• Journal of the Korean Wood Science and Technology
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• v.22 no.4
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• pp.37-42
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• 1994

The adsorption of water vapor and equilibrium moisture content(EMC) of the specimens for four softwood species dried by conventional- and high temperature method and equilibrated to 15% of the target EMC condition at 25$^{\circ}C$ were determined by oven drying method and with moisture meters. The amount of adsorption for high temperature dried red pine was significantly higher than that of conventional kiln dried wood, while those of eastern white pine, eastern hemlock and Norway spruce were not significantly different between drying methods. EMCs of these four species determined by oven drying method and with capacitive admittance moisture meter were not significantly different between drying methods. EMC of high temperature dried red pine determined with resistance moisture meter was significantly higher than that of conventional kiln dried wood. But EMCs of other species did not show significant difference between drying methods. EMCs of conventional and high-temperature dried wood determined with electronic moisture meters, especially in the case of the capacitive-admittance moisture meter measurement, were lower than that determined by oven drying method.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.458-465
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• 2020

Isotherms, kinetics and thermodynamic properties for adsorption of acid fuchsin (AF) dye by activated carbon were carried out using variables such as dose of adsorbent, pH, initial concentration and contact time and temperature. The effect of pH on adsorption of AF showed a bathtub with high adsorption percentage in acidic (pH 8). Isothermal adsorption data were fitted to the Freundlich, Langmuir, and Dubinin-Radushkevich isotherm models. Freundlich isothem model showed the highest agreement and confirmed that the adsorption mechanism was multilayer adsorption. It was found that adsorption capacity increased with increasing temperature. Freundlich's separation factor showed that this adsorption process was an favorable treatment process. Estimated adsorption energy by Dubinin-Radushkevich isotherm model indicated that the adsorption of AF by activated carbon is a physical adsorption. Adsorption kinetics was found to follow the pseudo-second-order kinetic model. Surface diffusion at adsorption site was evaluated as a rate controlling step by the intraparticle diffusion model. Thermodynamic parameters such as activation energy, Gibbs free energy, enthalpy entropy and isosteric heat of adsorption were investigated. The activation energy and enthalpy change of the adsorption process were 21.19 kJ / mol and 23.05 kJ / mol, respectively. Gibbs free energy was found that the adsorption reaction became more spontaneously with increasing temperature. Positive entropy was indicated that this process was irreversible. The isosteric heat of adsorption was indicated physical adsorption in nature.

• Applied Science and Convergence Technology
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• v.24 no.6
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• pp.228-231
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• 2015

We investigated the adsorption structures and the initial growth mode of ultra-thin Al films on a W(110) surface at a high temperature. When Al atoms were adsorbed on the W(110) at the substrate temperature of 1100 K and with coverage of 0.5ML, Al atoms formed a p($2{\times}1$) double-domain structure. When the coverage was 1.0 ML, the double domain of a hexagonal structure (fcc(111) face) rotated ${\pm}5^{\circ}$ from the [100] direction of the W(110) surface and another distorted hexagonal structure were found. Low-energy electron diffraction results along with ion scattering spectroscopy results showed that the Al atoms followed the Volmer-Weber growth mode at a high temperature.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.68-74
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• 2016

In this study, the fabrication of zeolite combined activated carbon spherical samples was carried out as follows. Briefly, ZSM-5 zeolite and activated carbon were composed as main absorbent materials; by controlling the weight percentage of zeolite and binder materials, a series of spherical samples (AZP 4, 6, 8) were prepared. These spherical samples were characterized by BET, XRD, SEM, EDX, and pressure drop; benzene and iodine adsorption tests, bactericidal effect test, and ignition temperature test were also performed. The adsorption capability was found to depend on the BET surface area; the spherical samples AZP6 with high BET surface area of $1011m^2/g$ not only exhibited excellent removal effects for benzene (24.9%) and iodine (920mg/g) but also a good bactericidal effect. The enhanced ignition temperature may be attributed to the homogeneous dispersion conditions and the proper weight percentage ratio between zeolite and activated carbon.

• Membrane and Water Treatment
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• v.9 no.2
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• pp.95-104
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• 2018

Copper pollution around the world has caused serious public health problems recently. The heavy metal adsorption on traditional membranes from wastewater is limited by material properties. Different adsorptive materials are embedded in the membrane matrix and act as the adsorbent for the heavy metal. The carbonized leaf powder has been proven as an effective adsorbent material in removing aqueous Cu(II) because of its relative high specific surface area and inherent beneficial groups such as amine, carboxyl and phosphate after carbonization process. Factors affecting the adsorption of Cu(II) include: adsorbent dosage, initial Cu(II) concentration, solution pH, temperature and duration. The kinetics data fit well with the pseudo-first order kinetics and the pseudo-second order kinetics model. The thermodynamic behavior reveals the endothermic and spontaneous nature of the adsorption. The adsorption isotherm curve fits Sips model well, and the adsorption capacity was determined at 61.77 mg/g. Based on D-R model, the adsorption was predominated by the form of physical adsorption under lower temperatures, while the increased temperature motivated the form of chemical adsorption such as ion-exchange reaction. According to the analysis towards the mechanism, the chemical adsorption process occurs mainly among amine, carbonate, phosphate and copper ions or other surface adsorption. This hypothesis is confirmed by FT-IR test and XRD spectra as well as the predicted parameters calculated based on D-R model.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.06a
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• pp.140-141
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• 2020

