• Title/Summary/Keyword: high-temperature shift

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Investigation of Zooplankton Communities in Streams in Northern Gyeonggi-do Province (경기북부 주요 하천 내 동물플랑크톤 군집특성 조사 연구)

  • Go, Soon-Mi;Im, Heung-Bin;Jung, Eun-Hee;Kim, Tae-Yuel;Kim, Jae-Kwang;Choi, Jeong-In;Lee, Ho-Jung;Oh, Jo-Gyo
    • Journal of Environmental Health Sciences
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    • v.45 no.5
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    • pp.426-433
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    • 2019
  • Objectives: Zooplankton communities play important roles in aquatic ecosystems as secondary producers that graze on phytoplankton and in turn are preyed upon by planktivorous and juvenile fish. They can shift their distribution, species composition, and abundance in response to environmental changes. Therefore zooplankton communities are important for understanding the energy flow in aquatic ecosystems and can be valuable indicators of environmental conditions. However, zooplankton in streams are still not well-studied, especially in northern Gyeonggi-do Province. This study aims to investigate the zooplankton communities in major streams in northern Gyeonggi-do Province. Methods: Zooplankton is important in the nutrient cycle and energy flow of aquatic ecosystems. Therefore, we surveyed zooplankton and measured temperature, DO, BOD, COD, T-N, T-P, and Chl-a in major streams (Sincheon, Gongneungcheon, Wangsukcheon, and Gapyeongcheon Streams) and stagnant water (Gomoji Reservoir). Results: The water quality in Gapyeongcheon Stream was the highest grade, while that of Gomoji Reservoir was mesoeutrophic and eutrophic during the research period. In the zooplankton community, Nauplius, Rotaria, and Monostyla spp. were dominant in Sincheon, Gongneungcheon, and Wangsukcheon Streams, and the dominance index was also high. In the case of Gapyeongcheon Stream, it was found that water quality and aquatic ecosystem health were good, and the lowest dominance index reflected this. In Gomoji Reservoir, Polyarthra spp., Nauplius, and Bosmina longirostris, which can be easily observed as eutrophication progresses, showed a high dominance rate. Therefore, it is necessary to monitor the progress of eutrophication in further research. Conclusions: We collected data on the zooplankton communities in streams and investigated their characteristics. As a result, specific species were found to be dominant at each survey sites and some of them are known to be observed as eutrophication progresses. Therefore, we should investigate the zooplankton community of streams around us and apply ecological stream management.

Athermalization and Narcissus Analysis of Mid-IR Dual-FOV IR Optics (이중 시야 중적외선 광학계 비열화·나르시서스 분석)

  • Jeong, Do Hwan;Lee, Jun Ho;Jeong, Ho;Ok, Chang Min;Park, Hyun-Woo
    • Korean Journal of Optics and Photonics
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    • v.29 no.3
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    • pp.110-118
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    • 2018
  • We have designed a mid-infrared optical system for an airborne electro-optical targeting system. The mid-IR optical system is a dual-field-of-view (FOV) optics for an airborne electro-optical targeting system. The optics consists of a beam-reducer, a zoom lens group, a relay lens group, a cold stop conjugation optics, and an IR detector. The IR detector is an f/5.3 cooled detector with a resolution of $1280{\times}1024$ square pixels, with a pixel size of $15{\times}15{\mu}m$. The optics provides two stepwise FOVs ($1.50^{\circ}{\times}1.20^{\circ}$ and $5.40^{\circ}{\times}4.23^{\circ}$) by the insertion of two lenses into the zoom lens group. The IR optical system was designed in such a way that the working f-number (f/5.3) of the cold stop internally provided by the IR detector is maintained over the entire FOV when changing the zoom. We performed two analyses to investigate thermal effects on the image quality: athermalization analysis and Narcissus analysis. Athermalization analysis investigated the image focus shift and residual high-order wavefront aberrations as the working temperature changes from $-55^{\circ}C$ to $50^{\circ}C$. We first identified the best compensator for the thermal focus drift, using the Zernike polynomial decomposition method. With the selected compensator, the optics was shown to maintain the on-axis MTF at the Nyquist frequency of the detector over 10%, throughout the temperature range. Narcissus analysis investigated the existence of the thermal ghost images of the cold detector formed by the optics itself, which is quantified by the Narcissus Induced Temperature Difference (NITD). The reported design was shown to have an NITD of less than $1.5^{\circ}C$.

