• 한국세라믹학회지
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• 제34권4호
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• pp.399-405
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• 1997

With the increase of ZnO content, heat of hydration decreased. For specimens containing ZnO more than 0.6 wt.%, the compressive stength of cement cured for 28 days could not be measured because setting was not occurred. With the increase of ZnO content, Blaine specific surface area of cement was decreased and the residue of 45 ${\mu}{\textrm}{m}$ and 90 ${\mu}{\textrm}{m}$ was increased when cement was ground. That is, grindability became worse as ZnO increased in clinker. The difference of color as a function of ZnO content could not be observed, but in the excess of amount of ZnO added, color became more white and reddish yellow.

• 한국세라믹학회지
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• 제22권6호
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• pp.15-20
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• 1985

In the course of cement hydration it was found that the addition of polyvinyl alcohol(contracted as PVA. here after) only in the cement paste could more influence on the set-retardation the depression of heat evol-ution rate than that of montmorillonit only or PVA-montmorillonie intercalation complex (PMIC) due to the effective adsorption of PVA on cement particles. The improved mechanical strength by addition of montmorillonite and PMIC was observed remarkably up to 0.05wt% due to the decrease of macro-pores caused by lowed viscosity or the acceleration of hydration reaction.

• 한국세라믹학회지
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• 제19권3호
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• pp.187-192
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• 1982

N.B.R. latex was used as the admixture in order to improve the various properties of gypsum plaster which is widely used as the construction material. The influences of N.B.R. latex on the hydration of gypsum plaster were studied. The results obtained are summerized as follows; 1. The water/gypsum plaster ratio is decreased wth increasing amounts of surfactant (P.O.E. Nonyl Phenol Ether) as the additive. 2. It is the pore of large size (${\gg}$7500A) that is mainly decreased with increasing amounts of surfactant. 3. With the small amount of surfactant as the additive, the hydration was slightly retarded, but was gradually recovered with increasing amounts of surfactant, and their heat of liberation after 20 hours were nearly same.

• 도시과학
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• 제9권1호
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• pp.7-16
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• 2020

Application of nanomaterials to cementitious composites has been attempted with the rapid development of nanotechnology since the 1990s. Various nanomaterials such as carbon nanotube, graphene, nano-SiO₂, nano-TiO₂, nano-Al₂O₃, nano-Clay, and nano-Magnetite have been applied to cementitious composites to improve the mechanical properties and the durability, and to impart a variety of functionality. In-depth information on the effect of nanomaterials on the hydration reaction, the microstructure, and the mechanical properties of cementitious nanocomposites is provided in the present study. Specifically, this paper mostly deals with the previous studies on the heat evolution characteristics of cementitious nanomaterials at an early age of curing, and the pore and the compressive strength characteristics of cementitious nanocomposites. Furthermore, the effect of nanomaterials on the cementitious nanocomposites was systematically discussed with the reviews.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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• pp.465-466
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• 2010

In this paper, an integrated system is proposed which can evaluate both the early-age properties and durability performance of concrete structures. This integrated system starts with a hydration model which considers both Portland cement hydration and chemical reactions of supplementary cementing materials (SCM). Based on the degree of hydration of cement and mineral admixtures, the amount of reaction products, the early age heat evolution, chemically bound water, porosity, the early age short-term mechanical behaviors, shrinkage and early-age creep are evaluated as a function of curing age and curing conditions. Furthermore, the durability aspect, such as carbonation of blended concrete and chloride attack, are evaluated considering both the material properties and surrounding environments. The prediction results are verified through experimental results.

• 한국세라믹학회지
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• 제35권11호
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• pp.1227-1232
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• 1998

In order to prohibit the delay of early stage hydration activator Na2SO4 was added to Fly Ash blended ce-ment and its effects were investigated. Various measurements such as Compressive strength Heat of hy-dration Pore size distribution Hydration products Microstructure were evaluated and the results show that specimens of Fly Ash(50wt%) with 5% Na2SO4 dramatically improved the compressive strength because pozzolanic reaction of Fly Ash and the formation of ettringite make th microstructure denser than OPC and flyash cement paste.

• 한국건축시공학회지
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• 제23권3호
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• pp.251-260
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• 2023

비정형 건축물은 외부면이 다양한 곡선이기 때문에 비정형 거푸집은 맞춤제작되어 사용된다. 비정형 거푸집 제작에 있어 재활용이 가능한 Phase Change Material(PCM)과 곡률구현에 용이한 Ultra-High Performance Concrete(UHPC)가 사용된다. 그러나 PCM은 약 58~64℃가 융점이며, UHPC의 수화열로 PCM 거푸집이 손상될 수 있어 실험을 통해 형상을 확인한다. 실험은 제작한 PCM 거푸집에 Silicone sheet 3mm를 설치한 (A)와 설치하지 않은 (B) 거푸집에 UHPC를 타설한다. 실험결과 (A) 3.793mm, (B) 5.72mm가 측정되었으며, (B) 거푸집이 수화열에 취약한 것으로 분석되었다. 이러한 연구는 초고강도 비정형 패널 및 PCM 거푸집 제작 관련 기초자료로 활용될 것으로 기대된다.

