• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 1999년도 무주 반딧불 축제 기념 세미나
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• pp.21-38
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• 1999

제초제는 현대 농업에서 필수적인 농자재이나 생리활성을 갖기에 비목적대상생물에 대한 위해성을 배제할 수 없다. 제초제의 문제점중 잔류문제는 가장 중요한 부분이며 그중 인간생활과 밀접한 관계를 갖는 토양, 농작물중의 잔류는 더욱 중요하다. 토양과 통작물중 제초제의 잔류유해성은 토양, 기상, 제초제의 사용 및 작물재배 등의 조건에 따라 현저히 변화되나, 현 시점에서 토양중 제초제의 잔류에 대한 문제점은 후작물에 대한 영향과 같은 국부적인 것을 제외하고는 거의 없으며 농작물중 난류 또한 큰 문제가 없는 것으로 사료된다. 그러나 국민건강, 토양생태계를 비롯 환경에 대한 더 높은 안전성 확보를 위하여 제초제에 대한 모니터링실험과 같은 잔류성 조사가 더 많이 요구되며 사용자는 안전사용기준을 준수해야 하겠으며 제초제개발측면에서는 보다 저독성 약제를 개발하는데 최선을 다해야 하겠다.

• 한국초지조사료학회지
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• 제11권3호
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• pp.162-168
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• 1991

Iterbicide resduc. cauicd ~rljul-y to ovcrsown pasture grasses \\hen herbicide appliccl for use in pasturc est;~blish~nt~nt lo gro~vth contro! ol n;rtivc ~r ~:cds and shrubs. 'l'hih L~sperirnel~t was conducted to cv;lluati. (he herbicidr residue anti its ph!:totosical ~riiiuence on the growth of introtluccd pasturts species. Esperimcmtal soils was treated with buthitlazolc, ~ o d l ~ l m chlorate, glyphosatc. U-46 anti paraquat each at twt) applici~tion rates. Lhcf~1i.s glowl~mlc~ including othrr pasture grasses and le~urnes were evaluatrd for tolerance to herbicide. IIerbicide residue in the amount ot injury caused to introduced pasture grasses was found in order of buthidazole, sodium chlorate, U-46 and glyphosate. Euthidazole was not available for use in pasture establishment because of their long persist of toxic herbicide residues. A great stand redl~ction of subseq ~ ~ c n t oversown pastures was also observed In sodium chlorate treatment. However, normal vegetative stand and grass production was obtained, when thc pasture grasses seeded 45-60 days later herbicide treatments. Glyphosate did not affect subsequent oversown pasture species in both grasses and legumes. fistuccr arundinc~cea and Pou pratensis were the most tolerant pasture species to herbicide residue while 7'rzfi,lium pyatense and Medicugo suti~u showed a wsceptible response regardless of herbicide.

• 농약과학회지
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• 제5권1호
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• pp.19-23
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• 2001

수도용 제초제 butachlor의 작물잔류성을 조사할 목적으로 주산단지 및 광주, 대구, 부산지역의 시장에서 쌀, 보리, 마늘 양파, 딸기 등 106점의 시료를 채취하여 잔류량을 분석하였다. 제초제 butachlor가 등록되어 있는 작물의 수확물 중 쌀 27점과 보리 15점에서 butachlor가 검출되지 않았으며, 또한 벼 재배 후 이모작으로 재배되는 작물인 마늘21점, 양파 18점, 딸기 18점에서도 검출되지 않았다.

• 한국잡초학회지
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• 제13권4호
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• pp.234-249
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• 1993