Local Environments of Li in the Interlayer of Clay Minerals at Room and High Temperatures (상온 및 고온에서 점토광물 층간의 Li 환경)

  • Kim, Yeong-Kyoo;Lee, Ji-Eun
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.3
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    • pp.193-201
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    • 2007
  • We used $^6Li$ and $^7Li$ MAS NMR to investigate the fate and local environments of Li in the interlayer of clay minerals such as hectorite, Woming-montmorillonite, beidellite, and lepidollite at room and high ($250^{\circ}C$) temperature. Although $^6Li$ NMR spectra show narrower peaks than those of $^7Li$ NMR, S/N ratio is low and there are no obvious differences in chemical shifts suggesting that it is difficult to apply $^6Li$ NMR to have information on the local environments of Li in the clay interlayers. $^7Li$ NMR spectra, however, show changes in the peak width and quadrupole patterns providing information on the local environments of Li in the interlayer even though changes in the chemical shift are not observed. In montmorillonite, two different local environments of Li are observed; one has a narrow peak with typical quadrupole patterns whereas another has a broad peak without those of the patterns. Changes in the peak width is also observed from broad to narrow in the $^7Li$ NMR spectra for beidellite but not for hectorite at high temperature. Our results suggest that the peak width change in the broad peak is attributed to the coordination changes in the water molecules around Li which is tightly bonded on the basal oxygen of Si tetrahedra as inner-sphere complexes. The narrow peak in montmorillnoite can be assigned to the Li bended as outer-sphere complexes.

Functional Analysis of Gene ID1103135 Encoding a 3-Phytase Precursor Homologue of Streptomyces coelicolor (Streptomyces coelicolor의 3-Phytase 상동성 유전자 ID1103135의 기능분석)

  • 김미순;강대경;이홍섭;연승우;김태영;홍순광
    • Korean Journal of Microbiology
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    • v.40 no.2
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    • pp.81-86
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    • 2004
  • Among the annotated ORFs of Streptomyces coelicolor, SCO7697 was supposed to encode for phytase (myo-inositol hexakisphosphate phosphohydrolase). The DNA fragment containing SCO7697 was cloned by the PCR from the chromosomal DNA of S.coelicolor A3(2)M. The cloned fragment was introduced into E. coli expres-sion vector, pET28a(+), to yield two recombinant plasmids, pET28-SP and pET28-LP, which were designed to encode different length of proteins. When the pET28-SP and pET28-LP were introduced into E. coli BL21, the transformants successfully overexpressed recombinant proteins, but the molecular weights of the expressed pro-teins were appeared bigger than those of expected in SDS-polyacrylamide gel electrophoresis. The shift of cul-tural temperature from 37 to $30^{\circ}C$ made most of expressed protein be solubilized. The expressed protein, however, did not show any phytase activity. When the DNA fragment with its own promoter placed on the E. coli-Streptomyces vector, pWHM3, and introduced into S. lividans, the phytase activity was not detected either. These results suggest that even though the SCO7697 was annotated as a probable phytase with high probability (E value is $6e^{-89}$), the real product doest not have phytase activity.

Characterization of Sericite Occurred in the Bobae Mine, Pusan, Korea (부산 보배광산산 견운모의 광물학적 특성)

  • Moon, Ji-Won;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.29 no.2
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    • pp.129-138
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    • 1996
  • The ores of the Bobae mine are mainly composed of sericite and quartz, and with appreciable amount of some other minerals such as andalusite. pyrophyllite, and albite, etc.. Sericite occurs in various a1teration zones having different crystal size and habit. Sericites can be c1assified into two types based on the crystal size; fine-grained and coarse-grained sericite. Fine-grained sericite occurs as an aggregate. Mineralogical characterizations of both types of sericites have been studied with various methods. Lattice parameters of two types of sericites occurred in various alteration zones are almost identical. but b parameter of coarse-grained sericite appears to be slight1y bigger than that of fine-grained aggregates. Average structural formula of fine- and coarse-grained sericite is $K_{1.44}Al_{3.86}(Si_{6.35}Al_{1.65})O_{20}(OH)_4$ and $K_{1.71}Al_{3.82}(Si_{6.20}Al_{1.80})O_{20}(OH)_4$, respectively. Structural formulae of coarse-grained sericites are close to that of muscovite. Infrared spectra show that there is slight distinction between sericites occurred in andalusite-pyrophyllite zone and other subzones. IR spectra of sericites due to Si-O vibration ($540{\sim}530cm^{-1}$) tend to shift to smaller wavenumber side from center to outer alteration zone. All samples have litt1e or no interstratified minerals. and this is demonstrated by Ir and DTA-TG results. It indicates that the Bobae mine is formed at relatively high temperature. That the ratio of quartz to sericite in ores varies greatly indicates that several discontinuous hydrothermal alteration processes have been involved.

