• 제목/요약/키워드: high porosity

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저 기공성 특수 포틀랜드 시멘트에 대한 비교연구 (Comparative Study on a Special Low-Porosity Portland Cement)

  • 장복기
    • 한국세라믹학회지
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    • 제25권5호
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    • pp.532-540
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    • 1988
  • Even the finest cement as having a specific surface area of 6.000~8.500$\textrm{cm}^2$/g (Blaine) is to convert into low-porosity hardened cement paste by the use of appropriate plasticizer. In this study, tests were carried out on such a special cement mix(fineness of 6.000$\textrm{cm}^2$/g, Ca-lignosulfonate plus k2CO3 as plasticizer and W/C=0.25) in comparison with ordinary Portland cement. Owing mainly to the high fineness of the cement powder and the low water-to-cement ratio, the hardened low-porosity cement paste showed a very tight microstructure, the pore texture of which consisted of micropores and wide pores only of small radii. The consequence of such mix was hence that the low-porosity special cement had excellent properties of early-high and very high strengths as compared to ordinary Portland cement. Its volume change when dried in the air or re-wetted, exhibited superor behaviour as well.

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알카리 전처리에 의한 NBKP의 형태학적 및 이화학적 변화 (Morphological and Physicochemical Changes of NBKP by Alkali Pretreatment)

  • 문성필;장민환
    • 펄프종이기술
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    • 제41권4호
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    • pp.58-64
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    • 2009
  • This study was carried out to prepare high porosity pulp for oil and air filter media from commercial grade NBKP with 6 - 20% NaOH treatment. The fiber width of NBKP remarkably decreased by NaOH pretreatment. The air permeability of the test sheet prepared from alkali-pretreated NBKP increased with increasing NaOH concentration up to 15%. The burst factor was greatly decreased by alkali pretreatment. By 15 - 20% NaOH pretreatment of NBKP, it could be possible to prepare a high porosity pulp. It seems that the high porosity of the pulp was due to a strong swelling and a great change of the cellulose crystalline lattice from cellulose I to cellulose II with NaOH treatment of NBKP. The study suggested that alkali- pretreated NBKP could be used for manufacturing oil and air filter media.

수용성 입자를 이용한 다공성 폴리머 구조체의 공극률 향상과 기계적 물성과의 관계 (Relationship between Mechanical Properties and Porosity of Porous Polymer Sheet Fabricated using Water-soluble Particles)

  • 소새롬;박석희;박상후
    • 한국기계가공학회지
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    • 제17권6호
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    • pp.16-23
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    • 2018
  • A polymer porous sheet, which can be applied to diverse wearable devices, has some advantages such as light-weight, high flexibility, high elongation, and so many others. In order to fabricate a porous sheet, water-soluble particles like sugar were utilized frequently, and there has been great advances. However, with our best knowledge, there are not enough reports on the mechanical behavior of porous sheets having different porosity. So, in this work, we tried to find out the relationship between porosity and mechanical deformation of a porous sheet. The process parameters such as a particle size, sheet thickness and PDMS mixing ratio with curing agent were analyzed on the effect of increasing the porosity of a sheet. Also, mechanical deformation of a sheet was tested using a tensile experiment. Through the experimental results, we make a conclusion that a highly porous sheet with thin thickness has high flexibility, and it deformed nearly double elongation comparing to worst one among nine cases.

Effects of Physicochemical/Mineralogical Characteristics of Limestones and Porosity after Calcination on Desulfurization Reactivities

  • Baek, Chul-Seoung;Seo, Jun-Hyung;Cho, Jin-Sang;Cho, Kye-Hong;Han, Choon
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.34-42
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    • 2016
  • Characteristics of wet flue gas desulfurization and in-furnace desulfurization of domestic and overseas limestone with different crystallinity and crystalline size are studied in this article. Properties of desulfurization were evaluated in relation to physicochemical/ mineralogical characteristics, degree of pore formation for different calcination temperatures and TNC(total neutralizing capability). TNC of domestic high crystalline limestone was lower than that of overseas one. On the other hand, the porosity after calcination was shown to be relatively high for domestic limestone, which had high initial rates of desulfurization reactions in-furnace. Based on low pore formation and porosity with high TNC of crystalline high-Ca limestones compared to macrocrystalline ones, the former are preferred for wet desulfurization processes.

