• Title/Summary/Keyword: heavy metal Pb

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Heavy Metal Analysis in Fresh Water Shellfishes of the Kum River System (금강수계에 서식하는 담수패류의 중금속 함량에 관하여)

  • 김덕만;김형석
    • The Korean Journal of Malacology
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    • v.7 no.1
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    • pp.66-75
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    • 1991
  • 금강수위에 서식사는 패류의 중금속함량을 알아 보기 위하여 1001년 4월부터 동년 10월사이에 우기를 피하여 금강유역에서 8개 지소를 임으 선택하여 채집한 8종의 부족류 중 비교적 각 지역에서 공통적으로 채집될 수 있었던 말조개와 채첩을 각각 10개체씩 선택하여 패를 아가미, 외투막, 폐각근, 족근 및 내장기관등 각 부위별롸 나누어 Cd, Cu, Pu, Zn의 함량을 원가흡광법으로 분석하여 다음과 같은 결론을 얻었다.1. 각 부위별 중금속 함량을 전체적으로 본 평균값은 Zn을 제외하고는 전체 패류의 내장부위가 모두 다른 어느 부위보다도 매우 높은 함량을 나타냈으며, 그 다음은 지역에 따라 다소의 차이는 있언ㅆ지만 대부분 외투막과 아가미, 족근, 폐각근의 순으로 나타났다.2. 각 패류별 중금속 함량은 역시 Zn만을 제외하고는 상류로부터 하류로 내려감에 따라 중금속 함량이 높아지는 경향을 보였다.3. 여러 금속 중 Zn만이 각 부위별에서 내장부위보다 아가미, 외투막에서 비교적 높은 값을 볼 수 있었으며, 일반적으로 다른 중금속은 하류보다 상류가 그 함량이 적은 경향을 보였으나, Zn만은 상류족에서 비교적 높은 함량을 보였고, 지역에 따라 그 함량이 다른 경향을 나타내었다. Zn 다음의 중금속함량은 Cu, Pb, Cd의 순으로 그 농도를 나타내었다.

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Rainwater Quality Variations for the Effective Usage (효율적 우수이용을 위한 초기우수의 수질변화)

  • 이창수;지홍기
    • Journal of Environmental Science International
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    • v.12 no.3
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    • pp.275-279
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    • 2003
  • A water quality analysis of rainwater collected from catchment equipment(2m${\times}$1m) was conducted to determine its suitability for domestic purposes, in this study. As the results of analysis, the pH of rainwater was 6.3${\pm}$0.3, and the turbidity of rainwater was over the 5 times than drinking water guidelines. For the usage of rainwater as the domestic and drinking water, the rainwater is need to treat. The analysis value of BOD was about 3 mg/L and the values of heavy metal as the Pb, Cd, Fe, Mn, Cr$\sub$6/$\^$+/and Cu was satisfied with drinking guidelines. Overall results of analysis support the possibility of rainwater as the domestic and drinking water.

Manufacturing of 2025 Coin Type PAn/Li-Al Secondary Battery (2025 Coin형 PAn/Li-Al 2차전지의 제조)

  • Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.202-206
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    • 1990
  • The existing batteries such as lead acid battery and Nicad battery have been at serious issue, because heavy metal such as Pb and Cd give rise to environmental pollution. Therefor, when these material is changed over polymeric electroactive material, we expect environmental pollution will be prevented. We decided to develop 2025 coin type PAn/Li-Al secondary battery for goal of memory back-up battery. This report is concerned with manufacturing of 2025 coin type PAn/Li -Al secondary battery.

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World research trends and problems in papers relating metal contamination level of herbal medicines (한약 금속오염과 관련된 세계적인 인식경향 -발표된 논문을 중심으로-)

  • Lee Sun-Dong;Lee Jung-Seok;Park Kyung-Sik
    • Journal of Society of Preventive Korean Medicine
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    • v.6 no.1
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    • pp.117-128
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    • 2002
  • Metal problems in herbal medicine are not regulate properly by law and public management around world country until this time. General people belief as safety about herbal since natural material. And almost all persons can also purchase by their-self and use by self-prescription in reality. As this result herbal medicines can always occur acute and chronic toxicity by not proper use problems, side-effect and overdose. Heavy metal toxic diseases in historical view point was big accidents that didnot forget including minamata and itai-itai in Japan. These accident's teach to us must not use toxic metal level and not include or at least Pb Hg As Cd in all kind material use and intake by people, especially herbal. Herbal contamination research is beginner state that had not many papers until nowadays. Even if this pan had some papers, it had negative result and bigger and larger than problems level because of one way research trend of not many sample case-report and screening test of dried herbal form in chiefly. Many persons have afraid and risk thinking about herbal, animal and minerals since these cause. Further research related this subject will be needed at fact of epidemiology including case-control and cohort study for more precision research affecting in short and long term intake of oriental medicines

