• Title/Summary/Keyword: heating curing

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Study of the Curing Reaction Rate of a Glass Fiber Reinforced Bisphenol-A (BPA) Epoxy Prepreg by Differential Scanning Calorimetry (DSC) (Differential Scanning Calorimetry (DSC)를 이용한 유리섬유 Bisphenol-A(BPA)계 에폭시 프리프레그의 경화 반응 속도 연구)

  • Kwon, Hyeon-Jin;Park, Hee-Jung;Lee, Eun-Ju;Ku, Sang-Min;Kim, Seon-Hong;Lee, Kee-Yoon
    • Composites Research
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    • v.31 no.1
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    • pp.30-36
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    • 2018
  • The curing behavior of glass fiber reinforced epoxy prepregs based on Bisphenol-A (BPA) was studied by differential scanning calorimetry (DSC). The total heat of reaction(${\Delta}H_{total}=280.3J/g$) was determined based on the results of the dynamic heating scanning experiments. Isothermal experiments were carried out at $110{\sim}130^{\circ}C$, and it was observed that the maximum conversion and the maximum reaction rate were increased as temperature increased. Also Kamal equation was applied to analyze autocatalytic reaction of epoxy prepregs. The higher temperatures, the greater reaction rate constants ($k_1$, $k_2$). Theoretical values were calculated by these reaction rate constants and compared with experimental values. And it was confirmed that they were in reasonable agreement. At the beginning of the reaction, the experimental data and theoretical prediction were shown the same tendency, but at the end of reaction, the experimental data were smaller than theoretical predicted values due to reaction rates controlled by diffusion.

Evaluation on the thermal performance of earth plastering utilizing eco-friendly materials (친환경재료를 활용한 흙미장의 단열성능 평가)

  • Yang, Jun-Young;Hwang, Hey-Zoo;Oh, Yang-Ki
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.85-88
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    • 2012
  • Lately, the scale of the primary energy consumption in Korea is ranked 10th in the world, and it takes up about 1.9% of the entire energy consumption in the world. And among total energy consumption in Korea, the ratio of the part corresponding to the residence or commercial buildings is about 30.5%. Also, with the increased interest in eco-friendly buildings, the production of eco-friendly building materials consisting of them also increases as well. However, since the process of their production generates much energy consumption, so this is being raised as a social problem. Therefore, this study suggests a method to improve thermal performance by using eco-friendly earth plastering materials and natural materials in order to reduce energy consumption in buildings. The experiment evaluated thermal performance by measuring the external and internal temperature of the curing after the plastering of 1cm in the wooden box of 30cm * 30cm * 30cm. As a result, there was difference in the order of powdered coal, pealite, chaff, and rice straw. Among them, powdered coal indicated excellent thermal performance. This will be the foundational research used to improve interior environment and reduce heating bills.

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Bonding of nano-modified concrete with steel under freezing temperatures using different protection methods

  • Yasien, A.M.;Bassuoni, M.T.
    • Computers and Concrete
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    • v.26 no.3
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    • pp.257-273
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    • 2020
  • Concrete bond strength with steel re-bars depends on multiple factors including concrete-steel interface and mechanical properties of concrete. However, the hydration development of cementitious paste, and in turn the mechanical properties of concrete, are negatively affected by cold weather. This study aimed at exploring the concrete-steel bonding behavior in concrete cast and cured under freezing temperatures. Three concrete mixtures were cast and cured at -10 and -20℃. The mixtures were protected using conventional insulation blankets and a hybrid system consisting of insulation blankets and phase change materials. The mixtures comprised General Use cement, fly ash (20%), nano-silica (6%) and calcium nitrate-nitrite as a cold weather admixture system. The mixtures were tested in terms of internal temperature, compressive, tensile strengths, and modulus of elasticity. In addition, the bond strength between concrete and steel re-bars were evaluated by a pull-out test, while the quality of the interface between concrete and steel was assessed by thermal and microscopy studies. In addition, the internal heat evolution and force-slip relationship were modeled based on energy conservation and stress-strain relationships, respectively using three-dimensional (3D) finite-element software. The results showed the reliability of the proposed models to accurately predict concrete heat evolution as well as bond strength relative to experimental data. The hybrid protection system and nano-modified concrete mixtures produced good quality concrete-steel interface with adequate bond strength, without need for heating operations before casting and during curing under freezing temperatures down to -20℃.