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Difference of the Chemical Compositions Between Petroleum Ether Extract and its Tall Oil in Pitch Pine, Pinus Rigida Mill (리기다소나무재(材)의 유기용매(有機溶媒) 추출물(抽出物)과 그 tall oil 간의 조성(組成)의 차이(差異))

  • Ko, Sang-Woon;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.2
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    • pp.79-89
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    • 1988
  • This experiment was carried out to investigate the difference of compositions between petroleum ether extract and its tall oil in Pinus rigida Mill. xylem and to obtain the basic data on effective extraction and its utilization of by-product, resin and fatty acid, when pulp making. After both petroleum ether extract from wood meal and its tall oil in pitch pine were separated to the resin and fatty acid by using DEAE-Sephadex and aluminum oxide column, these were analyzed with gas chromatograph. The results obtained were as follows: 1. Fatty acids contained as ester form in living trees were varied by peroxide of organic solvent in petroleum ehter extraction and cooking chemicals in cooking. 2. Pimaric-type acid was eluted earlier than abietic-type acid in resin acids and the fewer the carbons, the earlier the elution in fatty acids. 3. The retention time of SE-30 column was even smaller than that of OV-101 column but the relative retention time obtained by using methyl pimarate and methyl stearate as internal standard was nearly identical. 4. Both petroleum ether extract and tall oil mainly consisted of resin acids, expecially abietic-type acid. 5. Tall oil had more fatty acid but less resin acid than petroleum ether extract. Also, the content of unidentified materials was increased owing to the isomerization and the shift of double bond position in unsaturated fatty acids by high temperature and cooking chemicals when cooking.

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Cultivation status and breed development of Lentinula edodes cultivar Sanjo 701ho in the sawdust cultivation (표고 톱밥재배용 산조 701호의 품종육성 및 재배현황)

  • Noh, Jong-Hyun;Kim, Kyung-Jin;Lee, Byung-Seok;Kim, Seon-Cheol;Kim, In-Yeop;Choi, Sun-Gyu;Kwon, Hyuk-Woo;Lee, Won-Ho;Joung, Eui-Young;Chung, Nam-Hun;Ko, Han-Gyu
    • Journal of Mushroom
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    • v.18 no.3
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    • pp.179-188
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    • 2020
  • The oak mushroom (Lentinula edodes) is a popular edible mushroom that has long been cultivated and eaten throughout Northeast Asia (including Korea). Its taste and flavor are unique. Oak mushrooms are cultivated on logs and in sawdust. The cultivation period on logs is 4-5 years, while the cultivation period in sawdust is 6 months, which is rapidly driving a shift from log to sawdust based cultivation. In particular, the Sanjo 701ho cultivar of L. edodes is a mid-range to high-temperature variety that is widely known for its suitability for summer cultivation on sawdust in Korea. This study summarizes new developments and achievements in the oak mushroom industry in Korea, and details the cultivation history of Sanjo 701ho, its culturing characteristics, various demonstration tests, and the expansion of domestic varieties.

Control of Graphene's Electrical Properties by Chemical Doping Methods

  • Lee, Seung-Hwan;Choi, Min-Sup;La, Chang-Ho;Yoo, Won-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.119-119
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    • 2011
  • This study examined the synthesis of large area graphene and the change of its characteristics depending on the ratio of CH4/H2 by using the thermal CVD methods and performed the experiments to control the electron-hole conduction and Dirac-point of graphene by using chemical doping methods. Firstly, with regard to the characteristics of the large area graphene depending on the ratio of CH4/H2, hydrophobic characteristics of the graphene changed to hydrophilic characteristics as the ratio of CH4/H2 reduces. The angle of contact also increased to 78$^{\circ}$ from 58$^{\circ}$. According to the results of Raman spectroscopy showing the degree of defect, the ratio of I(D)/I(G) increases to 0.42% from 0.25% and the surface resistance also increased to 950 ${\Omega}$ from 750 ${\Omega}$/sq. As for the graphene synthesis at the high temperature of 1,000$^{\circ}$ by using CH4/H2 in a Cu-Foil, the possibility of graphene formation was determined as a function of the ratio of H2 included in the fixed quantity of CH4 as per specifications of every equipment. It was observed that the excessive amount of H2 prevented graphene from forming, as extra H-atoms and molecules activated the reaction to C-bond of graphene. Secondly, in the experiment for the electron-hole conduction and the Dirac-point of graphene using the chemical doping method, the shift of Dirac-point and the change in the electron-hole conduction were observed for both the N-type (PEI) and the P-type (Diazonium) dopings. The ID-VG results show that, for the N-type (PEI) doped graphene, Dirac-point shifted to the left (-voltage direction) by 90V at an hour and by 130 V at 2 hours respectively, compared to the pristine graphene. Carrier mobility was also reduced by 1,600 cm2/Vs (1 hour) and 1,100 cm2/Vs (2 hours), compared to the maximum hole mobility of the pristine graphene.

