• Title/Summary/Keyword: high-temperature high-shear viscosity

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Apparent Viscosity Properties of Electro-Rheological Fluid by Using Rotational Viscometer (회전식 점도계를 이용한 ERF의 겉보기 점도 특성)

  • 장성철;이진우;김태형;박종근
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.196-201
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    • 2001
  • Electro-Rheological(ER) fluids change their apparent viscosity according to the electric field strength. Therefore, there are many practical applications using the ER fluids. ER effect on the dispersive system of polarizable fine powder/dielectric oil has been investigated. The electrical and rheological properties of starch based ER fluid were reported. Yield stress of the fluids were measured on the couette cell type rheometer as a function of electric fields, particle concetrations, and temperatures. The electric field is applied by high voltage DC power supply, The outer cup is connected to positive electrode(+) and the bob becomes ground(-). And the temperatures the viscosity(or shear stress) versus shear rates were measured. In this experiment shear rates were increased from 0 to 200s$^{-1}$ in 2 minutes. This thesis presents Bingham properties of ER fluids subjected to temperature variations. The temperature dependence of the viscosity was determined for ER fluids consisting of 35 weight % starch particles in automatic transmission oil.

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The Influence of Engine Operating Conditions and Lubricants on Oil Film Thickness of Engine Connecting Rod Bearing (커넥팅로드 베어링의 유막두께에 미치는 기관 운전조건 및 윤활유의 영향)

  • Lee, D.H.;Chang, B.J.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.5
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    • pp.1-10
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    • 1994
  • By applying of total electric capacitance method on engine connecting rod bearing during engine operating, the influence of engine operating conditions and lubricants on bearing oil film thickness was investigated. Minimum oil film thickness increases with kinematic viscosity, but as increasing of viscosity, the increasing ratio of film thickness is reduced. Also minimum oil film thickness increases with engine speed but there is a limit. Above this limit, film thickness decreases in opposition because of crankshaft inertia. As increasing of engine torque and oil temperature, munimum oil film thickness decreases linearly. For non-Newtonian oils, the correlation between $100{\circ}C$ kinematic viscosity and munimum oil film thickness is very poor.

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Effects of Temperature and Concentration on the Rheological Properties of the Biopolymer Produced by Bacillus sp. K-1 Strain and Mutants (Bacillus sp. K-1과 변이주들에 의해 생산된 Biopolymer의 물성에 미치는 온도 및 농도의 영향)

  • Jeong, Nak-Hyeon;Yun, Gwang-Seop;Im, Mu-Hyeon
    • Food Science and Preservation
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    • v.4 no.3
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    • pp.343-349
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    • 1997
  • The rheological Voperties of biopolymers produced by Bacilli sp. K-1 and its mutant strains(KM-21, KM-83) were studied at the temperature ranges with 20∼80$^{\circ}C$, at the concenration of 2∼6%, at the pH ranges from 3.0 to 9.0 and at the shear rate of 9.3-930sec-1 The apparent viscosity of biopolymers was decreased with increasing shear rate, and thereby biopolymers showed pseudoplastic characteristics. It was found that the apparent viscosity models respected 19 temperature, concentration and both temperature and concentration were expressed by Arrhenius Model, Exponential Model and combined of the above two Models. Therefore, the apparent viscosity could be predictable by Arrhenius and Exponential Models with high R2.

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Rheological Behavior of Semi-Solid Ointment Base (Vaseline) in Steady Shear Flow Fields (정상전단유동장에서 반고형 연고기제(바셀린)의 레올로지 거동)

  • Song, Ki-Won;Kim, Yoon-Jeong;Lee, Chi-Ho
    • Journal of Pharmaceutical Investigation
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    • v.37 no.3
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    • pp.137-148
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    • 2007
  • Using a strain-controlled rheometer [Rheometrics Dynamic Analyzer (RDA II)], the steady shear flow properties of a semi-solid ointment base (vaseline) have been measured over a wide range of shear rates at temperature range of $25{\sim}60^{\circ}C$. In this article, the steady shear flow properties (shear stress, steady shear viscosity and yield stress) were reported from the experimentally obtained data and the effects of shear rate as well as temperature on these properties were discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters (yield stress, consistency index and flow behavior index). Main findings obtained from this study can be summarized as follows : (1) At temperature range lower than $40^{\circ}C$, vaseline is regarded as a viscoplastic material having a finite magnitude of yield stress and its flow behavior beyond a yield stress shows a shear-thinning (or pseudo-plastic) feature, indicating a decrease in steady shear viscosity as an increase in shear rate. At this temperature range, the flow curve of vaseline has two inflection points and the first inflection point occurring at relatively lower shear rate corresponds to a static yield stress. The static yield stress of vaseline is decreased with increasing temperature and takes place at a lower shear rate, due to a progressive breakdown of three dimensional network structure. (2) At temperature range higher than $45^{\circ}C$, vaseline becomes a viscous liquid with no yield stress and its flow character exhibits a Newtonian behavior, demonstrating a constant steady shear viscosity regardless of an increase in shear rate. With increasing temperature, vaseline begins to show a Newtonian behavior at a lower shear rate range, indicating that the microcrystalline structure is completely destroyed due to a synergic effect of high temperature and shear deformation. (3) Over a whole range of temperatures tested, the Herschel-Bulkley, Mizrahi-Berk, and Heinz-Casson models are all applicable and have an almostly equivalent ability to quantitatively describe the steady shear flow behavior of vaseline, whereas the Bingham, Casson,and Vocadlo models do not give a good ability.

