• Title/Summary/Keyword: hot melt

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The Effect of Casting Conditions on the Fluidity during Lost Foam Casting of Al Alloy (알루미늄 합금의 소실모형주조 시 유동도에 미치는 주조 조건의 영향)

  • Shin, Seung-Ryoul;Han, Sang-Won;Lee, Kyong-Whoan;Lee, Zin-Hyoung
    • Journal of Korea Foundry Society
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    • v.24 no.1
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    • pp.34-39
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    • 2004
  • The effects of casting condition and hot melt glue during Lost Foam Casting were investigated on the fluidity of Al alloy melt. The fluidity increased linearly with increasing pouring temperature in thick castings but non-linearly in thin casting due to the difference in main heat flow direction. The metal flow velocity was in range of $0.5{\sim}2.7$ cm/s in no evacuation condition and the minimum value of it was measured after the melt flow through the hot melt barrier. The mold evacuation improved the metal flow velocity by around $0.5{\sim}1$ cm/s. And the reaction zone layer thickness was about 1 cm in no-evacuation conditions but about 0.6 cm in mold evacuation condition of 710 torr due to the easier removal of pyrolsis product of EPS. And hot melt barrier thickness of 0.6 mm increased the reaction zone layer thickness up to about 2.5 cm. The fluidity decreased remarkably with an enlarged thickness of hot melt due to a lot of pyrolysis products.

The effect of melt flow index on polymer deformation in hot embossing process (고분자 분자량 변화에 따른 핫 엠보싱 공정 연구)

  • Yoon, Keun-Byoung;Jeong, Myung-Young
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1025-1029
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    • 2003
  • We studied the cross-sectional profiles of deformed thermoplastics in hot embossing process and compared with melt flow index for various embossing conditions such as embossing temperature, embossing pressure and initial thickness of the thermoplastics. The fastest embossing times for complete penetration of the cavities were obtained at temperature greater than $60^{\circ}C$ above glass transition temperature (Tg). When the melt flow index of polymer is low, the penetration ratio does not become large even if the embossing pressure increases. The complete occupation of the cavities was easier obtained with high melt flow index polymer than low melt flow index polymer at the same process condition. We believe these results can be very useful for optimizing nanostructured hot embossing also known nanoimprinting process conditions.

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Preparation and Their Properties of Hot-Melt Adhesive using Styrene Block Copolymer and Petroleum Resin (스타이렌 블록 공중합체(SBC)와 석유수지를 이용하여 제조한 핫멜트 접착제의 제조 및 특성)

  • Jeong, Booyoung;Cheon, Jungmi;Yoo, Chongsun;Chun, Jeahwan
    • Journal of Adhesion and Interface
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    • v.9 no.4
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    • pp.12-16
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    • 2008
  • Hot-melt adhesive was solid phase in room temperature as 100% solid contents. So it has advantage which attach to substrate with the low pressure heat, fast adhesion speed and environment friendly. In this study, We studied about the effect of a kind of SBS resin and petroleum resin as a tackifier resin and their ratio for hot-melt adhesive on properties. The styrene and $C_9$ resin contents in hot-melt adhesive was increased with increasing viscosity, tensile strength, peel strength and thermal resistance.

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Functional Improvement of Hot Melt Adhesive Using Polyamide Type Resin -(I) Physical Properties of Adhesives- (폴리아미드계 수지를 이용한 핫멜트 접착제의 기능 향상 -(I) 접착제의 물성-)

  • Chun, Young-Sik;Hong, Young-Keun;Chung, Kyung-Ho
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.194-202
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    • 1996
  • Hot melt adhesive based on the polyamide resin was studied to improve the conventional hot melt adhesives such as ethylene-vinyl acetate which have inherent problems against creep and heat resistance. It was found that the terpolymer of nylons6, nylon66, and nylon12 or the nylon blend instead of nylon homopolymer was suitable base resin for hot melt adhesives, since the disruption of regularity in the polymer chains reduced the crystallinity, resulting in lower melting point and melt viscosity. Also, the rheological properties of the polyamide based hot melt adhesive could be controlled by the incorporation of terpene resin, butyl benzyl phthalate, and paraffin wax. The results of melt viscosities and tensile properties of adhesive itself indicated that the optimum adhesion properties could be obtained through the blending of CM831/843P resins with weight ratio 75/25~50/50. The adhesion between steel and steel was tested by using lap shear geometry. It was found that the surface roughness of steel affected the adhesion strength.

