• 콘크리트학회지
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• 제6권6호
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• pp.151-158
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• 1994

본 연구에서는 수경성 시멘트 경화체의 구조적 결함인 휨강도를 향상시키시 위해 보통 포틀랜드 시멘트비를 0.1로 하여 혼합수량을 줄이고 수용성 고분자 물질인 Hydroxy Propy Methyl Cellulose(HPMC)를 첨가하여 시멘트입자의 윤활작용에 따른 균일한 분산효과와 결합효과를 얻도록 하였으며, twin roll mill로 혼련 성형하여 치밀하고 균일한 경화제 시편을 제조하였다. 이러한 고강도 시멘트 경화체의 휨강도는 약 96MPa, 탄성계수는 60GPa로 우수한 특성을 나타내었다. 고강도 시멘트의 고강도화 기구는 100${\mu}m$ 이상의 큰 기공제거 및 균열성장경로인 모세관 기공의 감소, 미수화 시멘트의 증가로 인한 탄성계수의 증가와 crack toughening(입자 가교, 고분자 섬유 가교, frictional interlocking)에 의한 파괴 인성의 향상 때문인 것으로 판단된다.

• 대한치과재료학회지
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• 제44권1호
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• pp.69-77
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• 2017

The aim of this study was to investigate the effects of chitosan powder addition on the strengthening of conventional glass ionomer cement. Two types of chitosan powders with different molecular weight were mixed with conventional glass ionomer cement (GIC): low-molecular weight chitosan (CL; 50~190 kDa), high-molecular weight chitosan (CH; 310~375 kDa). The chitosan powders (CL and CH) were separately added into the GIC liquid (0.25-0.5 wt%) under magnetic stirring, or mixed with the GIC powder by ball-milling for 24 h using zirconia balls. The mixing ratio of prepared cement was 2:1 for powder to liquid. Net setting time of cements was measured by ISO 9917-1. The specimens for the compressive strength (CS; $4{\times}6mm$), diametral tensile strength (DTS; $6{\times}4mm$), three-point flexure (FS; $2{\times}2{\times}25mm$) with flexure modulus (FM) were obtained from cements at 1, 7, and 14 days after storing in distilled water at $(37{\pm}1)^{\circ}C$. All mechanical strength tests were conducted with a cross-head speed of 1 mm/min. Data were statistically analyzed by one-way ANOVA and Tukey HSD post-hoc test. The mechanical properties of conventional glass ionomer cement was significantly enhanced by addition of 0.5 wt% CL to cement liquid (CS, DTS), or by addition of 10 wt% CH (FS) to cement powder. The CL particles incorporated into the set cement were firmly bonded to the GIC matrix (SEM). Within the limitation of this study, the results indicated that chitosan powders can be successfully added to enhance the mechanical properties of conventional GIC.

• 콘크리트학회논문집
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• 제27권2호
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• pp.177-184
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• 2015

시멘트를 대체하여 고로슬래그 미분말을 건설재료로 대량으로 활용하기 위해서는 잠재수경성을 향상시켜 조기강도를 개선시킬 수 있는 적절한 활성화제가 필요하다. 이 연구에서는 경석고와 황산나트륨을 이용하여 하이볼륨 고로슬래그 시멘트의 수화특성에 대한 연구를 수행하였다. 수화특성을 평가하기 위해 고로슬래그 미분말을 전체 바인더의 80%로 고정하였으며, 나머지 20%를 시멘트와 활성화제로 구성하였다. 경석고와 황산나트륨의 치환율(1~7%)에 따른 응결, 압축강도, 미소수화열 및 미세구조 특성을 시멘트만을 사용한 경우와 비교하여 분석하였다. 이 연구에서는 경석고와 황산나트륨을 활성화제로 사용한 경우, 하이볼륨 고로슬래그 미분말의 조기 수화특성을 향상을 위해 필요한 $SO_3$ 함량을 전체 바인더 중량대비 약 3~5% 제안하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2017년도 추계 학술논문 발표대회
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• pp.107-108
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• 2017

The purpose of this study is to derive the optimum water absorbing curing time. It was found that the cement paste compressive strength was increased with the water absorbing ratio up to 40%, but the compressive strength was slightly lower when the catch level was over 50%. It is considered that the superfluous water did not react and remained in the inside of the specimen, causing microcracks in the inside due to the high temperature curing, resulting in a decrease in strength. Therefore, it is considered that the optimum catcher curing time for improving the strength through catcher curing is when the catcher reaches 40%.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 봄 학술발표회 논문집(I)
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• pp.171-176
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• 1998

Recently, the Belite cement having the high fluidity, high strength, and low heat properties, was developed, and is being promoted the efforts for application on the real structures. Accordingly, for the purpose of practical use of high strength concrete using the Belite cement, was carried out the performance evaluation experiments about the structural members(column, beam, column-beam joint, steel bond strength etc.). Specimens were made in three types of concrete(Belite:350, 600kg/$\textrm{cm}^2$, OPC:350kg/$\textrm{cm}^2$) by taking into account the key parameters. In this paper, were summarized the comparative experimental results on the material properties and structural performance of Belite concrete.