Rheological Characterization of Hydrogen Peroxide Gel Propellant

  • Jyoti, B.V.S.;Baek, Seung Wook
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.2
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    • pp.199-204
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    • 2014
  • An experimental investigation on the rheological behavior of gelled hydrogen peroxide at different ambient temperature (283.15, 293.15 and 303.15 K) was carried out in this study. The gel propellant was rheologically characterized using a rheometer, in the shear rate ranges of 1 to $20s^{-1}$, and 1 to $1000s^{-1}$. Hydrogen peroxide gel was found to be thixotropic in nature. The apparent viscosity value with some yield stress (in-case of shear rate 1 to $20s^{-1}$) drastically fell with the shear rate. In the case of the shear rate range of 1 to $20s^{-1}$, the apparent viscosity and yield stress of gel were significantly reduced at higher ambient temperatures. In the case of the shear rate range of 1 to $1000s^{-1}$, no significant effect of varying the ambient temperature on the gel apparent viscosity was observed. The up and down shear rate curves for hydrogen peroxide gel formed a hysteresis loop that showed no significant change with variation in temperature for both the 1 to $20s^{-1}$ and the 1 to $1000s^{-1}$ shear rate ranges. No significant change in the thixotropic index of gel was observed for different ambient temperatures, for both low and high shear rates. The gel in the 1 to $20s^{-1}$ shear rate range did not lead to a complete breakdown of gel structure, in comparison to that in the 1 to $1000s^{-1}$ shear rate range.

Rheological Properties of Hot Pepper-soybean Pastes Mixed with Acetylated Starches

  • Choi, Su-Jin;Chang, Hak-Gil;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.17 no.4
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    • pp.780-786
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    • 2008
  • Effect of acetylated starches (acetylated rice starch and acetylated tapioca starch) on rheological properties of hot pepper-soybean paste (HPSP) at different mixing ratios of rice flour (RF) and acetylated starch (AS) (10/0, 9/1, 8/2, and 7/3) was evaluated in steady and dynamic shear. All HPSP samples at $25^{\circ}C$ exhibited shear-thinning (n=0.31-0.36) and thixotropic behavior with high yield stresses and their steady flow curves were well described by power law and Casson models. The presence of AS resulted in the decrease in consistency index (K), apparent viscosity (${\eta}_{a,100}$), and yield stress (${\sigma}_{oc}$), and their predominant decreases were noticed at higher ratio of RF to AS (7/3 ratio). Arrhenius temperature relationship represents variation with temperature in the range of $5-35^{\circ}C$ with the high determination coefficients ($R^2=0.97-0.99$). Dynamic moduli (G', G", and ${\eta}^*$) values of HPSP samples mixed with AS were lower than those of HPSP with no added AS within the experimental range of frequency (0.63-62.8 rad/sec). Steady and dynamic shear rheological properties of HPSP samples seem to be greatly influenced by the presence of acetylated starch.

Effect of Chemical Composition, Molecular Weight, Carbon Black Concentration and Temperature on the Flow Behavior of Styrene/Butyl Methacrylate Homo- and Co-polymer Particles (화학적 구성, 분자량, 카본블랙의 농도 및 온도에 따른 스티렌/부틸메타크릴레이트 단일중합체 및 공중합체 입자의 유동성)

  • Park, Moon-Soo;Moon, Ji-Yeon
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.23-29
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    • 2011
  • We measured shear viscosity of polymeric particles, prepared by suspension polymerization with hydrophobic silica as a stabilizer at $75^{\circ}C$, by a capillary rheometer. Shear viscosity displayed a non-Newtonian behavior with an increase in weight average molecular weight. Measurement of shear viscosity at 170 and $190^{\circ}C$ with copoly(styrene/butyl methacrylate) (co-PSB) particles by varying the ratio between styrene (St) and butyl methacrylate (BMA) showed that shear viscosity was a function of molecular weight, temperature and compositional ratio. When the ratio was 7/3, 5/5 and 3/7, shear viscosity slightly reduced with an increase in BMA concentration despite similar weight average molecular weights. We found that shear viscosity of copolymers with BMA concentrations exceeding 70% displayed a sharp reduction at high shear rates. It is speculated that increased PBMA chain length contributes to enhanced flowability of copolymers. When carbon black was incorporated into co-PSB, shear viscosity progressively increased with increasing carbon black concentration. The increase in shear viscosity, however, was less pronounced compared to the cases of molecular weight increase.

