• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.302-308
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• 2022

The PdO nanoparticle with large surface area was selected to solve the environmental pollution problem at fire range caused by high energy explosives research department explosive (RDX) and high melting explosive (HMX). By simulating water pollution, RDX and HMX nitramine explosives were dissolved in water, followed by the degradation reaction at 313 K by adding PdO. In order to measure the degradation reaction rate of explosives, ¹H NMR was used, which can monitor the reaction rate without losing sample during reaction, and observe the progress of the reaction through the spectrum. The results showed that the degradation of RDX and HMX by PdO nanoparticles are pseudo-first order reaction. The degradation of explosives compounds were observed via the chemical shift and peak intensity analysis of NMR peaks. The measured rate constants for these reactions of RDX and HMX were 2.10 × 10^-2 and 6.35 × 10^-4 h^-1, respectively. This study showed that the application of PdO nanoparticles for explosives degradation is a feasible option.

• Explosives and Blasting
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• v.28 no.2
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• pp.99-107
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• 2010

Domestic explosive demolition techniques have been developed and applied for low-rise structures up to now. However, the demand for the development of those techniques that can be applied economically, safely and environment-friendly rapidly increases because the old high-rise RC rahmen structures that were built since around 1970s are now required to rebuild. As a result, element technologies of explosive demolition for low-rise structures were applied to take advantage of technology in high-rise structures that performed application testing at Chungang Department demolition field in Daejeon city. It could judge elements technology establishment for high-rise structure demolition and field application and suggest the improvements when the problems occurred to develop High-rise building demolition techniques for method of protection a field test and the dust reduction test. The water cannon test was applied to reduce the dust site and the drilling tests are performed to select the best components for explosives demolition elements techniques of the reliability. This paper shows that we have the ability to remove a high-rise building using environmentally friendly safe and economical explosives demolition method. It would contribute to prevent a foreign company from entering the domestic market and should contribute to acquire competitiveness of domestic demolition industry.

• Applied Chemistry for Engineering
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• v.20 no.2
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• pp.159-164
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• 2009

Monomers of oxetane high explosives were theoretically examined in terms of reactivity, reaction mechanism and process of polymerization substituted by azido $(-CH_2N_3)$, nitrato $(-CH_2ONO_2)$ and hydrazino $(-CH_2N_2H_3)$ which belong to the 5th class hazardous materials and have explosiveness under acid catalyst using MINDO/3, MNDO, and AMI methods for formal charge, heat of formation, and energy level. Nucleophilicity and base of oxetane high explosives could be explained by negative charge size of oxetane oxygen atom and reactivity of oxetane in the growth stage of polymerization under acid catalyzer could be expected to be governed by positive charge size of axial carbon atom and low LUMO energy of electrophile. It could be estimated that carbenium ion was more beneficial in the conversion process of oxetane high explosives than that of stabilization energy (13.90~31.02 kcal/mole) of oxonium ion. In addition, concentration of oxonium ion and carbenium ion in equilibrium state influenced mechanism and it was also estimated that $S_N1$ mechanism reacts faster than that of $S_N2$ in prepolymer growth stage considering quick equilibrium based on form and calculation of polymerization under acid catalyzer.

• Journal of the Korea Institute of Military Science and Technology
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• v.4 no.1
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• pp.20-29
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• 2001

We recently developed a friability test procedure, which will be used as one of substance tests for Extremely Insensitive Detonating Substances(EIDSs) in Test Series 7 of the United Nations. This test was intended to assess the susceptibility of insensitive explosives to the break-up as high strain rate and subsequent ignition characteristics of the deformed material. We designed an air gun system using the hydro code simulation. The projectile velocities of the gun were in good agreement with those predicted by the hydro code with an inert material. Three different types of explosives, melt castable Comp B, castable plastic bonded explosives(PBXs), and pressable PBXs were tested during the development of the test procedure. Two tastable PBXs, i.e. DXD-09 and DXD-10, which are currently under development as candidate formulations of EIDS were classified as EIDS, since test results with these formulations were far better than the criterion of the UN Test Series 7.

