• Title/Summary/Keyword: high temperature retention time

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Degradation kinetics of vitamins in premixes for pig: effects of choline, high concentrations of copper and zinc, and storage time

  • Yang, Pan;Wang, Hua Kai;Zhu, Min;Li, Long Xian;Ma, Yong Xi
    • Animal Bioscience
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    • v.34 no.4
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    • pp.701-713
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    • 2021
  • Objective: The present work was undertaken to evaluate the effects of storage time, choline chloride, and high concentrations of Cu and Zn on the kinetic behavior of vitamin degradation during storage in two vitamin premixes and four vitamin-trace mineral (VTM) premixes. Methods: Two vitamin premixes (with or without 160,000 mg/kg of choline) were stored at 25℃ and 60% humidity. Besides, four VTM premixes were used to evaluate the effects of choline (0 vs 40,000 mg/kg) and trace minerals (low CuSO4+ZnO vs high CuSO4+ZnO) on vitamin stability in VTM premixes stored in room, and the VTM premixes were stored in room temperature at 22℃. Subsamples from each vitamin and VTM premix were collected at 0, 1, 2, 3, 6, and 12 months. The retention of vitamin A (VA), vitamin D3 (VD3), vitamin E (VE), vitamin K3 (VK3), vitamin B1 (VB1), vitamin B2 (VB2), vitamin B3 (VB3), vitamin B5 (VB5), and vitamin B6 (VB6) in vitamin premixes and VTM premixes during storage was determined. The stability of vitamins in vitamin premixes and VTM premixes was determined and reported as the residual vitamin activity (% of initial) at each sampling point. Results: The effect of choline on VK3 retention was significant in vitamin premixes (p<0.05). The negative effect of storage time was significant for the retentions of VD3, VK3, VB1, VB2, VB5, and VB6 in vitamin premix (p<0.05). For VTM premixes, negative effect of storage time was significant (p<0.05) for the losses of vitamin in VTM premixes. Choline and high concentrations of Cu and Zn significantly increased VA, VK3, VB1, and VB2 loss during storage (p<0.05). The supplementation of high concentrations of Cu and Zn significantly decreased the concentrations of VD3 and VB6 (p<0.05) in VTM premixes at extended storage time. Conclusion: The maximum vitamin stability was detected in vitamin and VTM premixes containing no choline or excess Cu and Zn. The results indicated that extended storage time increased degradation of vitamin in vitamin or VTM premixes. These results may provide useful information for vitamin and VTM premixes to improve the knowledge of vitamin in terms of its stability.

Structural assessment of reactor pressure vessel under multi-layered corium formation conditions

  • Kim, Tae Hyun;Kim, Seung Hyun;Chang, Yoon-Suk
    • Nuclear Engineering and Technology
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    • v.47 no.3
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    • pp.351-361
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    • 2015
  • External reactor vessel cooling (ERVC) for in-vessel retention (IVR) has been considered one of the most useful strategies to mitigate severe accidents. However, reliability of this common idea is weakened because many studies were focused on critical heat flux whereas there were diverse uncertainties in structural behaviors as well as thermal-hydraulic phenomena. In the present study, several key factors related to molten corium behaviors and thermal characteristics were examined under multi-layered corium formation conditions. Thereafter, systematic finite element analyses and subsequent damage evaluation with varying parameters were performed on a representative reactor pressure vessel (RPV) to figure out the possibility of high temperature induced failures. From the sensitivity analyses, it was proven that the reactor cavity should be flooded up to the top of the metal layer at least for successful accomplishment of the IVR-ERVC strategy. The thermal flux due to corium formation and the relocation time were also identified as crucial parameters. Moreover, three-layered corium formation conditions led to higher maximum von Mises stress values and consequently shorter creep rupture times as well as higher damage factors of the RPV than those obtained from two-layered conditions.

