• Elastomers and Composites
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• v.48 no.2
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• pp.103-113
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• 2013

The properties of the rubber composites containing a silane and silica were evaluated by changing the mixing time and temperature, in order to find the optimum mixing conditions. Characteristics of the compounds were evaluated after mixing at $120^{\circ}C$, $140^{\circ}C$, and $160^{\circ}C$ with various mixing time. With increasing of mixing time, mooney viscosity decreased while the bound rubber contents of the compounds increased. Viscosity rise by increased mixing time was bigger at low temperature and the higher the mixing temperature the faster in the formation of bound rubber. With lower mixing temperature of $120^{\circ}C$, cross-linking rate was almost constant. Dynamic viscoelastic properties and dispersity of the compound showed that dispersion of ingredients and reaction was not sufficient with the mixing time of less than 10min. On the contrary, with high temperature, it was obvious that good dynamic and physical properties could be obtained due to sufficient coupling reaction, however it was thought this high temperature is not optimum because of sensitive cross-linking rate and physical properties and excessive formation of bound rubber. Consequently, it was confirmed that the mixing condition of 10min at $140^{\circ}C$ was optimum for the silane coupling reaction and dispersion of functionalized S-SBR containing silica and silane.

• Elastomers and Composites
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• v.48 no.2
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• pp.94-102
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• 2013

Characteristics of rubber mixture were evaluated in order to find the optimum mixing conditions of compounds containing silica and silane at various temperatures. With different mixing temperatures of 105, 120, 130, 140 and $160^{\circ}C$, the viscosity of the compound mixed at $105^{\circ}C$ showed a very high viscosity value. Compounds mixed the temperature range from at $120^{\circ}C$ to $140^{\circ}C$ showed lower viscosity than the compound mixed at $105^{\circ}C$. However, the difference was found to be small in those temperature ranges. On the contrary, at the mixing temperature of $160^{\circ}C$, the viscosity of compound increased again. Through the physical and dynamic observations, it was verified that at the mixing temperature below $120^{\circ}C$ only insufficient silica-silane reaction has been obtained. In addition, with the elevated mixing temperature of $160^{\circ}C$, Cross-linking occurred during mixing by the sulfur contained in coupling agent. In the temperature ranges from $120^{\circ}C$ to $140^{\circ}C$, because of the fast coupling reaction at higher temperature, it was thought to be more advantageous during reaction even though the trend of viscosity and dynamic mechanical property was not clear.

• Clean Technology
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• v.13 no.1 s.36
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• pp.34-45
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• 2007

Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.30 no.5
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• pp.435-444
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• 2017

The vehicle-track structure dynamic interaction analysis problem can be treated as sliding contact problem, and it is assumed that vehicle run at a constant speed over a rail modeled as beam elements. Unfortunately, Salome-Meca can not satisfy the compatibility condition for the beam master elements, which are consist of the elements with higher order polynomial shape function, in sliding contact problem. In this study, it is suggested to use more finer beam master element mesh as the remedy for incompatibility in sliding contact problem, and the accuracy of the solution is secured. For this, the effect of beam element mesh refinement consisting runway is analysed through simple examples, and the applicability to the dynamic interaction analysis is evaluated. Finally, the dynamic interaction analysis of railway skewed culvert transition problem is carried out to evaluate the effect of supporting stiffness due to backfill pattern changes and track irregularity due to uneven subgrade settlement.

• Korean Journal of Materials Research
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• v.8 no.6
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• pp.532-537
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• 1998

The purpose of this study was to investigate the behavior of ozone in DI water and the reaction with wafers during the semiconductor wet cleaning process. The solubility of ozone in DI water was not only dependent on the temperature but also directly proportional to the input concentration of ozone. The lower the initial ozone concentration and the temperature, the longer the half-life time of ozone. The reaction order of ozone in DI water was calculated to be around 1.5. The redox potential reached a saturation value in 5min and slightly increased as the input ozone concentrations increased. The completely hydrophilic surface was created in Imin when HF etched silicon wafer was cleaned in ozonized DI water containing higher ozone concentrations than 2ppm. Spectroscopic ellipsometry measurements showed that the chemical oxide formed by ozonized DI water was measured to be thicker than that by piranha solution. The wafers contaminated with a non-ionic surfactant were more effectively cleaned in ozonized DI water than in piranha and ozonized piranha solutions.

• Journal of Gifted/Talented Education
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• v.19 no.1
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• pp.1-23
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• 2009

Science field trip is a comprehensive learning activity in which students can solve problems by themselves, whose importance is emphasized in learning for the gifted. But because not much study has been done yet on this, and convergent activities such as solving too many problems or requesting given answers have generally been done, it has been criticized for not being enough to develop the abilities of gifted Students. Therefore, this study attempted to analyze the activity process of the gifted through field trip to which open inquiry is adapted so that the demands of the gifted can be met, and the abilities of the gifted can be brought out. The study focused on 18 gifted elementary science students at Institute of Science Gifted Education, Cheongju National University of Education, and in the field trip process of the students, analyzed the types of establishment of inquiry problems and inquiry process, and the behavioral characteristics of gifted science students shown during field trip activity through field trip proceedings, transcript contents, poster materials, questionnaires, etc. As a result, more inquiry problems were established after than before inquiry, and the level of inquiry problems was also higher after inquiry. The solution process for inquiry problems of the gifted science students were done in the following order: planning, inquiring, follow-up inquiring and consolidating. But it proceeded to open inquiry process, the next stage being decided according to circumstances. Also, in the inquiry that the students did, diverse factors were revealed such as basic and integrative inquiries, and especially, the students were competent in analyzing the results after transforming and interpreting them. And the analysis of the interaction among the students showed many behavioral traits of talented science students.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.17-26
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• 2003