제초제(除草劑)는 현대(現代) 농업(農業)에서 필수적인 농자재(農資材)이나 생리활성(生理活性)을 갖기에 비목적대상생물(非目的對象生物)에 대한 위해성(危害性)을 배제(排除)할 수 없다. 제초제(除草劑)의 문제점(問題點)중 잔류문제(殘留問題)는 가장 중요한 부분이며 그중 인간생활(人間生活)과 밀접한 관계(關係)를 갖는 토양(土壤), 농작물(農作物)중의 잔류(殘留)는 더욱 중요하다. 토양(土壤)과 농작물(農作物)중 제초제(除草劑)의 잔류분해성(殘留分解性)은 토양(土壤), 기상(氣象), 제초제(除草劑)의 사용(使用) 및 작물재배(作物栽培) 등의 조건(條件)에 따라 현저히 변화(變化)되나, 현(現) 시점(時點)에서 토양(土壤) 중 제초제(除草劑)의 잔류(殘留)에 대한 문제점(問題點)은 후작물(後作物)에 대한 영향(影響)과 같은 국부(局部)적인 것을 제외(除外)하고는 거의 없으며 농작물(農作物)중 잔류(殘留) 또한 큰 문제(問題)가 없는 것으로 사료(思料)된다. 그러나 국민건강(國民健康), 토양생태계(土壤生態系)를 비롯 환경(環境)에 대한 더 높은 안정성(安定性) 확보(確保)를 위하여 제초제(除草劑)에 대한 모니터링실험과 같은 잔류성(殘留性) 조사(調査)가 더 많이 요구(要求)되며 사용자(使用者)는 안전사용기준(安全使用基準)을 준수(遵守)해야 하겠으며 제초제개발측면(除草劑開發側面)에서는 보다 저독성(低毒性) 약제(藥劑)를 개발(開發)하는데 최선(最善)을 다해야 하겠다.

• Journal of Ginseng Research
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• 제20권1호
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• pp.101-105
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• 1996

Several attempts have been made to protect crops against injury from herbicide quinclorac residue in soil. In this experiment, a selection of suitable crops for bioassay of the residue and a reduction of phytotoxicity by treatment with active carbon were carried out to prevent or to counteract the phytotoxicity. Cucumber (Cuumts satims) and kidney bean (Phaseolus Mgaris) were the suitable indicator plant in points of a sensitivity to the herbicide residue and an easy cultivation. The phytotoxicity was able to be observed at 20 and 30 days after seeding on kidney bean and cucumber respectively. In pot trials, application of the active carbon at 50 kg/10a protected effectively the 2-year-old ginseng plant from the injury in a paddy soil where the herbicide had been treated at 3 g a. i./10a.

• 한국초지조사료학회지
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• 제11권2호
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• pp.46-46
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• 1991

Adequate regrowth control of weeds and shrubs has been one of the important problem for pasture establishment by overseeding on reclaimed forest hilly land. This experiment was carried out on sloping shrub land near Anseong, Gyeonggido to evaluate the effects of herbicide application on growth control of native weeds, shrubs and trees. We evaluated 63 different weeds and wood species in the trials, which are grown common in korean forest. Buthidazol and 4 other herbicides (sodium chlorate, glyphosate, U-46 and gramoxone) were sprayed each at two application rates during the period of the most intensive growth, on 20 July 45 days before overseeding of pasture species. Glyphosate and sodium chlorate gave excellant control of growth of all species. However. Uncus effusus, Carex heterostachya, Polygonatum humile, Rubus corchorifolius, Lonicera coeralea and Rhododendron mucronulatum were classified as a tolerant weed and wood species to herbicides. Herbicide buthidazol showed also successive control of regrowth of weeds and wood species. But buthidazol was evaluated as a none available herbicide for use in pasture establishment. because o! their long persist of toxic herbicide residue in soils after treatments. Herbicide U-46 and gramoxone had almost no effect on regrowth of shrubs and tree species

• 한국초지조사료학회지
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• 제11권2호
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• pp.76-83
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• 1991

Adequate regrowth control of weeds and shrubs has been one of the important problem for pasture establishment by overseeding on reclaimed forest hilly land. This experiment was carried out on sloping shrub land near Anseong, Gyeonggido to evaluate the effects of herbicide application on growth control of native weeds, shrubs and trees. We evaluated 63 different weeds and wood species in the trials, which are grown common in korean forest. Buthidazol and 4 other herbicides (sodium chlorate, glyphosate, U-46 and gramoxone) were sprayed each at two application rates during the period of the most intensive growth, on 20 July 45 days before overseeding of pasture species. Glyphosate and sodium chlorate gave excellant control of growth of all species. However. Juncus effusus, Carex heterostachya, Polygonatum humile, Rubus corchorifolius, Lonicera coeralea and Rhododendron mucronulatum were classified as a tolerant weed and wood species to herbicides. Herbicide buthidazol showed also successive control of regrowth of weeds and wood species. But buthidazol was evaluated as a none available herbicide for use in pasture establishment. because o! their long persist of toxic herbicide residue in soils after treatments. Herbicide 1:-46 and gramoxone had almost no effect on regrowth of shrubs and tree species.