Simplified HPLC Method for the Determination of Pseudoephedrine Hydrochloride from Allegra D Tablet

  • Park, Moon-Hee;Shin, In-Chul
    • Biomolecules & Therapeutics
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    • v.15 no.2
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    • pp.123-126
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    • 2007
  • A sensitive, simple and highly selective liquid chromatography method of determination for extraction of pseudoephedrine hydrochloride from Allegra D tablet was developed. The chief benefit of the present method is the minimal sample preparation, as the procedure is only filtering through pore syringe filter. Two drugs (pseudoephedrine hydrochloride, fexofenadine) were separated on a C$_{18}$ column and analyzed by high performance liquid chromatography (HPLC). The method had a chromatographic run time of 8.0 min. 1 ml of pseudoephedrine hydrochloride solution (1 mg/ml) was filtered through 0.22 um pore syringe filter. 50 ul of filtering solution was injected to HPLC pump and we knew the retention time (1.85 min) of separating of pseudoephedrine hydrochloride using UV detector at 280 nm. We used C$_{18}$ column (4.6 mm${\times}$250 mm), mobile phase solution (<0.05 mol/L NaH$_2$PO$_4$, 2 ml/L H$_3$PO$_4$>/CH$_3$CN / sodium dodesyl sulfate = 60 ml / 40 ml / 1 g). We separated psedoephedrine hydrochloride at run time of 1.85 min from Allegra D tablet solution (1 mg/ml) filtered through 0.22 um pore syringe filter using UV detector at 280 nm. Flow rate was set at 1.0 ml/min and the column temperature was set at 40$^{\circ}C$. Psedoephedrine hydrochloride solution (1 mg/ml) separated from Allegra D tablet was filtered through 0.22 um pore syringe filter and injected 50 ul. We confirmed the peak of psedoephedrine hydrochloride at same retention time and the separating solution was freeze-dried. In conclusion, A simple isocratic reverse-phase HPLC method has been developed that provides excellent separation of pseudoephedrine from Allegra D tablet.

Characteristics of Nylon 6/Poly(acrylonitrile-co-styrene-co-acrylic rubber) Blends Containing Compatibilizer (상용화제가 포함된 나일론 6/Poly(acrylonitrile-co-styrene-co-acrylic rubber) 블렌드의 특성)

  • Kim, Lang-Wook;Yoo, Sun-Hwa;Kim, Chang-Keun
    • Polymer(Korea)
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    • v.31 no.1
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    • pp.8-13
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    • 2007
  • To overcome drawbacks of the nylon 6/poly (acrylonitrile-co-butadiene-co-styrene) (ABS) blend, nylon 6 blend with poly (acrylonitrile - co-styrene - co-acrylic rubber) (ASA) which containing poly (butyl acrylate) as a rubber phase in substitute of poly (butadiene) in ABS, was examined. Poly (styrene-co-maleic anhydride) (SMA) containing 25 wt% of maleic anhydride (MA) or poly (styrene- co-acrylo-nitrile-co-maleic anhydride) (SANMA) containing less than 3 wt% MA was used as a compatibilizer to fabricate blends having high impact strength. Changes in the mechanical properties of nylon 6/ASA blend with compatibilizer content were similar with those of nylon 6/ABS blend. Blends haying high impact strength was produced when blends contained more than about 20 wt% rubber. Blends containing SAM or SANMA as a compatibilizer were stayed in a injection molding machine at the molding temperature and afterwards specimens for the examination of the impact strength was prepared. Impact strength of blends containing SMA was decreased with retention time, while that of blends containing SANMA was not changed with retention time.

