• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.7
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• pp.72-79
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• 2019

Concrete is vulnerable to cracks due to volume changes caused by temperature changes, shrinkage during curing, external forces, or poor construction. In particular, concrete placed in electric power tunnel structures can generate cracks by a variety of factors. As a result, these tunnel structures require continuous maintenance. In this study, we investigated the mechanical properties of electric power tunnel concrete using alpha-calcium sulfate hemihydrate, which is an industrial byproduct that has excellent expansion performance. To compensate for the decrease in compressive strength when substituting alpha-calcium sulfate hemihydrate, based on previous research, we added 9% alpha-calcium sulfate hemihydrate and adjusted the amount of admixture while using the same amount of cement. We then evaluated the mechanical properties of the concrete. The results showed that the compressive strength of the concrete was higher than that of ordinary Portland cement (OPC), and the shrinkage of concrete was reduced by more than 30% compared to that of OPC. Therefore, adding 9% of alpha-calcium sulfate hemihydrate is expected to have a significant effect in reducing concrete cracks.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.1
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• pp.25-32
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• 2024

In this study, the mechanical properties of PHC pile concrete using alpha-type hemihydrate gypsum were evaluated. As the replacement ratio of alpha-type hemihydrate gypsum increased, the setting time rapidly accelerated. In particular, when replacement ratio exceeded 20 %, the setting time was shortened due to rapid hydration reaction, making it impossible to secure working time. As the replacement ratio of alpha-type hemihydrate gypsum increased, the ettringite and gypsum peaks tended to increase, and it is believed that the shrinkage of concrete decreased due to the increase in the ettringite peak. At a As the replacement ratio of 5 to 15 % for alpha-type hemihydrate gypsum, the compressive strength increased or was found to be equivalent to that of OPC. But at 20 % substitution, workability deteriorated due to rapid setting, so use of the 5 to 15 % range is considered appropriate.

• Journal of the Korean Chemical Society
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• v.52 no.6
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• pp.622-629
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• 2008

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.432-436
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• 2001

In this study, calcium sulfate(gypsum) powder was obtained using waste sulfuric acid and stainless refinery sludge by- produced from chemical reagent and the iron industry, by the neutralization of waste sulfuric acid. As variables for the experiment the mole ratio of the H$_2$SO$_4$ : Ca(OH)$_2$, the pH, the reaction temperature and time, the amount of catalyst were used. The crystal shape and microstructure of obtained powder were observed by XRD and SEM, and the thermal property was investigated by DTA. As the NaCl is added 0~20wt% as a catalyst to the H$_2$SO$_4$ : Ca(OH)$_2$, system it can be found that the crystal shape goes through the processes as follows : gypsum dihydratlongrightarrowgypsum hemihydrate＋gypsum dihydratelongrightarrowgypsum hemihydrate. And gypsum hemihydrate is $\beta$-type as the result of DTA. As waste sulfuric acid and stainless refinery sludge were used, the pH of reacted solution (which was 0.8) was rapidly raised up to 8~9 by the addition of stainless sludge and gypsum dihydrate was produced as a by-product. Therefore, it was found that stainless refinery sludge is sufficiently applicable for the neutralization of waste sulfuric acid.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10a
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• pp.351-354
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• 2000

In recent years, the world development of alternative construction materials is associated with disposal problems of waste materials as a result of industrial activities. Technologies of refining gypsum to several gypsum modifications ($\alpha$ and $\beta$-hemihydrate) which can be used as construction material in a large scale do actually exist or are under development. This paper provides a technical and economic perspective of the waste gypsum treatment. Especially, several applications particularly of $\alpha$-hemihydrate will be presented, e.g. artificial gypsum aggregate and light-weight masonry units.

• Journal of the Korea Institute of Building Construction
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• v.11 no.2
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• pp.181-188
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• 2011

Spalling must be considered when designing high-strength concrete to cope with fire. This study investigates the temperature rise of steel bar in high-strength concrete coated with fireproof mortar using gypsum exposed to fire. It was found that fireproof mortar using gypsum is more effective in constraining the temperature rise of steel bar in the high strength concrete than fireproof mortar using cement, and that the thinner the cover depth of the fireproof mortar, the more significant the influence of the gypsum. In addition, while there was no difference between ${\alpha}$-hemihydrate mortar and ${\beta}$-hemihydrate mortar on the temperature rise of steel bar, the compressive strength of ${\alpha}$-hemihydrate mortar is higher than that of ${\beta}$-hemihydrate mortar.

• Applied Chemistry for Engineering
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• v.17 no.6
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• pp.619-624
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• 2006

This study was performed to investigate the formation process of calcium sulfate ${\alpha}$-hemihydrate from FGD gypsum produced at thermal power plant burning bituminous coal. The experimental results showed that calcium sulfate $\alpha$-hemihydrate with a large aspect ratio was produced in the temperature range of $120^{\circ}C$ and $140^{\circ}C$ in the absence of additives through dissolution-recrystallization mechanism. It was also observed that addition of Na-succinate as a catalyst changed crystal shape from acicular to prismatic, resulting in decreased water/powder ratio down to 33%. Optimum concentration of Na-succinate was 20mM. It was confirmed that the optimum moulding pressure and moisture content of moulded body from FGD gypsum were $30kg_f/cm^2$ and between 10% and 15% respectively, which prevent moulded body from collapsing and maximize the capillary effect by given pore volume while autoclaving.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.158-159
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• 2014

In general, the shrinkage occurring in the floor mortar is large the influence by the dry shrinkage. In order to reduce the cracks occurring in the floor mortar, studies of physical methods are often performed, but these methods is difficult to prevent cracking of the floor mortar essentially. Therefore, in this study, the dry shrinkage properties of floor mortar of gypsum and red clay type using alpha-hemihydrate gypsum had been evaluated. The experimental variables were cement mortar(CM), gypsum mortar(GM), red-clay mortar(RM), the evaluation items was conducted experiment to evaluate the setting time, the compressive strength, drying shrinkage cracks, the dry shrinkage. As a result, it was confirmed that condensation time of GM is shorter that that of CM, and GM satisfied the compressive strength of the floor mortar standard. Also shrinkage deformation of GM reduced more than the CM.

• Journal of the Korean Ceramic Society
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• v.25 no.3
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• pp.300-306
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• 1988

The catalytic effect of salts on formation of ${\alpha}$-calcium sulfate hemihydrate under water vapor at atmospheric pressure was studied and the formation of q-calcium sulfate hemilydrate from by-product gypsum of phosphoric acid process was investigated. The order of catalytic effect of salts are as follow: Ammonium chloride>Sodium succinate>Calcium chloride>Sodium tartrate>Magnesium chloride The prismatic crystals was formed when ammonium chloride, calcium chloride and magnesium chloride was added, whereas the needle crystals was formed when sodium tartrate was added. Ammonium chlorideis most successful in catalytic effects in formation of ${\alpha}$-calcium sulfate hermihydrate for the by-product gypsum of phosphoric acid process.

• Magazine of RCR
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• v.4 no.4
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• pp.50-53
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• 2009