
• 2011

In this study we experimented that how polyurethane effect to acrylic-polyurethane resin in Full-Grain leather coatings. First of all, we consummated waterborne acrylic emulsion and waterborne polyurethane resin, Than we prepared F.G leathers which were coated by acrylic resin and acrylic-polyurethane resins. According to measured data for solvent resistance, acrylic resin and acrylic-polyurethane resins had good property. Sample a(WAC) had most low strength($2.10kg_f/mm^2$) and sample d(WAC 93 : WPU 7) had most high strength($3.41kg_f/mm^2$). Also we knew that most good property of abrasion is d(47.4 mg). In elongation case, a(WAC) had most good result(645 %) in this experiment.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2008년도 춘계학술대회 논문집
• /
• pp.793-794
• /
• 2008

• 대한소아치과학회지
• /
• 제33권2호
• /
• pp.233-243
• /
• 2006

와동 형성시 C-factor와 충전방법이 복합레진 수복물에서의 수축 응력에 미치는 영향을 평가하고자 발거된 소구치를 대상으로 C-factor가 3.6과 1.0인 와동을 각각 형성한 후 hybrid형 복합레진인 $Z-250^{TM}$(3M ESPE U.S.A.)과 flowable형 복합레진인 $Filtek\;flow^{TM}$(3M ESPE U.S.A.)를 사용하여 layering을 시행하고 광중합하면서 strain gauge법을 이용하여 치질에서의 수축 응력을 측정하였다. 시편을 절단하여 레진과 상아질 사이 계면의 접착상태를 주사전자현미경으로 관찰한 결과 다음과 같은 결과를 얻었다. 1. C-factor에 따른 수축 응력을 측정한 결과 C-factor가 3.7인 제 1군과 제 2군 그리고 제 5군이 900초 후 각각 0.11, 0.07, 0.07 MPa로 C-factor가 1.0인 제 3군과 제 4군의 0.05와 0.04 MPa에 비해 크게 나타났다(P<0.05). 1,800초 후에는 제 1군, 제 5군, 제 2군, 제 3군, 제 4순으로 크게 나타났으나 제 2군과 제 3군 그리고 제 3군과 제 4군 사이에는 유의성이 없었다. 2. 재료에 따른 수축 응력의 차이는 C-factor가 3.7인 와동의 경우 hybrid형 레진인 Filtek $Z-250^{TM}$이 flowable 레진인 $Filtek\;flow^{TM}$에 비해 수축 응력이 크게 나타났으나(P<0.05), C-factor가 1.0인 와동의 경우 재료의 차이에 따른 수축응력의 유의한 차이가 없었다. 3. Layering에 따른 수축 응력은 Filtek $Z-250^{TM}$을 layering 없이 bulk 충전한 제 1군에 비해 flowable 레진을 layering한 제 5군이 전 측정 시간대에 걸쳐 수축 응력이 유의하게 낮게 나타났다(P<0.05). 4. C-factor가 3.7인 제 1군과 제 2군 제 5군은 900초까지 수축 응력이 증가하다 이후 점차 감소하는 경향을 보였다. 5. C-factor가 1.0인 와동의 경우 충전용 레진 종류에 관계없이 레진과 와동벽 사이에 긴밀한 접착 상태를 보였으나 C-factor가 3.7인 와동의 경우 부분적으로 틈이 관찰되었다. 전반적으로 와동저에 비해 와동벽에서 틈이 더 많이 관찰되었다. 이상의 결과를 종합하여 보면 복합레진 수복시 수축응력에 따른 합병증을 예방하기 위해 C-factor를 크지 않게 와동을 설계, 형성하여야 하며 C-factor가 클 경우 flowable 레진을 이장하는 등 재료적인 면에서의 선택과 적용법이 중요할 것으로 사료된다.

• Restorative Dentistry and Endodontics
• /
• 제15권2호
• /
• pp.17-33
• /
• 1990

The purpose of this study was to evaluate the fracture toughness of dental composite resins and to investigate the filler factor affecting the fracture behaviour on which the degree of fracture toughness depends. Six kinds of commercially available composite resin;, including two of each macrofilled, microfilled, and hybrid type were used for this study, The plane strain fracture toughness ($K_{10}$) was determined by three-point bending test using the single edge notch specimen according to the ASTM-E399. The specimens were fabricated with visible light curing or self curing of each composite resin previously inserted into a metal mold, and three-point bending test was conducted with cross-head speed of 0.1mm/min following a day's storage of the specimens in $37^{\circ}C$ distilled water. The filler volume fractions were determined by the standard ashing test according to the ISO-4049. Acoustic Emission(AE), a nondestructive testing method detecting the elastic wave released from the localized sources In material under a certain stress, was detected during three-point bending test and its analyzed data was compared with, canning electron fractographs of each specimen. The results were as follows : 1. The filler content of composite resin material was found to be highest in the hybrid type followed by the macrofilled type, and the microfilled type. 2. It was found that the value of plane strain fracture toughness of composite resin material was in the range from 0.69 MPa$\sqrt{m}$ to 1 46 MPa$\sqrt{m}$ and highest In the macrofilled type followed by the hybrid type, and the microfilled type. 3. The consequence of Acoustic Emission analysis revealed that the plane strain fracture toughness increased according as the count of Acoustic Emission events increased. 4. The higher the plane strain fracture toughness became, the higher degree of surface roughness and irregularity the fractographs demonstrated.

