• Journal of Electrochemical Science and Technology
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• v.12 no.4
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• pp.387-397
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• 2021

Deep eutectic solvents have been established as feasible metal electroplating solvent alternatives over traditional toxic aqueous plating baths. However, water, either added intentionally or unintentionally, can significantly influence the solvent's physical properties and performance, thereby hindering its industry application. In this study, the hygroscopicity, or the ability to absorb moisture from the environment, of synthesized ethaline (1:2 choline chloride:ethylene glycol) was investigated. The kinematic viscosity, electrical conductivity, electrochemical window, and water content of ethaline were monitored over a 2-week period. Karl Fischer titration tests showed that ethaline exposed to the atmosphere displayed significant hygroscopicity compared to its unexposed counterpart. ¹H NMR spectroscopy revealed that water vapor was readily absorbed at the surface due to the hydrophilic groups present in the ethaline molecule. Water uptake resulted in the decrease in viscosity, increase in electrical conductivity and narrowing of the electrochemical window of ethaline. Solution heating at 100℃ removed the absorbed moisture and allowed the recovery of the solvent's initial properties.

• Steel and Composite Structures
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• v.43 no.5
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• pp.673-688
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• 2022

Post-earthquake fire is a major threat since most structures are designed allowing some damage during strong earthquakes, which will expose a more vulnerable structure to post-earthquake fire compared to an intact structure. A series of experimental research on steel-concrete composite beam-to-column joints subjected to fire after cyclic loading has been carried out and a clear reduction of fire resistance due to the partial damage caused by cyclic loading was observed. In this paper, by using ABAQUS a robust finite element model is developed for exploring the performance of steel-concrete composite joints in post-earthquake fire scenarios. After validation of these models with the previously conducted experimental results, a comprehensive numerical analysis is performed, allowing influential parameters affecting the post-earthquake fire behavior of the steel-concrete composite joints to be identified. Specifically, the level of pre-damage induced by cyclic loading is regraded to deteriorate mechanical and thermal properties of concrete, material properties of steel, and thickness of the fire protection layer. It is found that the ultimate temperature of the joint is affected by the load ratio while fire-resistant duration is relevant to the heating rate, both of which change due to the damage induced by the cyclic loading.

• Geomechanics and Engineering
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• v.33 no.1
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• pp.65-75
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• 2023

Recycled concrete aggregate (RCA) is widely used as a construction material in road construction, concrete structures, embankments, etc. However, it has been reported that calcite (CaCO₃) precipitation from RCA can be a cause of clogging when used in drainage applications. An accelerated calcite precipitation (ACP) procedure has been devised to evaluate the long-term geochemical performance of RCA in subsurface drainage systems. While the ACP procedure was useful for the French Drain application, there remained opportunities for improvement. In this study, key factors that control the formation of calcite precipitation were quantitatively evaluated, and the results were used to improve the current prototype ACP method. A laboratory parametric study was carried out by investigating the effects of reaction temperature and time on the formation of calcite precipitation of RCA, with determining an optimum reaction temperature and time which maximizes calcite precipitation. The improved ACP procedure was then applied to RCA samples that were graded for Type I Underdrain application, to compare the calcite precipitation. Two key findings are (1) that calcite precipitation can be maximized with the optimum heating temperature (75℃) and time (17 hours), and (2) the potential for calcite precipitation from RCA is not as significant as for limestone. With the improved ACP procedure, the total amount of calcite precipitation from RCAs within the life cycle of a drain system can be determined when RCAs from different sources are used as pipe backfill materials in a drain system.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.3
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• pp.286-291
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• 2023

Perovskite materials are promising candidates for next-generation optoelectronic devices owing to their outstanding external quantum efficiency, high color purity, and ability to tune the light emission wavelength. However, conventional thermal annealing processes caused the degradation of perovskite, resulting in poor optoelectronic properties and a short lifetime. Herein, we propose a laser-induced recrystallization of perovskite thin film to enhance its light-emitting properties. Laser-induced recrystallization process was performed using rapid and instantaneous laser heating, which successfully induced grain growth of the perovskite material. The laser processing conditions were thoroughly optimized based on theoretical calculations and various material analyses such as x-ray diffraction, scanning electron microscope, and photoluminescence spectroscopy.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.1
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• pp.1-10
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• 2024

Direct use of sunlight through the glass windows is an efficient way to reduce the energy consumption related to the heating, cooling, and lighting. Introduction of near-infrared modulating properties through colloidal doped metal oxide nanocrystals into the classical electrochromic materials accelerates the development of next-generation electrochromic devices. There has been a steady enhancement in the performance of electrochromic devices, necessitating a review of the recent progress in next-generation electrochromic devices employing doped metal oxide nanocrystals. This review provides an overview of the current developments in next-generation electrochromic smart windows utilizing colloidal doped metal oxide nanocrystals, with a focus on the key factors for achieving these advanced windows. Colloidal doped metal oxide nanocrystals are a crucial component in realizing and bringing to market the next generation of electrochromic windows, though further research and development are still required in this regard.