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Synthesis and Cations Binding Properties of a New C,N-bipyrazolic Ligand

  • Attayibat, Ahmed;Radi, Smaail;Ramdani, Abdelkrim;Lekchiri, Yahya;Hacht, Brahim;Bacquet, Maryse;Willai, Stephanie;Morcellet, Michel
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1648-1650
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    • 2006
  • The synthesis of a new C,N-bipyrazolic ligand with a functionalized donor-group is reported. The binding properties of the ligand and two other ligand of similar structures towards heavy metal ions ($Hg^{2+}$, $Cd^{2+}$, $Pb^{2+}$, $Zn^{2+}$, $Cu^{2+}$) and alkaline metal ions ($K^+$, $Na^{+}$, $Li^+$) were studied by a liquid-liquid extraction process and the extracted cation percentage was determined by atomic absorption measurements. The selectivity of the ligand to Hg(II) has been mentioned in the abstract.

Other Processed Products, Monitoring and the Exposed Dose Assessment of Heavy Metal, the Illegal Compounds (기타가공품의 중금속, 부정유해물질 모니터링 및 노출량 평가)

  • Jang, Jin-Seob;Kwon, Mun-Ju;Kim, Meyong-Hee;Park, Jin-Soo;Lim, Soo-Sun;Kwon, Sung-Hee;Song, Sung-Min;Yeo, Eun-Young;Hong, Seong-Hee;Kim, Jung-Im;Om, Ae-Son
    • Journal of Food Hygiene and Safety
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    • v.30 no.1
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    • pp.35-42
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    • 2015
  • This study was performed for both evaluating the safety of other processed products and providing basic information for making the general standard for contaminants in the category of other processed products. We analyzed the contents of three heavy metals, thirty six anti-impotence drugs and their analogues, three anti-obesity drugs and their analogues, twenty eight steroid drugs and their analogues, collecting in Incheon Metropolitan City. Any illegal compound was not detected in those products. However the contents of lead, cadmium and mercury of those products were at the range of 0.001-13.390 mg/kg, 0.03-1.231 mg/kg and 0.001-0.650 mg/kg respectively. Because there are no standards of heavy metals against other processed products, we compared the analytical results with relevant standards of both S. Korea and foreign countries. As a result, two products exceeded the relevant standards of lead, and other two products exceeded the relevant standards of mercury. The relative hazards compared to PTWI of FAO/WHO (Codex), Seafoods-pajeonmix, Perilla seed powder exceeded PTWI standards 0.214. The compulsory standards of each food product are determined by the category of the products. Because there is no standard of heavy metals in the category of other processed products in S. Korea, any food products registered as other processed product by manufacturer are free with those standards. Abusing similar problems on the categorization of food products could cause consumers' health problem. To prevent these problems, detail regulations on the categorization of food products have to be introduced.

Assessment of Particle Size Distribution and Pollution Impact of Heavy metalsin Road-deposited Sediments(RDS) from Shihwa Industrial Complex (시화산업단지 도로축적퇴적물의 입도분포 및 중금속 오염영향 평가)

  • Lee, Jihyun;Jeong, Hyeryeong;Ra, Kongtae;Choi, Jin Young
    • Journal of Environmental Impact Assessment
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    • v.29 no.1
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    • pp.8-25
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    • 2020
  • Industrialization has increased the production of road-deposited sediments (RDS) and the level of heavy metals in those RDS, which can have a significant impact on the surrounding aquatic environments through non-point pollution. Although the relationship between contamination characteristics and particle size of RDS is important for pollution control, there is very little information on this. In this study, we investigated the characteristics of grain size distribution and heavy metal concentrations in the road-deposited sediments (RDS) collected from 25 stations in Shihwa Industrial Complex. The environmental impact of RDS with particle size is also studied. Igeo, the contamination assessment index of each metal concentration, represents the RDS from Shihwa Industrial Complex are very highly polluted with Cu, Zn, Pb and Sb, and the levels of those metals were 633~3605, 130~1483, 120~1997, 5.5~50 mg/kg, respectively. The concentrations of heavy metals in RDS increased with the decrease in particle size. The particle size fraction below 250 ㎛ was very dominant with mass and contamination loads, 78.6 and 70.4%, respectively. Particles less than 125 ㎛ of RDS were highly contaminated and toxic to benthic organisms in rivers. RDS particles larger than 250 ㎛ and smaller than 250 ㎛ were contaminated by the surrounding industrial facility and vehicle activities, respectively. As a result of this study, the clean-up of fine particles of RDS, smaller than 125-250 ㎛, is very important for the control and reduction of non-point pollution to nearby water in Shihwa Industrial Complex.