Model Prediction and Experiments for the Electrode Design Optimization of LiFePO4/Graphite Electrodes in High Capacity Lithium-ion Batteries

  • Yu, Seungho;Kim, Soo;Kim, Tae Young;Nam, Jin Hyun;Cho, Won Il
    • Bulletin of the Korean Chemical Society
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    • 제34권1호
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    • pp.79-88
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    • 2013
  • $LiFePO_4$ is a promising active material (AM) suitable for use in high performance lithium-ion batteries used in automotive applications that require high current capabilities and a high degree of safety and reliability. In this study, an optimization of the electrode design parameters was performed to produce high capacity lithium-ion batteries based on $LiFePO_4$/graphite electrodes. The electrode thickness and porosity (AM density) are the two most important design parameters influencing the cell capacity. We quantified the effects of cathode thickness and porosity ($LiFePO_4$ electrode) on cell performance using a detailed one-dimensional electrochemical model. In addition, the effects of those parameters were experimentally studied through various coin cell tests. Based on the numerical and experimental results, the optimal ranges for the electrode thickness and porosity were determined to maximize the cell capacity of the $LiFePO_4$/graphite lithium-ion batteries.

수침에 따른 공극률이 큰 포항 이암의 특성 (Properties of Pohang Mudstone with High Porosity According to Water Immersion)

  • 김병수;이윤재;김태형;김병준
    • 한국지반공학회논문집
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    • 제37권11호
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    • pp.83-92
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    • 2021
  • 본 연구에서는 공극률이 큰 포항지역 이암의 특성을 평가하고자 유효공극률 측정, 전자 현미경(SEM) 관찰 및 X-선 회절분석(XRD), 슬레이킹, 팽창, 수침기간에 따른 일축압축강도 특성을 분석하였다. 16개의 시험편(정육면체, 5cm)에 대한 시험결과, 유효공극률(porosity)은 평균 14.67%로 일반적인 이암 공극률보다 높은 공극률을 보였으며, 전자 현미경(SEM) 관찰을 통해 실제로 공극률이 큼을 확인하였다. X-선 회절분석결과 팽윤성 점토광물 함유량은 2.3~4.1%(녹니석, 카올린)로 선행연구 된 포항지역 이암보다 낮은 점토 함유량을 보였다. 슬레이크 내구성 지수는 37.73~87.73%로 저~중정도 내구성을 보여 선행연구 결과 대비 다소 낮은 내구성을 보였으며, 팽윤성은 30분간 장축방향 최대 흡수팽창 변화률 1.79~1.82%로 급격하게 팽창함을 확인하였다. 수침에 따른 일축압축강도 감소 특성은 수침 10분 경과 후 만에 시험편이 급격히 풍화되어 강도가 감소하여 기존 포항지역 이암과 관련된 선행연구의 결과와도 상이함을 확인하였다. 이것은 연구대상 이암의 큰 공극률 때문으로 판단된다.

진동기의 단계별 조절이 모형 제작시 기포발생에 미치는 영향에 관한 연구 (A Study to Effect on the Porosity when Model Making for Control of Vibrator)

  • 이도경
    • 대한치과기공학회지
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    • 제13권1호
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    • pp.15-19
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    • 1991
  • This study was made to effect on the porosity when model making for control of vibrator. Samples of total 600 were made by plaster and stone divided low, medium and high which is 100 each. The following results were obtained to observation porosity of surface by eyes. 1. Second stage was fewer than third stage, first stage was fewer than third stage in porosity number of plaster model. 2. Second stage was fewer than first stage in porosity number of stone model. 3. Stone model was fewer than plaster model in porosity number of third stage.