• New & Renewable Energy
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• v.19 no.4
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• pp.61-71
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• 2023

The necessity of energy utilization using livestock manure has been proposed with the decrease in domestic agricultural land. Livestock manure solid fuel has been investigated as a promising energy resource owing to its convenient storage and use in agricultural and livestock fields. Additional electricity production is possible through the integration of a biomass combustion boiler with the organic Rankine cycle (ORC). In this study, a mathematical system model of the cattle manure solid fuel boiler integrated with the ORC was developed to analyze the components' performance under variable operating conditions. A sensitivity analysis was conducted to confirm the electrical efficiency of the ORC turbine and the applicability of this system. The minimum required waste heat recovery rate was derived considering the system marginal price and levelized cost of electricity of the ORC. The simulation results showed that, in Korea, more than 77.98% of waste heat recovery and utilization in ORC turbines is required to achieve economic feasibility through ORC application.

• Journal of Navigation and Port Research
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• v.48 no.2
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• pp.125-136
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• 2024

This research presents an innovative integrated ethanol solid oxide fuel cell (SOFC) system designed for applications in marine vessels. The system incorporates an exhaust gas heat recovery mechanism. The high-temperature exhaust gas produced by the SOFC is efficiently recovered through a sequential process involving a gas turbine (GT), a regenerative system, steam Rankine cycles, and a waste heat boiler (WHB). A comprehensive thermodynamic analysis of this integrated SOFC-GT-SRC-WHB system was performed. A simulation of this proposed system was conducted using Aspen Hysys V12.1, and a genetic algorithm was employed to optimize the system parameters. Thermodynamic equations based on the first and second laws of thermodynamics were utilized to assess the system's performance. Additionally, the exergy destruction within the crucial system components was examined. The system is projected to achieve an energy efficiency of 58.44% and an exergy efficiency of 29.43%. Notably, the integrated high-temperature exhaust gas recovery systems contribute significantly, generating 1129.1 kW, which accounts for 22.9% of the total power generated. Furthermore, the waste heat boiler was designed to produce 900.8 kg/h of superheated vapor at 170 ℃ and 405 kP a, serving various onboard ship purposes, such as heating fuel oil and accommodations for seafarers and equipment.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.1091-1099
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• 2024

Fluoride-salt-cooled High-temperature Reactor (FHR) is a promising nuclear reactor technology. Among many challenges presented by the molten fluoride salts is the corrosion of salt-facing structural components. Higher moisture contents, in the FLiNaK (LiF-NaF-KF, 46.5-11.5-42 mol%) salt, aggravate intergranular corrosion and pitting for the given alloys. Therefore, several thermal dehydration tests of FLiNaK salt were performed with a batch size suitable for thermal-hydraulic experiments. Thermogravimetric Analysis (TGA) was performed for the three constituent fluoride salts individually. Preliminary thermal dehydration plans were then proposed for NaF and KF salts based on the TGA curves. However, the dehydration process may not be required for LiF since its low mass loss (<1.3 wt%). To evaluate the performance of these thermal dehydration plans, a batch-scale salt dehydration test facility was designed and constructed. The preliminary thermal dehydration plans were tested by varying the heating rates, target temperature, and holding time. The sample mass loss data showed that the high temperatures (>500 ℃) were necessary to remove a significant amount of moisture (>1 wt%) from NaF salt, while relatively low temperatures (around 300 ℃) with a long holding time (>10 h) were sufficient to remove most of the moisture from KF salt.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.51-52
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• 2023

Recently, heat island and dry island phenomena occur frequently due to land surface development and excessive energy consumption in urban areas. As a result, the surface temperature of the building and the entire temperature of its surroundings are increased, and as a result, the durability of the building is rapidly deteriorated. In order to suppress these causes, a method of maintaining the temperature of road heating wires was implemented as a temporary measure, but this did not predict climate change. Therefore, this study is a method to measure the compressive strength, density, and thermal conductivity of light weight concrete using waste glass foam beads. After fabricating a simple chamber, the temperature and humidity of the inside and outside were measured with an Arduino device in consideration of external factors. Therefore, if waste glass foam beads made through proper mixing are constructed in the urban center, the quality of the urban can be improved.

• Journal of the Korean Institute of Gas
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• v.14 no.1
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• pp.8-14
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• 2010

In this study, we experimentally investigated a compression ignition engine operated with Bio-diesel blended LPG fuel. In particular, the performance, emissions characteristics (including total hydrocarbon, carbon monoxide, nitrogen oxides, and carbon dioxides emissions), and combustion stability of a CI engine fueled with Bio-diesel blended LPG fuel were examined at 1500 rpm. The percentage of Bio-diesel in the fuel blend ranged from 20-60%. The results showed that stable engine operation was possible for a wide range of engine loads up to 40% Bio-diesel by mass. When the Bio-diesel content was increased, leading to a decrease in the lower heating value of the blended fuel, the cetane value increased, resulting in a advanced start of heat release. Exhaust emission measurements showed that THC and CO emissions were increased when using the blended fuel at low engine speeds due to partial burn from over-mixing. NOx emission was emitted less at lower loads and more at higher loads.