• 한국약용작물학회지
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• 제24권3호
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• pp.237-245
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• 2016

Background: Cyanazine is used as a pre-emergent herbicide once during the growing season to control weeds of many upland crops worldwide. This study aimed to establish a method to determined cyanazine residue levels in major medicinal crops by using high performance liquid chromatography-UV detection/mass spectometry (HPLC-UVD/MS). Methods and Results: Cyanazine residue was extracted with acetone from the raw products of four representative medicinal plants - Scutellaria baicalensis, Paeonia lactiflora, Platycodon grandiflorum and Angelica gigas. The extract was diluted with a large volume of saline water and directly partitioned into dichloromethane to remove polar co-extractives in the aqueous phase. It was then purifined using optimized Florisil column chromatography. HPLC analysis conducted using an octadecylsilyl column allowed the successful separation of cyanazine from co-extractives of the samples, and the amount was sensitively quantified by ultraviolet absorption at 225 nm with no interference. The accuracy and precision of the proposed method were validated by conducting recovery experiments on each medicinal crop sample fortified with cyanazine at two concentration levels per crop in triplicate. Conclusions: The mean recoveries ranged from 91.2% to 105.3% for the four representative medicinal crops. The coefficients of variation were less than 10%, irrespective of the sample types and fortification levels. The limit of quantification of cyanazine was 0.02 mg/kg as verified by the recovery experiment. A confirmatory method was performed by liquid chromatography/MS using selected-ion monitoring technique to clearly identify the suspected residue.

• Journal of Ginseng Research
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• 제20권1호
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• pp.96-100
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• 1996

In this experiment, germination test of ginseng seed and growth test of two year old ginseng in soil incorporated with quinclorac (3,7-Dichloro-8-quinoline carboxylic acid) were conducted to evaluate phytotoxicity caused by quinclorac residue in soil. Ginseng seed germiilation was hardly affected, but growth of ginseng seedling was retarded by quinclorac. The phytotoxicity of quinclorac on ginseng seedling was expressed at the lowest level tested, 3.75 g a.i./10a (118 of recommended rate for rice cultivation). The representative phytotoxicity in ginseng were decreased root weight, shortened leaf width and leaf length, and weak lateral root Quinclorac residue decreased by 1/4 in pot soil after 2 months and below 2 ppm in the paddy soil applied at usual rate (30 g a.i./10a) after 1∼ 2 years. Below 2 ppd ginseng did not show any phytotoxicity symptom.

• 농약과학회지
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• 제4권4호
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• pp.35-39
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• 2000

국내 농업환경 중 농약지표 설정을 위해 16개 지대 29지역 100농가를 대상으로 수도 재배용 농약 실제 사용량을 조사 분석하였다. 또한 농약별 실제 사용량에 따른 잔류 경향을 알아보고자, 조사농가에서 재배된 벼의 현미 및 볏짚 중 농약잔류량을 분석하였다. 수도재배시 용도별 농약 실제 사용량은 살충제 43%, 제초제 29%, 살균제 27%를 나타냈으며, 살충제 중 주요 사용농약은 carbofuran, BPMC, cartap 등이었다. 제초제는 혼합제인 molinate+pyrazosulfuran-ethyl과 butachlor, 살균제의 경우 IBP와 혼합제 isoprothiolan+tricyclazole이 우선적으로 사용되었다. 제형별 농약사용량은 입제농약 위주의 사용경향을 나타냈으며 GR>DP>WP>EC>FG>SP 순이었다. 수도재배 단위면적당(a.i./ha) 농약사용량은 7.13 kg이었으며, 전국 총 사용량을 추산한 결과 8,387 M/T로 추정되었다. 용도별 농약 실제 사용량과 출하량과의 일치도는 살충제 84.3%, 제초제 77.8%, 살균제 94.7%로 나타났고 총 실물량 일치도는 97%이었다. 농약 실제 사용량에 따른 농약잔류성은 살균, 살충제로서 사용 빈도가 높은 농약인 BPMC와 IBP가 $57.7{\sim}94.9%$의 높은 검출빈도를 나타냈으며, 이들 농약의 잔류수준은 허용기준 미만이었다.