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임펠러 블레이드용 다이캐스팅 금형의 게이트 방안 설계 (Gate Design to Reduce Porosity in High Pressure Die Cast Impeller Blade)

  • 정순규;추인호;이정환;김대용
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 춘계학술대회 논문집
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    • pp.435-436
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    • 2009
  • In the effort on cost reduction in marine equipment company, the medium sized impeller blade ($500mm{\times}200mm{\times}20mm$) of an axial flow pan was manufactured by the high pressure die casting, with which was replaced the gravity die casting. High pressure die casting is a practical alternative because of some advantages such as excellent accuracy and smooth cast surface as well as cost reduction if a certain amount of porosity in the parts can be minimized. In order to reduce the porosity in the center of the neck which is thickest region of the impeller blade, the several gate designs were proposed in this work. The flow simulations for each gate design were performed and then the optimal design was determined by considering the air pressure distribution in neck section. Finally, the size of porosity in the neck of the die cast impeller blade for optimal design was less than 1mm, which satisfied the requirement.

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Analysis of a functionally graded nanocomposite sandwich beam considering porosity distribution on variable elastic foundation using DQM: Buckling and vibration behaviors

  • Nejadi, Mohammad Mehdi;Mohammadimehr, Mehdi
    • Computers and Concrete
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    • 제25권3호
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    • pp.215-224
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    • 2020
  • In the present study, according to the important of porosity in low specific weight in comparison of high stiffness of carbon nanotubes reinforced composite, buckling and free vibration analysis of sandwich composite beam in two configurations, of laminates using differential quadrature method (DQM) is studied. Also, the effects of porosity coefficient and three types of porosity distribution on critical buckling load and natural frequency are discussed. It is shown the buckling loads and natural frequencies of laminate 1 are significantly larger than the results of laminate 2. When configuration 2 (the core is made of FRC) and laminate 1 ([0/90/0/45/90]s) are used, the first natural frequency rises noticeably. It is also demonstrated that the influence of the core height in the case of lower carbon volume fractions is negligible. Even though, when volume fraction of fiber increases, the critical buckling load enhances smoothly. It should be noticed the amount of decline has inverse relationship with the beam aspect ratio. Investigating three porosity patterns, beam with the distribution of porosity Type 2 has the maximum critical buckling load and first natural frequency. Among three elastic foundations (constant, linear and parabolic), buckling load and natural frequency in linear variation has the least amount. For all kind of elastic foundations, when the porosity coefficient increases, critical buckling load and natural frequency decline significantly.

고온에 노출된 실리카퓸 혼입 고강도 콘크리트의 공극구조 변화 (Veriation of Pore Structure of High Strength Concrete Including Silica Fume Exposed to High Temperature)

  • 송훈;소양섭
    • 콘크리트학회논문집
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    • 제16권5호
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    • pp.597-604
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    • 2004
  • 본 연구는 실리카퓸을 사용한 고강도 콘크리트의 고온하의 압축강도의 저하 및 공극률 변화를 통하여 강도 감소와 공극구조와의 연관성을 검토하였다. 또한, 실리카퓸 혼입의 유무와 각 가열온도에서의 시멘트 수화물의 탈수에 의한 공극특성의 변화에 관한 기초 데이터를 제공하고자 하였다. 연구결과, 실리카퓸의 혼입에 따른 필러효과 및 물-결합재비의 차로 인해 공극률 및 공극분포는 다르게 나타났다. 가열온도가 상승함에 따라 공극률도 점진적으로 증가하는 경향을 보였다. 또한, $600^{\circ}C$ 이상의 고온에서의 경향성은 더욱 현저하였다. 가열온도의 상승에 따라 $0.1{\~}0.5{\mu}m$공극의 증가는 현저하였으며 이는 모세관 공극의 수분의 증발 및 C-S-H계 수화물 및 수산화칼슘이 분해되어 결합수가 탈수한 결과이다. 고열에 의한 신축도 콘크리트 내부의 미세균열을 발생시켜 공극률 증가를 유발한다. 이러한 공극률 증가는 가열온도에 따라 일정한 경향성을 띠므로 화해를 입은 콘크리트의 수열온도 및 국부적인 성능저하를 예측할 수 있을 것으로 기대된다.