A Study on the Water Gas Shift Reaction of RPF Syngas (RPF(Refuse plastic fuel) 합성가스의 수성가스 전환 반응 연구)

  • Roh, Seon Ah
    • Resources Recycling
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    • v.30 no.6
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    • pp.12-18
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    • 2021
  • The water-gas shift reaction is the subsequent step using steam for hydrogen enrichment and H2/CO ratio-controlled syngas from gasification. In this study, a water-gas shift reaction was performed using syngas from an RPF gasification system. The water-gas shift using a catalyst was performed in a laboratory-scale tube reactor with a high temperature shift (HTS) and a low temperature shift (LTS). The effects of the reaction temperature, steam/carbon ratio, and flow rate on H2 production and CO conversion were investigated. The operating temperature was 250-400℃ for the HTS system and 190-220℃ for the LTS system. Steam/carbon ratios were between 1.5 and 3.5, and the composition of reactant was CO : 40 vol%, H2 : 25 vol%, and CO2 : 25 vol%. The CO conversion and H2 production increased as the reaction temperature and steam/carbon ratio increased. The CO conversion and H2 production decreased as the flow rate increased due to reduced retention time in the catalyst bed.

The Physical Property of PET Coolness Knitted Fabric for High Emotional Garment (고감성 의류용 PET 냉감 니트 소재의 물성)

  • Kim, Hyun Ah;Woo, Ji Yoon;Kim, Seung Jin
    • Textile Coloration and Finishing
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    • v.26 no.2
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    • pp.114-123
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    • 2014
  • This research investigated the physical properties of PET coolness filaments and their knitted fabrics including dyeing characteristics of these knitted fabrics according to the different dyeing time and temperature. The coolness filament(S) with non-circular cross-section and hydrophilic property was spun and another commercialized coolness(A) and regular(R) PET filaments were prepared for comparing coolness and another physical properties. Qmax of coolness knitted fabric made with S filament was higher than that of R-PET filament, and the maximum value of Qmax of S knitted fabric was shown at the dyeing conditions of temperature, $110^{\circ}C$ with 30 min. or 40min. It was shown that hand of S knitted fabric was a little harsh comparing to A and regular knit specimens, but shape retention and wearing performance of garment made with S knit specimen were estimated as good owing to high bending and shear rigidity. K/S of S knitted fabric was higher than those of regular PET and A knit specimens. Dyeing fastness of coolness knitted fabric showed between 4th and 5th grade.

Studies on the Optimal Sterilization Conditions of Red Pepper Paste Packed in Retort Pouch. (레토르트 파우치 고추장의 적정 고온 살균조건에 관한 연구)

  • Lee, Shin-Young;Choi, Kook-Chi;Lee, Sang-Kyu
    • Journal of Industrial Technology
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    • v.3
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    • pp.87-94
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    • 1983
  • Heating characteristics of red pepper paste packed in report pouches of various thicknesses and their storage stability were investigated to determine the adequate processing conditions that good bacteriological safty and minimal quality changes could be obtained, when sterilized by using a steam-air system retort. A heat penetration into pouch-packed red pepper paste was carried out through by a conductive heat transfer, indicating a simple logarithmic heating curve, and the smaller thickness revealed the higher heat penetration rate, suggesting the possibility of high temperature-short time sterilization of red pepper paste. The processing conditions with Fo-value of 4.5 or higher were sufficient for keeping up bacterial safty, but based on C-value, better quality retention was obtained at pouch thickness of 15mm under the processing temperature of $120^{\circ}C$. Subsequent storage study revealed that the red pepper paste packed in 15mm and processed at $120^{\circ}C$ with Fo=4.5 could be held without any spoilage and overall acceptance change, when stored for 6 months at room temperature under the relative humidity of 70%. After 3 months storage in $38^{\circ}C$ under saturation humidity, overall acceptance of red pepper paste were judged not to be maintainable on the acceptable level, but it may be suggested that above the results could be kept up a desirable quality without any remarkable deterioration.