Fabrication and Characterization of Cellulose Electro-Active Paper with Increased Thickness (두께를 증가시킨 셀룰로오스 Electro-Active Paper 의 제조와 특성평가)

  • Kim, Ki-Baek;Jung, Hyejun;Kim, Jaehwan
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.2
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    • pp.241-246
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    • 2013
  • This paper reports fabrication and characterization of cellulose Electro-Active Paper (EAPap) with increased thickness. Usual thickness of cellulose EAPap was $15{\mu}m$. This thickness needs to be increased to enhance the mechanical force output of EAPap. To fabricate thick cellulose EAPap, the fabrication process parameters including casting and drying processes should be investigated. In this paper, the casting thickness is increased from $800{\mu}m$ to $1500{\mu}m$, and heating times on a hot plate before and after curing process are introduced at 40 and $60^{\circ}C$ for 30 and 60 minutes, respectively. Thickness measurement, Thermal Gravitational Analysis (TGA), UV-transmittance, Young's modulus, and piezoelectric charge constant are measured. Heated EAPaps with increased thickness have similar TGA result, higher transmittance, higher Young's modulus and lower piezoelectric charge constant.

A Study on the Making of Slag Cement Clinker from Reduced and Modified Converter Slag (개질전로슬래그를 활용한 슬래그 시멘트 클링커 소성에 관한 연구)

  • Park Sun-Ku;Kim Young-Whan;Ko In-Yong
    • Resources Recycling
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    • v.11 no.6
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    • pp.24-30
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    • 2002
  • Reduced and modified converter slag was ball milled and sieved to -200/+325 mesh. CaO,$SiO_2$, $Fe_2$$O_3$ was added to slag powder and mixed to make it similar to the composition of normal portlant cement. The pellet made of this powder was heated from $1250^{\circ}C$ to $1450^{\circ}C$ for 15 min~45 min. Most feasible condition for making slag cement clinker is the heating more than 20 min at $1450^{\circ}C$. The compressive strength of the mortar made of this slag cement clinker was better than that of normal port-lant cement in long time curing.

UV/Thermal Hybrid Nanoimprint System for Flexible Substrates (유연기판을 위한 UV/Thermal 하이브리드방식 나노임프린트 시스템)

  • Lim, Hyung-Jun;Lee, Jae-Jong;Choi, Kee-Bong;Kim, Gee-Hong;Ahn, Hyun-Jin;Ryu, Ji-Hyeong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.3
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    • pp.245-250
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    • 2011
  • An UV/thermal hybrid nanoimprint lithography system was designed and implemented for the pattern transfer to flexible substrates. This system can utilize a plate stamp, roll stamp, and film stamp. For all cases of using those stamps, this system is also switchable an UV or thermal nanoimprint lithography mode. This paper shows how to design the heating and UV curing plates and proposes how to change them easily. Because the pressure condition and the speed of the press roller varies by the characteristics of the stamp and substrate, all the parameters related to the nanoimprint lithography have to adjustable. Some transferred patterns are shown in this paper to verify the performance of the hybrid nanoimprint lithography system. The flexible substrates with nano-scale patterns on them will be key components for next generation technologies such as flexible displays, bendable semi-conductors, and solar cells.

Study on Mechanical Properties Modification of Styrene Butadiene Rubber Composites Filling with Graphene and Molybdenum Disulfide

  • Xu, Li Xiang;Sohn, Mi Hyun;Kim, Yu Soo;Jeong, Ye Rin;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.52-59
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    • 2019
  • Styrene-butadiene rubber (SBR) composites, incorporated with graphene, molybdenum disulfide and their hybrid in different filling ratio, were fabricated by a two roll-mill. The dispersion states of all the samples' matrix were employed by carbon black dispersion tester. The curing properties of the pre-vulcanized rubber composites were investigated, after molding by heating press machine, the tensile strength, storage modulus, friction coefficient, the swelling property had also been tested according to ASTM. The composite G1M10 (filling with 1 phr graphene and 10 phr molybdenum) showed the best mechanical properties and viscoelastic properties in this research with a better filler dispersion state and more compact matrix structure.

