• Bulletin of the Korean Chemical Society
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• v.35 no.4
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• pp.1121-1127
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• 2014

The design, synthesis, and structural characterization of two new palladium complexes based on Schiff base ligands is reported; $[Pd(L1)_2]$ (1) and $[Pd(L2)_2]$ (2), [HL1 = 2-((E)-(2,6-diethylphenylimino)methyl)-4,6-dibromophenol, L2 = (E)-N-benzylidene-2,6-diethylbenzenamine], which are obtained by functionalizing Schiff base ligands with or without electron-withdrawing groups. Both compounds are mononuclear structures. Comparisons are made to the compounds 1 and 2 to analyze and understand the effect of electron-withdrawing groups. Antibacterial activity studies indicate the electron-withdrawing groups on Schiff base ligands enhance antibacterial activity. Catalytic activity, however, is reduced due to the enhanced steric-hindrance of the electron-withdrawing groups. Electronic absorption and emission properties of HL1, L2, 1 and 2 are also reported.

• Elastomers and Composites
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• v.47 no.2
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• pp.148-155
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• 2012

EPDM, IIR, and BIIR composites were thermally aged and the crosslink density changes were investigated. Crosslink densities of the EPDM composite increased with increasing the aging time and temperature, whereas those of IIR and BIIR composites for long-term aging at high temperatures tended to decrease. Activation energies for the crosslink density changes of the EPDM composite were higher than those of the BIIR one. The experimental results were explained with the number of allylic hydrogens, activation of the zinc complex, the steric hindrance effect, and oxidation of rubber chain.

• Bulletin of the Korean Chemical Society
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• v.30 no.3
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• pp.589-594
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• 2009

We have performed DFT B3LYP/6-31G(d,p) calculations to investigate the complexation behaviors of the ethyl ester derivative of p-tert-butylcalix[6]arene (1) toward a variety of alkylammonium ions. We have studied the binding sites of these host-guest complexes focusing on the p-tert-butylcalix[6]arene pocket (endo) of 1. The smaller alkylammonium cations have the better complexation efficiency than the bulkier alkylammonium ions with the p-tert-butylcalix[6]aryl ester. The hydrogen-bonding of N-H$\ldots$O is one of the important factors for the complexation behavior of the p-tert-butylcalix[6]aryl ester, in addition to the NH-aromatic π, CH-aromatic π and electrostatic interactions, and the steric hindrance of alkylammonium cation. The hydrogen-bonded distances and angles of N-H$\ldots$O are reported for the complexes of the p-tert-butylcalix[6]aryl ester with various alkylammonium ions.

• Proceedings of the KSR Conference
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• 2006.11b
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• pp.1247-1252
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• 2006

This Report explains a plan for the application and construction about BOM(Bill Of Material) in charge of primary part of the RIMS(Rolling-Stock Information Maintenance System) maximizing the RIMS's reliability. The BOM system of the Seoul Metro is accomplished the frequent changes of the structure and design through the OEM(Original Equipment Manufacturer) and the maintaining and repairing work and also The BOM system is constructed so that Seoul Metro can solve all problems of the composition change, Rolling-Stock construction, changeful history management. In addition the BOM system of the Seoul Metro is considered the applicative side of the technical data, information of the material, expediency and hindrance analysis.

• Proceeding of Spring/Autumn Annual Conference of KHA
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• 2002.11a
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• pp.183-187
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• 2002

This study researched that the remodeling was executed desirably in the side of deweller's household to the subject of ten apartment housings located in Gwang-ju, Jun-nam province. The study method was used the field study method and used in parallel with participant observation. As a result of the study, first, the problems of remodeling enforcement process are brought about standardized design, bad construction and the difficulty of solution in the defect occurrence. Second, By that request of the household is not reflected, the room except bedroom and the bathroom of inner room are low practical use degree. And wash space, garden space, assistant space of kitchen work were becoming hindrance factor of the residing environment because the use is irrational.