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The Spring Metazooplankton Dynamics in the River-Reservoir Hybrid System (Nakdong River, Korea): Its Role in Controlling the Phytoplankton Biomass (강-저수지 복합형 시스템내 봄 동물플랑크톤의 역동성 (낙동강, 한국): 식물플랑크톤 생체량 조절자로서의 역할)

  • Chang, Kwang-Hyeon;Jeong, Kwang-Seuk;Joo, Gea-Jae;Kim, Hyun-Woo
    • Korean Journal of Ecology and Environment
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    • v.36 no.4 s.105
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    • pp.420-426
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    • 2003
  • During a three-year study (2000-2002), dramatic changes in the phytoplankton biomass and high transparency were repeatedly observed during mid-spring in the lower part of the Nakdong River. Rotifers (Brachionus, Keratella, Polyarthra) , sharply increased toward the middle and end of spring. As hydrologic retention time increased (to near 20 days) and water temperature increased from $10^{\circ}C$ to > $20^{\circ}C$ toward the end of spring, small cladocerans noticeably increased. Once phytoplankton biomass passed their peak stage in the mid-spring, a short period (one or two weeks) of relatively low phytoplankton biomass and high Secchi transparencies occurred. Grazing by the zooplankton was highest in spring, thus, it seems that high grazing activities of zooplankton grazing regulated phytoplankton dynamics in the river. The results indicate that the role of zooplankton grazing in controlling the phytoplankton biomass becomes more important during the spring when river water is relatively stagnant.

Ammonia Removal Characteristics of Biolfilm Reactor (생물막을 이용한 상수 원수에서의 암모니아 제거 특성)

  • Shin, Hang-Sik;Lim, Kycong-Ho;Lee, Sang-Min
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.1
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    • pp.78-84
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    • 1996
  • The presence of ammonia, usually in the form of ammonium ion ($NH_4{^+}$), can enhance bacterial growth m the distribution system and make the production of drinking water more costly if ammonium must be removed to ensure good disinfection. Removal of ammonia by biological oxidation could be economical which prevents excess chlorine dosage In this research, effects of hydraulic retention time (HRT) and media type on the ammonia removal efficiencies of submerged biofilm reactor were investigated. The biofilm reactors combined the characteristics of high biological solids capture efficiency and good hydraulic control. The results indicate that biofilms can remove over 77 percent of the ammonia with HRT of longer than 2 hr even at low temperature ranging from 14.6 to $16.6^{\circ}C$. The HRT has a significant effect on nitrification. The overall nitrification and efficiency of ammonia removal increase with increasing HRT. It has also been observed that when the fibrous media was used, the ammonia removal, nitrification rate and endurance to shock improved.

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Analysis of Sediment Nutrients as Potential Sources of the Lake Water Quality (퇴적물 토양의 영양염류가 호소 수질에 미치는 잠재 요인 분석)

  • Jung, Joon-Oh;Kim, Young-Woo
    • Journal of Environmental Health Sciences
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    • v.35 no.5
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    • pp.376-385
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    • 2009
  • The characteristics of Lake Cheonhoji water and sediment were investigated in oder to utilize these as fundamental materials for the management of lake water quality. The hydrographic properties of Lake Cheonhoji which are relatively low chance of nutrients loading from the watershed and a long retention time of lake water, lead to the probability of high lake productivity. It was also observed that lake water showed stratification during summer and complete mixing during fall, even though water depth was relatively shallow. The trophic state was eutrophic to hypertrophic from summer to late fall. The overall properties of the sediment were oligohumic, high ignition loss and high composition of NAIP and Resid.-P, which might serve as potential pollution sources of lake water quality. In laboratory scale experiments, it was observed that leaching potential of nutrients in the sediment was greatly dependant upon water temperature and dissolved oxygen. Finally, water pollution in Lake Cheonhoji was considered to be largely due to the adverse cycle of uncontrollable eutrophication, which resulted in the subsequent occurrence of dead algae and animal plankton, organic sedimentation, reduction of dissolved oxygen and nutrients leaching, which again reinforced the cycle of eutrophication in the lake.