Effect of the Heating Temperature on the Alkali-activation Reaction of Calcined Kaolin Powder (열처리 카올린 분말의 알칼리활성화 반응에 미치는 가열온도의 영향)

  • Kim, Sung Gon;Song, Tae Woong
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.601-607
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    • 2012
  • The alkali-activation reaction of two types of typical kaolin calcined at various lower temperatures was investigated at room temperature and at elevated temperatures. For the assessment of the reactivity, the temperature increase and the setting time of pastes prepared with calcined kaolin and sodium/potassium hydroxide solution were measured. Unlike raw kaolin, calcined kaolin samples prepared at various temperature showed an alkali-activation reaction according to the different aspects of the changes in the mineral phases. The reactivity with alkaline solutions was exceedingly activated in the samples calcined at $600-650^{\circ}C$, but the reactivity gradually decreased as the temperature increased in a higher temperature range, most likely due to the changes in the crystal structure of the dehydrated kaolin. The activation effect of the calcination treatment was achieved at reaction temperatures that exceeded $60^{\circ}C$ and was enhanced as the temperature increased. The reactivity of the calcined kaolin with an alkaline solution was more enhanced with the solution of a higher concentration and with a solution prepared from sodium hydroxide rather than potassium hydroxide.

The Static Collapse Characteristics of CFRP Single and Double Hat Shaped Section Members according to the Interface Number for Lightweight (경량화용 CFRP 단일 모자형 부재와 CFRP 이중 모자형 부재의 계면수 변화에 따른 정적압궤특성)

  • Hwang, Woo-Chae;Cha, Cheon-Seok;Yang, In-Young
    • Journal of the Korean Society of Safety
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    • v.27 no.6
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    • pp.20-25
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    • 2012
  • Currently, the most important purpose in designing automobile is environment-friendly and safety performance aspect. CFRP(Carbon Fiber Reinforced Plastics) of the advanced composite materials as structure materials for vehicles, has a wide application in lightweight structural materials of air planes, ships and automobiles because of high strength and stiffness. In this study, experimental investigations are carried out for CFRP single and double hat shaped section member in order to study the effect of various stacking condition. They were cured by heating to the appropriate curing temperature($130^{\circ}C$) by means of a heater at the vacuum bag of the autoclave. The stacking conditions were selected to investigate the effect of the interface numbers. The CFRP single and double hat shaped section members which manufactured from unidirectional prepreg sheets were made of 8ply. The static collapse tests performed and the collapse mode and energy absorption capability were analyzed according to interface number.

Durability and mechanical performance in activated hwangtoh-based composite for NOx reduction

  • Kim, Hyeok-Jung;Park, Jang-Hyun;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Advances in concrete construction
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    • v.11 no.4
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    • pp.307-314
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    • 2021
  • Activated hwangtoh (ACT) is a natural resource abundant in South Korea, approximately 15.0% of soil. It is an efficient mineral admixture that has activated pozzolanic properties through high-temperature heating and rapid cooling. The purpose of this study is to improve a curb mixture that can reduce NOx outside and investigate durability performance. To this end, mortar curb specimens were manufactured by replacing OPC with ACT. The ACT substitution ratios of 0.0, 10.0, and 25.0% were considered, and mechanical and durability tests on the curb specimens were conducted at 28 and 91 days of age. Steam curing was carried out for three days for the production of curbs, which was very effective to strength development at early ages. The reduction in strength at early ages could be compensated through this process, and no significant performance degradation was evaluated in the tests on chloride attack, carbonation, and freezing and thawing. The mortar curb with an ACT of 10.0~25.0% replacement ratio exhibited clear NOx reduction through photocatalytic (TiO2) treatment. This is due to the increase in physical absorption through surface absorption and the photocatalyst-containing TiO2 coating. In this study, the reasonable range of the ACT replacement ratio for NOx reduction was quantitatively evaluated through a comprehensive analysis of each test.