• The Journal of Advanced Prosthodontics
• /
• 제15권3호
• /
• pp.114-125
• /
• 2023

PURPOSE. The aim of the study was to evaluate the optical properties of new generation (3Y-TZP) monolithic zirconia (MZ) with different abutment types and resin cement shades. MATERIALS AND METHODS. A1/LT MZ specimens were prepared (10 × 12 × 1 mm, N = 30) and divided into 3 groups according to cement shades as transparent (Tr), yellow (Y) and opaque (O). Abutment specimens were obtained from 4 different materials including zirconia (Group Z), hybrid (Group H), titanium (Group T) and anodized yellow titanium (Group AT). MZ and abutment specimens were then cemented. L^*, a^*, and b^* parameters were obtained from MZ, MZ + abutment, and MZ + abutment + cement. ∆E₀₀₁^* (between MZ and MZ + abutment), ∆E₀₀₂^* (between MZ and MZ + abutment + cement) and ∆E₀₀₃^* (between MZ + abutment and MZ + abutment + cement) values were calculated. Statistical analyses included 2-way ANOVA, Bonferroni, and Paired Sample t-Tests (P < .05). RESULTS. Abutment types and resin cements had significant effect on L^*, a^*, b^*, ∆E₀₀₁^*, ∆E₀₀₂^*, and ∆E₀₀₃^* values (P < .001). Without cementation, whereas zirconia abutment resulted in the least discoloration (∆E₀₀₁^* = 0.68), titanium abutment caused the most discoloration (∆E₀₀₁^* = 4.99). The least ∆E₀₀₂^* = 0.68 value was seen using zirconia abutment after cementation with yellow shaded cement. Opaque shaded cement caused the most color change (∆E₀₀₃^* = 5.24). Cement application increased the L^* values in all groups. CONCLUSION. The least color change with/without cement was observed in crown configurations created with zirconia abutments. Zirconia and hybrid abutments produced significantly lower ∆E₀₀₂^* and ∆E₀₀₃^* values in combination with yellow shaded cement. The usage of opaque shaded cement in titanium/anodized titanium groups may enable the clinically unacceptable ∆E₀₀^* value to reach the acceptable level.

• Elastomers and Composites
• /
• 제47권4호
• /
• pp.318-328
• /
• 2012

본 연구에서는 blocked isocyanate와 하이브리드 기술을 이용해서 1액 경화형 폴리우레탄 탄성체를 제조하였다. 1액 경화형 하이브리드 폴리우레탄의 제조를 위해서 hydroxyl group을 포함하는 실리카 하이브리드를 합성하고 입자크기, 형태 및 탄성체 내의 하이브리드 입자분포를 확인하였다. 또한, 열해리특성, 기계적 물성, 성형특성을 조사하였다. 1액 경화형 폴리우레탄 탄성체의 열해리 특성을 평가한 결과 온도가 높을수록, 열처리 시간이 길어질수록 blocking된 isocyanate의 해리가 더 잘 진행되었다. 합성된 실리카 하이브리드는 직경이 23~27 nm이고 구형이었으며 하이브리드 폴리우레탄의 단면을 FE-SEM과 EDS를 사용해서 분석한 결과 하이브리드 입자가 폴리우레탄 분자구조 내에 잘 분산되어있는 것을 확인하였다. 하이브리드 폴리우레탄의 경우에는 하이브리드를 포함하지 않는 폴리우레탄 탄성체에 비해 기계적물성, 내마모성 및 열적특성이 향상되었으며 가소제를 사용하는 경우에는 물성의 변화가 거의 없는 것으로 확인되었다.

• 접착 및 계면
• /
• 제2권1호
• /
• pp.1-8
• /
• 2001

본 연구에서는 슬러지 및 폐타이어 칩(WTC)으로부터 얻은 폐석분을 충전제로 하고 불포화 폴리에스테르 수지(UPE)를 결합재로 하여 고분자 혼성복합재를 제조하였다. 또한 무기 충전제와 매트릭스 사이의 계면 결합뿐만 아니라 매트릭스 내의 충전제의 분산을 향상시키기 위하여 실란[${\gamma}$-methacryloxy propyl trimethoxy silane(${\gamma}$-MPS)]을 이용하여 표면처리를 하였다. 혼성복합재의 구조적 특성과 기계적 물성에 대한 이 무기 재활용 충전제의 함량과 농도의 영향은 Mercury Porosimeter 및 주사전자현미경을 이용하여 관찰하였다.