The sorption experiment of cobalt was performed after the TRIGA soil was intentionally contaminated with cobalt was found that the sorption equilibrium coeficiency of soil decontamination was high when the ratio of soil mass to the volume of citric acid becomes 1:5 The TRIGA soil contaminated with 0.01 M, 0.001 M, and 0.0001 M of cobalt solution were decontaiminated with 0.01 M citric acid. The cobalt concentrtion in the wastewater were measured to be correspondingly 36.0, 14.0, 1.5 ppm. The results of wastewater recycling experiment by chemical precipitation method revealed that corresponding cobalt removal efficiency were 97% 88%. It was shown that the removal efficiency decreases as the cobalt concentration in the wastewater decreases. During the decontamination experiment, a lot of NaOH had to be added, and the volume of final solid waste reached almost 10% of that of the contaminated soil. The result of wastewater recyling experiment by ion exchange resin meted rethod revealed that to more the strong acid resins are used, the higher the cobalt removal efficiency becomes and the cobalt removal efficiency becomes and the lower the pH of recycling wastewater become. In order to obtain more than 95% removal efficiency, more than 0.625 g of strong acid resin was necessary in each of 3 experiments. There was an unexpected problem that a lot of strong acid resin waste was produced which amounts to 9.2% (volume) of the contaminated soil.

• Korean Journal of Soil Science and Fertilizer
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• v.10 no.2
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• pp.79-84
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• 1977

In order to confirm the effect of potash top dressing and to observe the effect of N, K compound fertilizers, 17-0-17, 17-0-14, and 15-0-20, specially prepared for top dressing to rice, a field experiment with rice (Oryza Sativa L., Akibare) was conducted in a poorly drained paddy field in comparison with potassium chloride. The results obtained are as follows, 1. The effect of potash top dressing to rice was so remarkable that the yield from the plots of split application of muliate potassium or compound fertilizer was significantly higher than that from the plot received no potash at all. In contrast, the plots received all the amount of potash as one dose at transplanting time showed no significant increase in yield compared with that of potash plot. 2, The effect of N, K compound fertilizer, granulated to about the size of a small bean appeared to be so slow that it gave little increase of yield when it was appiled as a top dressing at the primodial stage, but it gave an increase of yield when it was top dressed at effective tillering stage. 3, Granular N, K compound fertilizer to be top dressed at primodial stage might be prepared in small size so that the fertilizer readily go into solution when it was applied, otherwise the fertilizer should be applied eariler than the primodial stage.

• Korean Journal of Soil Science and Fertilizer
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• v.35 no.6
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• pp.344-351
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• 2002

Chemical speciation and transport of heavy metals in soil environment could be controlled by humic acid. In order to understand the mechanism on competitive adsorption of Cd and Cu on the surface of humic acid extracted from peat, the charge development of humic acid were investigate through a batch adsorption experiment with a series of different background electrolytes levels. The competitive adsorption of Cd and Cu to the humic acid were estimated according to the model using the proton binding constant obtained from the above batch test. The affinity of Cu to the carboxyl group on the humic acid was higher than that of Cd, but the affinity to the phenolic group was lower than to the carboxyl group. It seems that the amount of adsorbed Cd and Cu could be estimated using the proton binding constant obtained from a solution with single background ion. However, it is difficult to interpret the competitive adsorption of Cd and Cu with the constant for single background ion.

• Journal of Korean Society of Transportation
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• v.28 no.5
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• pp.55-64
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• 2010

In order to prepare an efficient solution for PM10 reduction in underground stations, the authors measured PM10 concentration levels every 30 minutes in the concourse, platform, and tunnel of Gaehwasan Station of Seoul's subway line 5. Through a correlation analysis of each changing pattern of PM10 concentration, the direction and velocity of diffusion in underground stations were estimated. The PM10 concentration levels were highest in the tunnel, followed by the platform and concourse. PM10 concentrations in the tunnel, platform, and concourse showed a pattern of increasing in the rush hours and decreasing in the non-rush hours. According to the statistical analysis of PM10 concentrations and changing patterns in each location, the higher PM10 concentration in the tunnel expanded to the platform, and some from the platform expanded to the concourse. Therefore, to efficiently reduce PM10 concentrations, it is essential to detect the centralized generation, diffusion factor, expanding route, expanding measure, and other variables and to remove or reduce the diffusion factor and level. Through operating the ventilation system in the right time frame while the PM10 concentration level increases, the power consumption and peak power consumption can be reduced.