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A Study on Adhesion Performance of Styrene-Block-Copolymer Based Hot Melt Pressure Sensitive Adhesives with Dicyclopentadiene Based Hydrogenated Hydrocarbon Resins (수첨 DCPD계 석유수지를 이용한 SBCs계 핫멜트점착제의 접착성능 연구)

  • Shim, Jaeho;Kim, Yunho;Lee, Jungjoon
    • Journal of Adhesion and Interface
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    • v.15 no.4
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    • pp.145-150
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    • 2014
  • Dicyclopentadiene (DCPD)-based hydrocarbon resins are widely used as tackifiers in many applications. In particular, hydrogenated DCPD-based hydrocarbon resins are widely used in premium hot-melt-type adhesives such as hot melt adhesives (HMAs) and/or hot melt pressure-sensitive adhesives (HMPSAs), because are water-white in color and possess excellent stability to light and heat. This article discusses the adhesive performance of various hydrogenated DCPD resins when they are used as tackifiers in styrene-block-copolymer (SBC)-based HMPSAs. This article shows the correlation between the characteristics of tackifiers and the adhesive performance of SBC-based HMPSAs. The higher the softening point of the tackifier, the higher is the $T_g$, softening point, and crossover temperature of the PSAs. High aromatic H wt% content reduces the high-temperature resistance of PSAs, as suggested by the decrease in the crossover temperature and softening point of the PSAs.

Adhesion Property of Low-Viscosity Polyurethane Hot-Melt Adhesive in according to the Deblocking Temperature and Content of Reactive Diluents (해리온도와 반응성 희석제 함량에 따른 저점도 폴리우레탄 핫멜트 접착제의 접착특성)

  • Choi, Min Ji;Jeong, Boo Young;Cheon, Jung Mi;Ha, Chang-Sik;Chun, Jae Hwan
    • Journal of Adhesion and Interface
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    • v.17 no.2
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    • pp.67-71
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    • 2016
  • In this study, low-viscosity polyurethane hot-melt were synthesized with polyether polyol / polyester polyol, 4,4-dicyclohexylmethane diisocyanate ($H_{12}MDI$), 2-butanone oxime (MEKO) to improve the properties and peel strength. The properties of the synthesized low-viscosity polyurethane hot-melt was evaluated through FT-IR, viscosity meter and UTM. When the content of the reactive diluent increases and the NCO-blocked prepolymer decreases, the viscosity of low-viscosity polyurethane hot-melt adhesive was increased. When the ratio of OH-terminated oligomer, NCO-blocked prepolymer and content of reactive diluent is 1 : 0.5 : 0.5, low-viscosity polyurethane hot-melt showed 1.1 kgf/cm peel strength.

Effect of Composition of EVA-based Hot-Melt Adhesives on Adhesive Strength (EVA계 핫멜트 접착제의 조성이 접착력에 미치는 영향)

