• Title/Summary/Keyword: homogeneous weight

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Hydrolysis of DFP Using Cu(II)-Lactic Acid and Cu(II)-LMWS-Chitosan Chelates (Cu(II)-Lactic Acid와 Cu(II)-LMWS-Chitosan 착물의 DFP 가수분해반응 연구)

  • Kye, Young-Sik;Jeong, Keunhong;Kim, Dongwook
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.475-480
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    • 2020
  • Chelates synthesized with Cu(II) ion and lactic acid or chitosan were applied to the hydrolysis of organophosphate simulant, DFP (diisopropyl fluorophosphate). Under the homogeneous reaction condition, Cu(II)-lactic acid chelate hydrolyzed DFP with the half life time of 37.1 min. Cu(II)-LMWS chitosan chelate was synthesized with 1 kDa molecular weight of chitosan, which showed low solubility, and then crystallized. The half life time for hydrolyzing DFP using Cu(II)-LMWS chitosan was 32.9 h indicating that the reaction rate is enhanced as much as 16 times more than that of using 18 kDa chitosan-Cu(II) complex. Under the homogeneous reaction condition, the half life time of Cu(II)-LMWS chitosan was 8.75 h. Therefore, we found out that the solubility of Cu(II)-LMWS chitosan makes the difference in the reaction rate as much as 4 times.

Image Retrieval Using the Color Co-occurrence Histogram Describing the Size and Coherence of the Homogeneous Color Region (칼라 영역의 크기와 뭉침을 기술하는 칼라 동시발생 히스토그램을 이용한 영상검색)

  • An Myung-Seok;Cho Seok-Je
    • The KIPS Transactions:PartB
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    • v.13B no.3 s.106
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    • pp.275-282
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    • 2006
  • For the efficient image retrieval, the method has studied that uses color distribution and relations between pixels. This paper presents the color descriptor that stands high above the others in image retrieval capacity. It is based on color co-occurrence histogram that the diagonal part and the non-diagonal part are attached the weight and modified to energy of color co-occurrence histogram, and the number of bins with petty worth have little influence is curtailed. It's verified by analysis that the diagonal part carries size information of homogeneous color region and the non-diagonal part does information about the coherence of it, Moreover the non-diagonal part is more influential than diagonal part in survey of similarity between images. So, the non-diagonal part is attached more weight than the diagonal part as a result of the research. The experiments validate that the proposed descriptor shows better image retrieval performance when the weight for non-diagonal part is set to the value between 0.7 and 0.9.

A Study on the Vibration Analysis of a Power Transmission Converter by Substructure Synthesis Method (부분구조합성법에 의한 동력전달 변화기의 진동해석에 관한 연구)

  • 박석주;왕지석;박성현;오창근;박영철
    • Journal of Advanced Marine Engineering and Technology
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    • v.24 no.3
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    • pp.52-57
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    • 2000
  • This study intends to reduce the weight of structure without changing the dynamic characteristics. At first, the Vibration analysis by the Substructure Synthesis Method and FFM using the ANSYS are performed for the engine speed converter to confirm the reliability of the analyzing tools. Weight minimization is performed by the Sensitivity Analysis and the Optimum Structural Modification. To decrease the converter weight ideally, the parts with low sensitivity are to be cut mainly, and the changing quantity of the natural frequency by the cut is to be recovered by the weight modification of the parts with high sensitivity. As the unique mathematical solution for the homogeneous problem(i.e. 0 object function problem) does not exist, the converter is redesigned with much thinner initial thickness. The goal of this study is to recover the dynamic characteristics of redesigned structure to those of the original one. To say in the other words, the modified structure has the same dynamic characteristics and the more lighter weight to compare with the original one.

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Weighted LP Estimates for a Rough Maximal Operator

  • Al-Qassem, H.M.
    • Kyungpook Mathematical Journal
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    • v.45 no.2
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    • pp.255-272
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    • 2005
  • This paper is concerned with studying the weighted $L^P$ boundedness of a class of maximal operators related to homogeneous singular integrals with rough kernels. We obtain appropriate weighted $L^P$ bounds for such maximal operators. Our results are extensions and improvements of the main theorems in [2] and [5].

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A Study on Comparison and Evaluation of various Strength in Seoul Granite (서울화강암의 암석강도 측정치의 비교 평가 연구)

  • 윤지선;김두영;정흥모
    • Tunnel and Underground Space
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    • v.5 no.2
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    • pp.144-154
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    • 1995
  • In this paper, we make a study on comparison and evaluation of the seoul granite properties, which are unit weight, uniaxial compressive strength, Brazilian tensile strength and, point load strength. The typical result are as follow- 1. From the measured value of point load strength anisotropy index, the seoul granite is considered to be homogeneous. 2. There is a linear relationship between uniaxial compressive strength and size corrected point load strength index. 3. Brazilian tensile strength and size corrected point load strength index are closely tied together.