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Petrochemistry of the Soyeonpyeong titaniferous iron ore deposits, South Korea (소연평도 함티타늄 자철광상의 암석지구화학적 연구)

  • Kim, Kyu Han;Lee, Jung Eun
    • Economic and Environmental Geology
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    • v.27 no.4
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    • pp.345-361
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    • 1994
  • Lens shaped titanomagnetite ore bodies in the Soyeonpyeong iron mine are embedded in amphibolites, which were intruded into Precambrian metasediments such as garnet-mica schist, marble, mica schist, and quartz schist. Mineral chemistry, K-Ar dating and hydrogen and oxygen stable isotopic analysis for the amphibolites and titanomagnetite ores were conducted to interpret petrogenesis of amphibolite and ore genesis of titanomagnetite iron ore deposits. Amphibolites of igneous origin have unusually high content of $TiO_2$, ranging from 0.94 to 6.39 wt.% with an average value of 4.05 wt.%. REE patterns of the different lithology of the amphibolite show the similar trend with an enrichment of LREE. Amphiboles of amphibolites are consist mainly of calcic amphiboles such as ferro-hornblende, tschermakite, ferroan pargasite, and ferroan pargasitic hornblende. K-Ar ages of hornblende from amphibolite and gneissic amphibolite were determined as $440.04{\pm}6.39Ma$ and $351.03{\pm}5.21Ma$, respectively. This indicates two metamorphic events of Paleozoic age in the Korean peninsula which are correlated with Altin orogeny in China. The titanomagnetite mineralization seems to have occurred before Cambrian age based on occurrence of orebodies and ages of host amphibolites. The Soyeonpyeong iron ores are composed mainly of titanomagnetite, ilmenite, and secondary minerals such as ilmenite and hercynite exsolved in titanomagnetite. The temperature and the oxygen fugacity estimated by the titanomagnetite-ilmenite geothermometer are $500{\sim}600^{\circ}C$ (ave. $550^{\circ}C$) and about $2{\pm}10^{-23}bar$, respectively. Hornblendes from ores and amphibolites which responsible for magnetite ore mineralization, have a relatively homogeneous isotopic composition ranging from +0.8 to +3.9 ‰ in ${\delta}^{18}O$ and from -87.8 to -113.3 ‰ in ${\delta}D$. The calculated oxygen and hydrogen isotopic compositions of the fluids which were in equilibrium with hornblende at $550^{\circ}C$, range from 2.8 to 5.9‰ in ${\delta}^{18}O_{H2O}$ and from -60.41 to -81.31 ‰ in ${\delta}D_{H2O}$. The ${\delta}^{18}O_{H2O}$ value of magnetite ore fluids are in between +6.4 to + 7.9 ‰. All of these values fall in the range of primary magmatic water. A slight oxygen shift means that $^{18}O$-depleted meteoric water be acted with basic fluids during immiscible processes between silicate and titaniferous oxide melt. Mineral chemistry, isotopic compositions, and occurences of amphibolites and orebodies, suggest that the titanomagnetite melt be separated immisciblely from the titaniferous basic magma.

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Mössbauer Studies of Changed Interaction on Cr Ions in Chromite (Chromite 물질의 자기상호작용에 관한 뫼스바우어 분광연구)

  • Choi, Kang-Ryong;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.17 no.1
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    • pp.47-50
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    • 2007
  • [ $ZnCr_2O_4$ ] shows geometrically frustrated magnet. Recently, $CoCr_2O_4$ has been investigated for multiferroic property and dielectric anomalies by spin-current model. Polycrystalline $CoCr_2O_4$ and $CoCrFeO_4$ compounds was prepared by wet-chemical process. Crystallographic and magnetic properties of $CoCr_2O_4$ and $CoCrFeO_4$ were investigate by using the x-ray diffractometer(XRD), vibrating sample magnetometer(VSM), superconducting quantum interference device magnetometer(SQUID), and $M\"{o}ssbauer$ spectroscopy. The crystal structure was found to be single-phase cubic spinel with space group of Fd3m. The lattice constants of $CoCr_2O_4$ and $CoCrFeO_4$ $a_0$ were determined to be 8.340 and 8.377 ${\AA}$, respectively. The ferrimagnetic transition temperature for the both samples were observed at 97 K and 320 K. The $M\"{o}ssbauer$ absorption spectra at 4.2 K show that the well developed two sextets are superposed with small difference of hyperfine field($H_{hf1}=507\;and\;H_{hf2}=492\;kOe$). Isomer shift values($\delta$) of the two sextets are found to be 0.33 and 0.34 mm/s relative to the Fe metal, respectively, which are consistent with the high spin $Fe^{3+}$ charge state.