• Journal of the Korea Institute of Military Science and Technology
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• v.8 no.4 s.23
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• pp.120-129
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• 2005

To analyze a blast effect of developed explosives, three different kinds of aluminized tastable explosives and melted cast explosive TNT were used. Conventional explosive TNT was used as a reference. Each tested explosive charge of 340mm diameter spherical type was initiated at the charge center with DXD-65(${\sim}750g$) booster and RP-87 EBW detonator. Thirteen piezo type pressure sensors were located at a range from 4 to 50m away from the charge. From the blast wave profiles, we calculated a peak blast pressure and impulse of the explosion. The calculated pressures and in pulses were converted to TNT Equivalent Weight(TEW) factor by the scaling ]aw method. The average TEW factors based on the blast pressure of TX-01, TX-02, TX-03, TX-04 were 1.298, 1.05, 1.266, 1.274 and the average TEW factors based on impulse were 1.504, 1.686, 1.640, 1.679. From the results, we concluded that TEW factors based on blast pressure and based on impulse of aluminized explosives were superior to TNT. This results are owing to the high contents of aluminum in formulations.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.4
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• pp.96-106
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• 2017

In pressable polymer bonded explosives (PBXs), densification occurs due to rearrangement and deformation of explosive particles during pressing. If brittle explosives are compressed till particle fraction become higher than theoretical random close packing fraction (RCPF), bigger particles should be fractured to fill the void. In this study, multi-modal particle system was introduced for the decrease in possibility of particle fracture during compression expecting decrease in shock sensitivity of highly filled pressable PBX. The experimental results showed the trimodal particle system had low sensitivity with high density, compared to bimodal particle system.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.4
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• pp.376-386
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• 2015

MOFs(Metal-Organic Frameworks) are new kinds of materials comprised of metal ions and functional organic ligands, and have large pores in its rigid structures which give the materials various functionalities, including gas absorption, separation, drug delivery etc. Recently photoluminescence properties of MOFs and possibilities of its application to high explosive sensing technologies are drawing attentions from scientists and engineers, because these methods are simple, cheap and easy to perform detection operations. In this article the author reviews the mechanisms of photoluminescence of MOFs, the detection methods of high explosives using MOFs and recent research progresses based on the papers published mainly during last 10 years.

• Explosives and Blasting
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• v.29 no.2
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• pp.67-80
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• 2011

Recently, the number of structure demolitions has increased in both civil and architecture fields due to various reasons such as redevelopment of a city, utilization of sites and restoration of deteriorated structures. In the past, domestic shell structures had been constructed with brick masonry and they were not high. Therefore, their demolition had been executed with ease. Recently, however, taller reinforced concrete shell structures have become a target for the destruction. Under these circumstances, how to efficiently demolish a structure and how to minimize effects of the destruction on environment including vibration and noise have become a main issue. One of the possible solutions is the explosive demolition. In this study, a case of explosives demolition of the stack, which is located in Jeju Thermal Power Plant in Republic of Korea and is 70 m tall, is addressed. In order to fall down the structure against the desired direction, 13.5 kg dynamite and 100 electric detonators were used.

• Explosives and Blasting
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• v.33 no.1
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• pp.1-12
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• 2015

In this study, the domestic bench blasting sites were researched to set the blast coefficient C according to the type of rock and type of industry. With the use of the experimental data on the representative industrial explosives and the data of the manufacturers'data on explosives, powder coefficient e was set up. The blast coefficient C was 0.21~0.30 when the average value for 5 representative kinds of rocks including granite was searched. The blast coefficient C for quarrying, mining and construction sites were 0.22, 0.13 and 0.26 respectively. On the other hand, powder coefficient e was obtained in four elements such as reactive energy, ballistic mortar test, VOD, Langefors'strength per unit weight. e value for emulsion which is one of the representative explosives was found to be 1 while those of high performance emulsion and ANFO were found to be 0.9 and 1, respectively.

• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.178-185
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• 2019

Three spherical quaternary composites composed of metal/metal oxide/high explosive/oxidizer were prepared by a crystallization/agglomeration process. From the characteristics of composites by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), the shortening of the decomposition zone of high explosives in the quaternary composite was observed, which may be attributed to the autocatalytic reaction caused by $ClO_2$ or HCl which are ammonium perchlorate (AP) degradation products. The activation energy analysis showed that the activation energy abruptly decreases at the end of the decomposition zone of high explosives, and it was considered to be caused by $HNO_2$ which is common in decomposition products of high explosives. The activation energy predicted from complex pyrolysis results by the distributed activation energy model (DAEM) showed much better in accuracy than those by model-fitting methods such as Kissinger-Akahira-Sunose and Flynn-Wall-Ozawa models.