  • Lee, Jung-Joon;Song, Yu-Hyun;Lim, Sang-Kyun;Park, Dae-Soon;Sung, Ick-Kyung;Chin, In-Joo
    • Journal of Adhesion and Interface
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    • v.11 no.4
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    • pp.155-161
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    • 2010
  • A series of ethylene vinyl acetate (EVA) based hot melt adhesives containing different types and compositions of tackifier resins were prepared to investigate their rheological behavior and T-peel adhesion strength on polyurethane (PU) elastomeric sheets. C5 aliphatic hydrocarbon resin (C5 resin), C9 aromatic hydrocarbon resin (C9 resin), hydrogenated dicyclopentadiene resin ($H_2$-DCPD resin), and dicyclopentadiene and acrylic monomer copolymer resin (DCPD-acrylic resin) were used as the tackifiers for the hot melt adhesives. To determine the polarity of the tackifiers, their oxygen contents were analyzed, and the DCPDacrylic resin was found to contain an oxygen content higher than the other tackifiers. Only the DCPD-acrylic resin showed complete miscibility with EVA and the homogeneous phase of the hot melt adhesive blends at all compositions. The T-peel adhesion strength between the hot melt adhesives and polyurethane elastomeric sheets was mainly affected by the polarity of the tackifier resins in the hot melt adhesives, rather than by the storage moduli, G', of the hot melt adhesives themselves.

Effect of Hot Pressing/Melt Mixing on the Properties of Thermoplastic Polyurethane

  • Lee, Young-Hee;Kang, Bo-Kyung;Kim, Han-Do;Yoo, Hye-Jin;Kim, Jung-Soo;Huh, Jae-Ho;Jung, Young-Jin;Lee, Dong-Jin
    • Macromolecular Research
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    • v.17 no.8
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    • pp.616-622
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    • 2009
  • In-depth understanding of the influence of hot pressing and melt processing on the properties of thermoplastic polyurethane (TPU) is critical for effective mechanical recycling of TPU scraps. Therefore, this study focused on the effects of hot pressing and melt mixing on molecular weight (MW), polydispersity index (PDI), melt index (MI), characteristic IR peaks, hardness, thermal degradation and mechanical properties of TPU. The original TPU pellet (o-TPU) showed two broad peaks at lower and higher MW regions. However, four TPU film samples, TPU-0 prepared only by hot pressing of o-TPU pellet and TPU-1, TPU-2 and TPU-3 obtained by hot pressing of melt mixed TPUs (where the numbers indicate the run number of melt mixing), exhibited only a single peak at higher MW region. The TPU-0 film sample had the highest $M_n$ and the lowest PDI and hardness. The TPU-1 film sample had the highest $M_w$ and tensile modulus. As the run number of melt mixing increased, the peak-intensity of hydrogen bonded C=O stretching increased, however, the free C=O peak intensity, tensile strength/elongation at break and average MW decreased. All the samples showed two stage degradations. The degradation temperatures of TPU-0 sample (359 $^{\circ}C$ and 394 $^{\circ}C$)were higher than those of o-TPU (342 $^{\circ}C$ and 391 $^{\circ}C$). While all the melt mixed samples degraded at almost the same temperature (365 $^{\circ}C$ and 381 $^{\circ}C$). The first round of hot pressing and melt mixing was found to be the critical condition which led to the significant changes of $M_n$/$M_w$/PDI, MI, mechanical property and thermal degradation of TPU.

A Comparative Study of Mechanical Property in Al-8Fe-2Mo-2V-1Zr Bulk Alloys Fabricated from an Atomized Powder and a Melt Spun Ribbon

  • Jung, T.K.;Sung, T.J.;Kim, M.S.;Kim, W.Y.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1023-1024
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    • 2006
  • Al-8Fe-2Mo-2V-1Zr alloys were prepared by the gas atomization/hot extrusion and the melt spinning/hot extrusion. For the gas atomized and extruded alloy, equiaxed grains with the average size of 400 nm and finely distributed dispersoids with their particle sizes ranging from 50nm to 200nm were observed. For the melt spun and hot extrusion processed alloy, refined microstructural feature consisting of equiaxed grains with the average size of 200nm and fine dispersoids with their particle sizes under 50nm appeared to exhibit a difference in microstructure. Strength of the latter alloy was higher than that for the former alloy up to elevated temperatures.

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