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http://dx.doi.org/10.18770/KEPCO.2020.06.03.297

Substituent Effect in the Reaction of Carbon Dioxide with Amine-Based Absorbent  

Shim, Jae-Goo (KEPCO Research Institute, Korea Electric Power Corporation)
Lee, Junghyun (KEPCO Research Institute, Korea Electric Power Corporation)
Jung, Jin-Kyu (KEPCO Research Institute, Korea Electric Power Corporation)
Kwak, No-Sang (KEPCO Research Institute, Korea Electric Power Corporation)
Publication Information
KEPCO Journal on Electric Power and Energy / v.6, no.3, 2020 , pp. 297-303 More about this Journal
Abstract
The reaction of carbon dioxide with the amine-based absorbents which have various substituents in the molecule was described. In the case of MEA which is a representative primary amine, the absorption reaction was proceeded very fast while the regeneration reaction was took place slowly due to the strong bond strength between the absorbent and carbon dioxide. The more substituents on N atom of the absorbent, the slower the absorption reaction between carbon dioxide and the absorbent, which in turn causes faster the regeneration rate from the reaction intermediate, carbamate.
Keywords
Amine-Based Absorbent; Carbon Capture and Storage; Post-Combustion $CO_2$ Capture; Substituent; Steric Hindrance;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 IEA, "Energy Technology Perspectives 2016," IEA Publication, 2016.
2 C. Hendriks, "Carbon dioxide removal from coal-fired power plants," Dissertation, Utrecht University, 1994.
3 R. J. Perry, M. J. O'Brien, "Amine disiloxanes for $CO_2$ capture," Energy Fuels, Vol. 25, pp. 1906-1918, 2011.   DOI
4 P. Bernardo, E. Drioli, G. Golemme, "Membrane gas separation: a review/state of the art," Ind. Eng. Chem. Res., Vol. 48, pp. 4638-4663, 2009.   DOI
5 H. Yang, Z. Xu, M. Fan, R. Gupta, R. B. Slimane, A. E. Bland, I. Wright, "Progress in carbon dioxide separation and capture," J. Environ. Sci., Vol. 2, pp. 14-27, 2008.
6 P. W. F. Reimer, W. G. Ormerod, "International perspectives and the results of carbon dioxide capture disposal and utilization studies," Energy Convers., Vol. 36(6-9), pp. 813-818. 1995.   DOI
7 IEA GHG, "Opportunities for Early Application of $CO_2$ sequestration technologies report PH4/10," IEA Greenhouse Gas R&D Programme, 2002.
8 J. G. Shim, J. H. Kim, K. R. Jang, "Absorption characteristics of aqueous sodium glycinate solution with carbon dioxide and its mechanistic analysis," J. Kor. Soc. Env. Eng., Vol. 30(4), pp. 430-438, 2008.
9 N. S. Gwak, J. H. Lee, D. W. Lee, J. H. Lee, J. G. Shim, "Performance analysis of upgrading process with amine-based $CO_2$ capture pilot plant," KEPCO Journal on Electric Power and Energy, Vol. 4, No. 1, pp 33-38, 2018. DOI: http://dor.org/10.18770/KEPCO.2018.04.01.033.   DOI
10 G. Satori, D. W. Savage, "Sterically hindered amines for $CO_2$ removal from gases," Ind. Eng. Chem. Fundam., Vol. 22, pp. 239-249, 1983.   DOI
11 W. J. Choi, J. B. Seo, S. Y. Jang, J. H. Jung, K. J. Oh, "Removal characteristics of $CO_2$ using aqueous MEA/AMP solutions in the absorption and regeneration process," J. Environ. Sci., Vol. 21(7), pp. 907-913, 2009.   DOI
12 Y. Liu, W. Fan, K. Wang, J. Wang, "Studies of $CO_2$ absorption/regeneration performances of novel aqueous monoethanolamine (MEA)-based solution,", J. Clean. Prod., Vol. 112, pp. 4012-4021, 2016.   DOI
13 T. L. Donaldson, Y. N. Nguyen, "Carbon dioxide reaction kinetics and transport in aqueous amine membranes," Ind. Eng. Chem. Fundam., 1980, Vol. 19, pp. 260-266.   DOI
14 G. T. Rochelle, "Amine scrubbing for $CO_2$ capture", Science, 2009, Vol. 325, pp. 1652-1654.   DOI
15 P. Muchan, C. Saiwan, J. Narku-Tetteh, R. Idem, T. Supap, P. Tontiwachwuthikul, "Screening tests of aqueous alkanolamine solutions based on primary, secondary, and tertiary structure for blended aqueous amine solution selection in post combustion $CO_2$ capture," Chem. Eng. Sci., Vol. 170, pp. 574-582, 2017.   DOI
16 E. F. da Silva, H. F. Svendsen, "Study of the carbamate stability of amines using ab initio methods and free-energy perturbations," Ind. Eng. Chem. Res., Vol. 45, pp. 2497-2504, 2006.   DOI
17 Y. Mergler, R. R. V. Gurp, P. Brasser, M. de Koning, E. Goetheer, "Solvent of CO2 capture. Structure-activity relationships combined with vapour-liquid-equilibrium measurements," Energy Proc., Vol. 4, pp. 259-266, 2011.   DOI