• Journal of Hydrogen and New Energy
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• v.9 no.3
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• pp.119-125
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• 1998

The modified statistical-mechanical theory for dense fluid mixtures of rigid spheres has been applied to rigid sphere fluids in the nonoverlapping pore model. The resulting expressions for the partition coefficient and diffusivity illustrate the influence of steric hindrance on the thermodynamic and transport properties in such systems. The open membrane model without the size-exclusion and shielding effects shows considerable overestimation of the diffusion flux when the effective mean pore radii of the order of $20{\AA}$ or less are involved. Theoretical predictions investigated here were also compared with experimental data for hydrogen gases in inorganic porous membranes and it was observed a qualitative agreement in the low pressure limit.

• KEPCO Journal on Electric Power and Energy
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• v.6 no.3
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• pp.297-303
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• 2020

The reaction of carbon dioxide with the amine-based absorbents which have various substituents in the molecule was described. In the case of MEA which is a representative primary amine, the absorption reaction was proceeded very fast while the regeneration reaction was took place slowly due to the strong bond strength between the absorbent and carbon dioxide. The more substituents on N atom of the absorbent, the slower the absorption reaction between carbon dioxide and the absorbent, which in turn causes faster the regeneration rate from the reaction intermediate, carbamate.

• Journal of the Korean Institute of Educational Facilities
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• v.21 no.6
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• pp.25-32
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• 2014

Korean academic libraries are facing serious space shortage problems due to an inability to accommodate for the rapidly increasing number of printed materials. Despite the current situation, Korean academic libraries have largely focused on impractical applications of the new library paradigm, using technology or management programs to improve the quality of research and learning environments of the university. However, such improvements would be fruitless without first resolving the space shortage crisis. In order to make realistic improvements to the quality of academic libraries, this study used questionnaires to employ the opinions of librarians currently practicing at such Korean libraries. Survey questionnaires about types and causes of space shortage problems, library facility expansion plans, expected effects of expansion, frequency of and reasons for furniture relocation, and tight spaces needing improvement were distributed to selected 4-year college librarians through Google Drive. Analysis of survey responses indicated that library space shortage was largely responsible for the hindrance of research and learning environments. Furthermore, it reflected the urgency to secure book storage space.

• Korean System Dynamics Review
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• v.6 no.2
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• pp.117-138
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• 2005

The defence industry of the Republic of Korea(ROK) has grown up since 1970, however it is facing a growth hindrance due to its structural problem. Many professionals of defense industry has developed some measures to upgrade and energize the defence industry of ROK, and also the current government is implementing various transformations and new policies under the initiative of cooperative independence defence. But most of papers published so far have some limitations resulting from their qualitative contents. And also it is true for them not to show policy alternatives devised by the system thinking. This paper identifies essential factors of defense industry, then analyze the causal relation among those factors. It also shows the causal loop to identify the politic leverages, on which concrete measures to resolve the structural problems are based.

• Smart Media Journal
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• v.6 no.1
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• pp.39-46
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• 2017

The internet has become an important part of the many aspects of people's daily lives such as work, study, entertainment and in form of electronic commerce, shopping. Electronic commerce is growing rapidly in Kenya. There are many successful business-to-business, business-to-customer and customer-to-customer online shopping companies in Kenya. As a consequence, competition between vendors is intense and, therefore, mitigating the negative effects of high product uncertainty is necessary requirement as it remains a biggest hindrance for success of the online shopping. The purpose of this research is to investigate how online product description, third party product assurance, customer service and website design mitigate the negative impact of high product uncertainty. A questionnaire with 28 items is designed to collect data from online customers. Using multiple regression analysis, the relationship between dependent variable (product uncertainty) and independent variables such as product description, third party assurance, website design and customer service is tested. The result shows that all the independent variables are negatively correlated with dependent variable, which means that product description, third party assurance, website design and customer service can be used by online vendors to lessen the problem of product uncertainty in online markets.