Comparison of the Viscosity of Ceramic Slurries using a Rotational Rheometer and a Vibrational Viscometer (회전형 레오미터와 진동형 점도계를 이용한 세라믹 슬러리의 점도 비교)

  • Ji, Hye;Lim, Hyung Mi;Chang, Young-Wook;Lee, Heesoo
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.542-548
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    • 2012
  • The viscosity of a ceramic slurry depends on the slurry concentration, particle shape and size, hydrodynamic interactions, temperature, shear rate, pre-treatment condition and the method of measurement with the selected equipment. Representative ceramic slurries with low to high viscosity levels are selected from colloidal silica, barium titanate slurry and glass frit paste. Rotational rheometers and vibrational viscometers are used to compare the measured viscosity for various ceramic slurries. The rotational rheometer measured the viscosity according to the change of the shear rate or the rotational speed. On the other hand, the vibrational viscometer measured one point of the viscosity in a fixed vibrational mode. The rotational rheometer allows the measurement of the viscosity of a ceramic paste with a viscosity higher than 100,000 cP, while the vibrational viscometer provides an easy and quick method to measure the viscosity without deformation of the ceramic slurry due to the measurement method. It is necessary to select suitable equipment with which to measure the viscosity depending on the purpose of the measurement.

Rheological behavior study of Marine Lubricating oil on the amount of MGO (Marine Gas Oil) dilution (해상용 경유의 희석량에 따른 선박용 윤활유의 유변학적 거동연구)

  • Song, In Chul;Lee, Young Ho;Yeo, Young Hwa;Ahn, Su Hyun;Kim, Dae il
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.2
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    • pp.240-245
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    • 2016
  • This paper describes the rheological behavior study such as viscosity and change of shear stress regarding marine lubricating oil according to the amount of Marine Gas Oil (MGO) dilution. The viscosity reduction due to fuel dilution is crucially important characteristic to decreasing engine durability because of the abrasion of piston ring or liner. The lubricating oil used in this paper was blended with magnetic stirrer diluted High Sulfur Diesel (HSD, 0.05 wt%) ratio of 3 %, 6 %, 10 %, 15 % and 20 %. The viscosity and shear stress of diluted lubricating oil were measured with the temperature range from $-10^{\circ}C$ to $80^{\circ}C$ using a rotary viscometer (Brookfield Viscometer). As the amount of MGO dilution increasing in lubricating oil, the viscosity and stress of those decreased, because the lubricating oil diluted MGO with low viscosity show the trends to decreased viscosity and shear stress. Especially, the viscosity and shear stress of lubricating oil radically decreased at low temperature ($0{\sim}-10^{\circ}C$) and doesn't effect in MGO dilution at over $40^{\circ}C$. As temperature risen, the reduction of the viscosity and shear stress in lubricating oil shows the Newtonian behavior. The lubricating oil was required to check up periodically to improve engine durability since the viscosity reduction by MGO dilution accelerating the engine abrasion.

A Fundamental Study on Bingham Characteristics of Electro-Rheological Fluids for Control System Application (제어 시스템 적용을 위한 ER유체의 빙햄 특성에 관한 기초적 연구)

  • Jang, Sung-Cheol;Jeong, Young-Bin;Jang, Gil-Sik
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.3 no.3
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    • pp.86-92
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    • 2004
  • This paper describes the properties of temperature-viscosity characteristics of hydrous and anhydrous electro-rheological fluids containing starch and titanium particle in silicone oil ER effects arise from electrostatic forces between the starch particles and titanium particles dispersed to the electrically insulating silicone oil induced when electric field is applied ER fluids under electric field control have been found to provide resonable estimates of ER fluid viscosity variation characteristics. Yield shear stress of the ER fluids were measured the couette cell type rheometer as a function of electrlc fields. The outer cup is connected to positive electrode(+) and bob becomes ground(-). The electrie field is applied by high voltage DC power supply. In this experiment shear rates were increased from 0 to 200 $s^{-1}$ in 2 minutes. The ER fluid's viscosity change is very small and stable at the temperature range of $40^{\circ}C$ to $60^{\circ}C$. Therefore, applications of a new ER fluid to control systems application are suitable.

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