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Improved Procedure for Purification of Clostridium botulinum type B Toxin (Clostridium botulinum Type B 독소의 정제방법에 관한 연구)

  • 박문국;양규환
    • Korean Journal of Microbiology
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    • v.20 no.4
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    • pp.183-188
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    • 1982
  • The neurotoxin of Clostridium botulinum type B was purified from a liquid culture. The purification steps consist of ammonium sulfate precipitation of whole culture, treatment of Polymin P(0.15%, v/v), gel filtration on Sephadex G-100 at pH5.6 and DEAE-Sephadex charomatography at pH8.0. The procedure recovered 17% of the toxin assayed in the starting culture. The toxin was homogeneous by sodium dodecyl sulfate(SDS)-polyacrylamide gel electrophoresis and had a molecular weight of 163, 000. Subunits of 106, 000 and 56, 000 molecular weight were found when purified toxin was treated with a disulfide-reducing agent and electro phoresed on SDS-polyacrylamide gels.

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Epoxidized Polybutadiene as a Thermal Stabilizer for Poly(3-hydroxybutyrate). II. Thermal Stabilization of Poly(3-hydroxybutyrate) by Epoxidized Polybutadiene

  • Choi, Ju-Yol;Lee, Jong-Keun;You, Young;Park, Won-Ho
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.195-198
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    • 2003
  • Epoxidized polybutadiene (EPB) was prepared by polybutadiene (PB) with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. EPB was blended with poly(3-hydroxybutyrate) (PHB) up to 30 wt% by solution-precipitation procedure. The thermal decomposition of PHB/EPB blends was studied by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and differential thermal analysis (DTA). The thermograms of PHB/EPB blends contained a two-step degradation process, while that of pure PHB sample exhibited only one-step degradation process. This degradation behavior of PHB/EPB blends, which have a higher thermal stability as measured by maximum decomposition temperature and residual weight, is probably due to crosslinking reactions of the epoxide groups in the EPB component with the carboxyl chain ends of PHB fragments during the degradation process, and the occurrence of such reactions can be assigned to the exothermic peaks in their DTA thermograms.

Purification and Characterization of Superoxide Dismutase from Pseudomonas polycolor

  • LEE SANG-OK;IL-CHUN SEO;SOOK-HYUN CHUNG;TAE-HO LEE
    • Journal of Microbiology and Biotechnology
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    • v.3 no.3
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    • pp.188-193
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    • 1993
  • Superoxide dismutase (SOD) was purified from Pseudomonas polycolor to an electrophoretically homogeneous state and partially characterized. SOD was purified by ammonium sulfate fractionation, column chromatography on DEAE-Sephadex A-50, phenyl-Toyopearl 650 M, and gel filtration on Sephadex G-100. The molecular weight and subunit molecular weight of the purified enzyme were estimated to be 40, 000 and 20, 000, respectively. The purified enzyme remained stable at pH 9.0~11.0, $25^{\circ}C$ for 40 hr, but rapidly became inactive below 9.0. SOD was stable up to $45^{\circ}C$ at pH 9.0 with about 80% relative activity, but rapidly became inactive at temperature above that. The enzyme was insensitive to cyanide and fluoride, and sensitive to hydrogen peroxide and azide. The results suggest that the enzyme be an iron-containing SOD.

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Preparation of PZI Tapes by Solvent Washing Dry Method (용매세척건조법에 의한 PZT 테입 제조)

  • 신효순;윤석진;김현재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.300-303
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    • 1999
  • For the fast dry of the aqueous tape, the process which water was replaced by organic solvent was proposed. So-called, it was the solvent washing dry, Three organic solvents (methanol, ethanol, and acetone) were selected for the washing solvent. The weight loss of the washed tapes was measured to evaluate the dry rate of the tapes and dried tapes were examined the generation of the cracks with the variations of the organic solvent and the washing time. Methanol, ethanol, and acetone were all available organic solvents for this method. The tapes washed in methanol, ethanol, and acetone were dried rapidly for twenty minutes. After thirty minutes, the weight losses were not any more. The solvent of the lower surface tension can decreases the crack of dried tape. If solvent substitutes water completely, though it was fast dried, crack can be eliminated. The tape casting system was designed for the solvent washing dry and prepared. An homogeneous tape was established by continuous tape casting process.

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Characteristics of $SnO_2$ Prepared by Preparation Method with Ammonium Nitrate (Ammonium Nitrate를 이용한 침전법으로 제조된 $SnO_2$ 특성분석)

  • Son, Hyang-Ho;Lee, Won-Gyu
    • Applied Chemistry for Engineering
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    • v.21 no.4
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    • pp.440-444
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    • 2010
  • $SnO_2$ powders were prepared from the calcination of stannic acids precipitated from the aqueous solution of $SnCl_4$ with ammonium nitrate as a precipitator at $90^{\circ}C$. For the comparison of properties, the stannic acids were prepared from the homogeneous precipitation method using urea as a precipitator at the same temperature. The stannic acid from ammonium nitrate at a thermal gravity analysis showed the weight loss until $700^{\circ}C$ and the percentage of total weight loss was 16.5%. The crystallization of stannic acid into $SnO_2$ finished in the calcination at $600^{\circ}C$ for 2 h. The crystallite size of $SnO_2$ increased with the increase of calcination temperature and initial concentration of $SnCl_4$ solution. In case of the same calcination condition, $SnO_2$ prepared from homogeneous precipitation using urea had a relatively smaller crystallite size rather than $SnO_2$ prepared from ammonium nitrate.