• Computers and Concrete
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• 제20권2호
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• pp.155-164
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• 2017

During the past decades, development of reinforcing materials caused a revolution in the structure of high strength and high performance cement-based concrete. Among the most important and exciting reinforcing materials, Steel Fiber (SF) becomes a widely used in the recent years. The main reason for addition of SF is to enhance the toughness and tensile strength and limit development and propagation of cracks and deformation characteristics of the SF blended concrete. Basically this technique of strengthening the concrete structures considerably modifies the physical and mechanical properties of plain cement-based concrete which is brittle in nature with low flexural and tensile strength compared to its intrinsic compressive strength. This paper presents an overview of the work carried out on the use of SF as reinforcement in cement-based concrete matrix. Reported properties in this study are fresh properties, mechanical and durability of the blended concretes.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2001년도 학술논문발표회
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• pp.82-87
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• 2001

The purpose of this study is for the active use of the fly ash, which is a by-product of the combustion pulverizes coal thermal power plants, to compensate for the lack of landfill and for conservation of energy, by using fly ash as the supplementary cementitious material, and to prove its possibility as the related products of the cement. First of all, the ordinary fly ash is grinded in a special method and its fineness is controlled from 6000$\textrm{cm}^2$/g to 8000$\textrm{cm}^2$/g, then replaced it with the 10% to 80% of the cement mortar in order to test physics characteristics. The first experiment conducts on the strength development in fly ash replacing content and fineness. and the changes of the flow values, incorporating fly ash into cement. The second one is about the slow development of the strength of the fly ash mortar in early ages, and improves its strength with the activator $Na_{2}SO_{4}$, using high volume fly ash.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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• pp.148-149
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• 2014

In modern society, population overcrowding and concentration of facilities are happened because of the concentration on to city. So this phenomenon demands improvement of material's performance, technical development of structure analysis and design and improvement of constructing ability .High strength concrete has some merits. High strengthening makes the cross section reduced, and that cause decrease of structure weight. And using high durable and superplasticizer promote liquidity, thus high quality concrete can be produced. Because of these advantages, this study is for showing validity of using it by compression/tensile strength experiment. As this experiment's result, when concrete become stronger, interface intensity coefficient between cement and aggregate is different and they don't adhere to each other. So there is brittle failure. Fragility factor also steadily increase with strong concrete, it tells high strength concrete has problem. Therefore the sources used in high strength concrete like cement and aggregate must have great quality. So the source's performance must be supervised well because their quality decides performance criteria.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 추계 학술논문 발표대회
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• pp.13-14
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• 2014

Ultra high performance concrete (UHPC) consists of cement, silica fume (SF), sand, fibers, water and superplasticizer. Typical water/binder-ratios are 0.15-0.20 with 20-30% of silica fume. The development off properties of hardening UHPC relates with both hydration of cement and pozzolanic reaction of silicafume. In this paper, by considering the production of calcium hydroxide in cement hydration and its consumption in the pozzolanic reaction, a numerical model is proposed to simulate the hydration of UHPC. The degree of hydration of cement and degree of reaction of silica fume are obtained as accompanied results from the proposed hydration model. The properties of hardening UHPC, such as degree of hydration of cement, calcium hydroxide contents, and compressive strength, are predicted from the contribution of cement hydration and pozzolanic reaction. The proposed model is verified through experimental data on concrete with different water-to-binder ratios and silica fume substitution ratios.

• 콘크리트학회논문집
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• 제22권5호
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• pp.633-640
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• 2010

이 연구에서는 숏크리트에 적용하기 위한 고분말도 시멘트의 기본 특성을 검토하고자 하였다. 고분말 시멘트의 주요특성을 연구하기 위하여 입도분포, 응결시간, 압축강도를 측정하였으며, SEM 관찰, DSC 열분석, X선 회절분석을 실시하였다. 고분말도 시멘트는 일반 포틀랜드 시멘트와 비교하여 응결시간이 크게 단축되었으며 압축강도가 개선되었다. 기기분석 결과 고분말도 시멘트는 초기수화물이 보다 미세하고 광범위하게 분포하는 것으로 확인되었으며, 이러한 결과는 시멘트의 분말도가 상승함에 따라 시멘트 입자와 물과의 접촉면이 증가하기 때문이다. SEM 관찰, DSC 열분석, X선 회절분석 결과 알루미네이트계 급결제는 칼슘알루미늄 수화물의 생성을 촉진하고, 알칼리프리계 급결제는 에트린자이트와 모노설페이트의 생성을 증진하는 것으로 나타났다. 페이스트 응결시간 측정으로부터 알루미네이트계 급결제와 알칼리프리계 급결제가 응결시간을 단축시키는 것으로 확인되었으며, 고분말도 시멘트는 압축강도가 크게 향상 되는 것으로 나타났다. 특히 알루미네이트계 급결제는 응결시간 단축에 효과적이며, 알칼리프리계 급결제는 7일 이후의 강도증진에 효과적인 것으로 확인되었다.