Concrete has a lower thermal conductivity or thermal diffusion coefficient compared to other building materials, so it is widely used as fireproof compartment material or refractory material for structures. However, in the event of thermal damage such as fire, cement curing agents and aggregates act differently, resulting in heat generation or deterioration of tissue due to dehydration, resulting in deterioration of physical properties and fire resistance. Therefore, in this study, the processing structure of cement paste is measured through nitrogen absorption method. The test specimen is a cement paste of 40% W/C and is set at 1000 ℃ under heating temperature conditions. As the temperature rose, the micro-pore mass below was reduced based on about 0.01 감소m, but the air gap above that was increased.Thus, in the range of pores measured in nitrogen adsorption, the air mass tended to decrease under high temperature conditions.

• Applied Chemistry for Engineering
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• v.8 no.2
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• pp.267-275
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• 1997

$ZrO_2$ Powder was Prepared by sol-gel process and the adsorption characteristic of cobalt($Co^{2+}$) by $ZrO_2$ adsorbent in high-temperature water was investigated using batch adsorption experiment with a stirred autoclave. The prepared $ZrO_2$ was calcined at $600{\sim}1400^{\circ}C$ and analyzed by X-ray diffractometry, SEM, BET surface area, FT-IR and TG-DTA measurement. The tetragonal Phase of $ZrO_2$ is produced $480^{\circ}C$ from amorphous gel at temperature $480^{\circ}C$. Both tetragonal and monoclinic phase of $ZrO_2$ exist at temperature between $600^{\circ}C$ and $1000^{\circ}C$. At temperature $1200^{\circ}C$, tetragonal to monoclinic phase trasition is occurred. The $Co^{2+}$ adsorption capacity of $ZrO_2$ calcined at $600^{\circ}C$ for 4 hours is 0.16 meq $Co^{2+}/g$ adsorbent in the high temperature at $250^{\circ}C$. The adsorption of $Co^{2+}$ on the $ZrO_2$ adsorbent is irreversible endothermic in the temperature range ($125-175^{\circ}C$). The standard enthalpy change (${\Delta}H^{\circ}$) of $ZrO_2$ calcined at $600^{\circ}C$ for 4 hours is 18 kJ/gmol.

• Textile Coloration and Finishing
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• v.4 no.4
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• pp.97-103
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• 1992

For manufacturing a high sorptive ACF, we used orthognal array experimental design to get optimum condition. The ability of ACF was measured by $CCl_4$ adsorption and showed those manufacturing conditions were effective in the order of treatment time>oxidative gas>treatment temperature. The optimal condition presented the maximum adsorption rate was at 90$0^{\circ}C$ for 6 minutes with $CO_2$/$H_2O$ gas in the PAN based ACF manufacturing process. The adsorption rate of developed ACF in this experiment was over 100%.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.136-136
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• 2013

High-resolution photoemission spectroscopy (HRPES) measurements were collected and density functional theory (DFT) calculations were conducted to track the coverage dependent variation of the absorption structure of 2-thiophenecarboxaldehyde (C4H3SCHO: TPCA) on the Ge(100) surface at room temperature. In an effort to identify the most probably adsorption structures on the Ge(100) surface, we deposited TPCA molecules at a low coverage and at a high coverage and compared the differences between the electronic features measured using HRPES. The HRPES data provided three possible adsorption structures of TPCA on the Ge(100) surfaces, and DFT calculations were used to determine the plausibility of the structures. HRPES analysis, corroborated by DFT calculations, indicated that an S-dative bonded structure was the most probable adsorption structure at relatively lower coverage levels, the [4+2] cycloaddition structure was the second most probable structure, and the [2+2]-C=O cycloaddition structure was the last probable structure on the Ge(100) surfaces at relatively higher coverage levels.

• The Korean Journal of Food And Nutrition
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• v.9 no.3
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• pp.299-306
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• 1996

The study was performed under the various conditions, such as the edible parts and particle sizes of Allium. The concentrations, the temperartures, and the pH of heavy metal solutions to investigated their adsorption capacity of heavy metals by genus Allium. The adsorption amount of Pb by Allium in the aqueous soluton was apparently higher than that of Ni and Cu by them. The larger the particle sloe of welsh onion and shallot was, the higher the adsorption of Cu was. The adsorptlons of Cu, Ni and sorption ratio was not different. As the temperature increased, the amount of heavy metal adsorption increased in general, but the adsorption of Ni by welsh onion and wild garlic and leek, Cu by shallot, wild garlic and leek decreased. Adsorption of Pb to Allium was not affected by the different values of pH, and adsorptions of Ni and Cu were greatly affected by those of pH. Especially, the higher the pH was, the greater the Ni adsorption to Allium was, and the lower the pH was, the higher the Cu adsorption was. The correlation between the amount of components in edible parts of Allium and that of adsorption of heavy metals was significantly high In amino acids containing sulfhydryl group(-SH) and vitamin B2.