A Study on the Development of Rapidly Hardening Grouting Method for the Effective Filling in the Underground Cavity (지하공동의 효율적 충전을 위한 급결 충전 그라우트공법개발에 관한 연구)

  • Kim, Soo-Lo;Kim, Tae-Heok;Shin, Dong-Chun;Kwon, Hyun-Ho
    • Tunnel and Underground Space
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    • v.19 no.6
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    • pp.534-544
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    • 2009
  • The collapse of the underground cavity can cause the abrupt local subsidence of the ground surface. It can be hazardous to the stability of road and building for human activity. Therefore it is necessary to develop reinforcement methods for the filling of the underground cavity. This study was executed to improve the material quality and systems to fill the calcium-aluminate mineral $(C_{12}A_7)$ environmentally, and minimize the loss of filling materials for the steep underground cavity. Filling material which was developed in this study is composed of rapid hardening material and additives. The developed material had rapid hardening and non-separation ability in the water cavity condition, so it made the effective underground dam in the cavity with prevention of material loss when it was poured in the water cavity. Results of heavy metal leaching test for environmental assessment showed that it was environmentally suiTable material for the filling in the mine cavity.

Blood Heavy Metal Concentrations of Korean Adults by Seafood Consumption Frequency: Using the Fourth Korea National Health and Nutrition Examination Survey (KNHANES IV), 2008 (국민건강영양조사 제4기 2차년도 (2008)를 이용한 어패류 섭취빈도에 따른 한국 성인의 혈중 중금속 농도 조사)

  • Kim, Young-A;Kim, Young-Nam;Cho, Kyung-Dong;Kim, Mi-Young;Kim, Eun-Jin;Baek, Ok-Hee;Lee, Bog-Hieu
    • Journal of Nutrition and Health
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    • v.44 no.6
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    • pp.518-526
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    • 2011
  • To determine blood heavy metal concentrations by seafood consumption in Korean adults, blood cadmium, mercury, and lead concentrations in a representative sample of 1,709 Koreans participated in the Fourth Korea National Health and Nutrition Examination Survey (KHANES IV-2) in 2008 were analyzed by age and seafood consumption frequency. The mean blood cadmium, mercury, and lead concentrations were $1.14{\pm}0.73{\mu}g/L$, $5.50{\pm}3.83{\mu}g/L$, and $2.56{\pm}1.22{\mu}g/dL$, respectively. The subjects aged ${\geq}$ 50 years had significantly higher blood cadmium concentrations than the subjects aged 20~39 years. Blood mercury concentrations of the 50's were significantly higher than those of the 20's and 30's (p < 0.05). Approximately, 43% of males and 22% of females had blood mercury concentrations > $5.8{\mu}g/L$ which is a blood mercury level equivalent to the current Reference Dose. Only 2 subjects had lead concentrations > $10{\mu}g/dL$, the standard lead level by the Centers for Disease Control and Prevention, USA. The subjects consuming pollack, mackerel, anchovy, corvina, shellfish, and salted seafood at least once a week had significantly higher mercury concentrations than the subjects consuming those seafoods less than once a month. However, there were no clear relationships between blood cadmium and lead concentrations and seafood consumption frequencies.

Elution Characteristics of Arsenic, Cadmium, Copper and Lead in Paddy Soil Nearby Mining Area Using Two Kinds of Extractant (두 가지 추출제를 이용한 광산지 인근 농경지 토양 중 비소, 카드뮴, 구리, 납의 용출 특성 평가)

  • Kwon, Jicheol;Lee, Goontaek;Jung, Myungchae;Kim, Jeong-wook;Yoon, Jeong-ki;Kim, Hyun-Koo;Kim, Ji-in;Lee, Honggil;Kim, Inja;Kim, Taeseung;Kang, Jiyoung
    • Journal of Soil and Groundwater Environment
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    • v.24 no.6
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    • pp.1-8
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    • 2019
  • This study evaluated the relative extraction ratio (RER) of As and heavy metals (Cd, Cu and Pb) in paddy soils using the two types extractant, 0.05 M EDTA and 0.43 M HNO3. The RER was calculated by dividing the concentrations of metals obtained by 0.05 M EDTA or 0.43 M HNO3 extraction by those obtained by aqua regia extraction. The RER of 0.43 M HNO3 was larger than that of 0.05 M EDTA. Correlation analysis indicated there was statistically significant correlation (p<0.001) between the concentration in aqua regia and 0.05 M EDTA or 0.43 M HNO3. Especially, Cd showed the higher correlation than other metals. Stepwise multiple linear regression analyses indicated soil pH, CEC, organic matter content, and soil texture all influenced the metal extraction rates and bioavailability of the metals.