• 한국산학기술학회논문지
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• 제11권3호
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• pp.1040-1046
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• 2010

급속경화 콘크리트의 가장 큰 단점은 단시간 내에 발생하는 급격한 수화발열 반응으로 인해 초기팽창이나 수축이 매우 크게 일어나 균열이 발생할 가능성이 높다는 것이다. 그러나 플라이 애시가 사용되면 콘크리트의 수화열을 낮출 수 있으므로 초기팽창과 수축을 현저히 줄일 수 있어 균열발생 억제에 효과적일 수 있다. 초속경 라텍스개질 콘크리트(VES-LMC)는 우수한 재료특성에도 불구하고, 재료 자체의 높은 수화열로 인해 균열이 발생하는 사례가 보고되고 있다. 따라서 본 논문에서는 플라이 애시를 VES-LMC에 적용할 수 있는 방법을 고안하여, 균열에 대한 안정성을 확보하기 위한 연구를 수행하였다. 울트라파인 플라이 애시(Ultra-Fine Fly Ash ; UFFA)를 사용하여 조기강도 저하의 단점이 극복된 조건에서, 초기 수화열을 낮추고 수축을 저감하여 균열안정성을 확보할 수 있도록 하였다. 실험결과 조기 압축강도는 UFFA 혼입률이 증가함에 따라 다소 감소하지만, 재령 28일 강도는 통계학적으로 유사한 것으로 나타났다. 초기수축 실험결과 UFFA가 단위시멘트량대비 15%에서 20%까지 치환되면 최대수축을 43~47%까지 줄일 수 있어 초기수축 억제에 매우 효과적이므로 균열에 대한 안정성을 확보할 수 있는 것으로 나타났다.

• 한국건축시공학회지
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• 제9권3호
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• pp.95-101
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• 2009

Constructing large-scale mat foundation mass concrete is increasing for the stability of building structure, because a lot of high rise building are being built in order to make full use of limited space. However, It is of increasing concerns that because limited placing equipments, available job-site and systems for mass concete placement in construction field do not allow to place great quantity of concrete at the same time in large scale mat foundation, consistency between placement lift can not be secured. And also, it is likely to crack due to stress caused by the difference of hydration heat generation time. To find out the solution against above problems, this study is to reconfirm the performance of normal concrete designed by mix proportion and super retarding concrete. The Fundamental test shows what happens if low heat proportioning and control method of setting time are applied at the job-site of newly constructed high rise building. The test result show that slump flow of concrete has been somewhat increased as the target retarding time gets longer, while the air content has been slightly decreased but this is no great difference from normal concrete. The setting time shows to be retarded as target retarding time gets longer, the range of retarding time increases. It is necessary to increase the amount of mix of super retarding agent in the proportion ration by setting curing temperature high since outdoor curing is about 6 hours faster than standard curing, which means the temperature of the concrete will be higher than the temperature of the surrounding environment, due to its high hydration heat when applying in a construction site. The compressive strength of super retarding concrete appears to be lower than normal concrete due to the retarding action in the early stage. However, as the time goes by, the compressive strength gets higher, and by the 28th day the strength becomes the same or higher than normal concrete.

• 한국터널지하공간학회 논문집
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• 제11권1호
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• pp.37-45
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• 2009

본 연구는 대형 대단면 터널 라이닝 구조물에 적용하기 위해 50 MPa급 고성능 콘크리트의 개발 및 적용을 위한 실험을 수행하였다. 이를 위해 플라이애쉬와 고로슬래그미분말을 1종 시멘트 단위량의 50%까지 치환한 8종의 배합을 선정하여, 8종의 배합의 역학적 특성에 관한 실험과 간이 단열온도 상승실험을 실시하였다. 또한 정량적인 평가를 위해 8종의 배합 중 1종 시멘트만을 사용한 배합(OPC) 및 2성분계 배합과 3성분계 배합중 각각 1종(BS30, F15S35)을 재선정하여 단열온도 상승실험과 Mock-up 실험을 수행하였다. 실물 부재 크기의 시험체의 수화열 측정결과는 유한요소해석과 비교하여 해석루틴의 신뢰도 향상을 기대할 수 있었다.