• Title/Summary/Keyword: heat evolution

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Color Enhancement of Natural Rubies by Annealing (천연루비의 열처리에 의한 향상 처리 연구)

  • Song Ohsung;Kim Sangyeob
    • Korean Journal of Materials Research
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    • v.15 no.4
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    • pp.252-256
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    • 2005
  • We removed the bluish of the natural ruby successfully by vacuum annealing, and measured the color evolution with annealing time and temperature. We varied the anneal temperature and time $800\~1500^{\circ}C$ and $3\~26$ hrs, respectively. The color evolution of rubies with annealing condition was recorded by a digital camera and a color coordination visible spectrometer. We determined the optimum bluish eliminating annealing condition was $1500^{\circ}C-3hr$, which conserving the natural inclusions. We suggest the bluish shrink with diffusion coefficient of $D=(5\times10^{-3}){\exp}(-200.000/RT)[cm^2/s]$. We propose the color of ruby may be determined as the identical red color if the color difference between two samples are less than 1.0, and the color difference nay be an auxiliary standard to evaluate the color of rubies.

A Study of tow-Power Density Laser Welding Process with Evolution of me Surface (자유표면변형을 고려한 저에너지밀도 레이저 용접공정 해석)

  • Ha Eung-Ji;Kim Woo-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.10
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    • pp.1202-1209
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    • 2004
  • In this study, numerical investigation has been performed on the evolution of weld pool geometry with moving free surface during low-energy density laser welding process. The free surface elevates near the weld pool edge and descends at the center of the weld pool if d$\sigma$/dT is dominantly negative. It is shown that the predicted weld pool width and depth with moving free surface are a little greater than those with flat weld pool surface. It is also believed that the weld pool surface oscillation during the melting process augments convective heat transfer rate in the weld pool. The present analysis with moving free surface should be considered when We number is very small compared to 1.0 since the deformation of the weld pool surface is noticeable as We number decreases.

A Unified Analysis of Low-Power and High-Power Density Laser Welding Processes with Evolution of Free Surface (자유표면변형을 고려한 저에너지밀도 및 고에너지밀도 레이저 용접공정 통합 해석)

  • Ha Eung-Ji;Kim Woo-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.10 s.241
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    • pp.1111-1118
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    • 2005
  • In this study, a unified numerical investigation has been performed on the evolution of weld pool and key-hole geometry during low-power and high-power density laser welding. Unsteady phase-change heat transfer and fluid flow with the surface tension are examined. The one-dimensional vaporization model is introduced to model the overheated surface temperature and recoil pressure during high-power density laser welding. It is shown that Marangoni convection in the weld pool is dominant at low-power density laser welding, and the keyhole with thin liquid layer and the hump are visible at high-power density laser welding. It is also shown that the transition from conduction welding to penetration welding fur iron plate exists when the laser power density is about $10^6W/Cm^2$.

Electrode Properties for Water Electrolysis of Hydrophilic Carbon Paper with Thermal Anneal (열처리된 친수성 카본 페이퍼 전극의 전기 물 분해 특성)

  • Yoo, Il-Han;Seo, Hyungtak
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.241-245
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    • 2016
  • Hydrogen is considered a potential future energy source. Among other applications of hydrogen, hydrogen-rich water is emerging as a new health care product in industrial areas. Water electrolysis is typically used to generate a hydrogen rich water system. We annealed 10AA carbon paper in air to use it as an electrode of a hydrogen rich water generator. Driven by annealing, structural changes of the carbon paper were identified by secondary electron microscope analysis. Depending on the various annealing temperatures, changes of the hydrophilic characteristics were demonstrated. The crystal structures of pristine and heat-treated carbon paper were characterized by X-ray diffraction. Improvement of the efficiency of the electrochemical oxygen evolution reaction was measured via linear voltammetry. The optimized annealing temperature of 10AA carbon paper showed the possibility of using this material as an effective hydrogen rich water generator.

Radiation-Induced Oscillatory Instability in Diffusion Flames (복사 열손실로 인한 확산 화염의 맥동 불안정에 관한 연구)

  • Sohn, Chae Hoon;Kim, Jong Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1185-1191
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    • 1999
  • Radiation-induced oscillatory instability in diffusion flames is numerically investigated with nonlinear dynamics considered. As the simplest flame model, a diffusion flame established in the stagnant mixing layer is employed with optically thin gas-phase radiation and unity Lewis numbers for all species. Attention is focused on the radiation-induced extinction regime, which occurs at large $Damk\ddot{o}hler$ number. Once the steady flame structure is obtained for a prescribed value of the initial $Damk\ddot{o}hler$ number, transient solution of the flame is calculated after a finite amount of the $Damk\ddot{o}hler$-number perturbation is imposed on the steady flame. Transient evolution of the flame exhibits three types of flame-evolution behaviors, namely decaying oscillatory solution, diverging solution to extinction and stable limit-cycle solution. A dynamic extinction boundary is identified for laminar flamelet library.

Thermal Dissipation Characteristics of Multi-Chip LED Packages (멀티 칩 LED 패키지의 방열 특성)

  • Kim, Byung-Ho;Moon, Cheol-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.25 no.12
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    • pp.34-41
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    • 2011
  • In order to understand the thermal performance of each LED chips in multi-chip LED package, a quantitative parametric analysis of the temperature evolution was investigated by thermal transient analysis. TSP (Temperature Sensitive Parameter) value was measured and the junction temperature was predicted. Thermal resistance between the p-n junction and the ambient was obtained from the structure function with the junction temperature evolution during the cooling period of LED. The results showed that, the thermal resistance of the each LED chips in 4 chip-LED package was higher than that of single chip- LED package.

Growth of Elongated Grains in $\alpha$'-Sialon Ceramics ($\alpha$'-Sialon 세라믹스에서의 주상형 입자성장)

  • 신익현
    • Journal of Powder Materials
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    • v.6 no.3
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    • pp.246-250
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    • 1999
  • The effects of the ${\beta}-Si_3N_4$ starting particle size and $\alpha$/$\beta$ phase transformation during sintering process on the microstructure evolution of Yttrium $\alpha$-Sialon ceramics were investigated. As-received ${\beta}-Si_3N_4$ powder (mean particle size: 0.54$\mu$m) and classified ${\beta}-Si_3N_4$ powder(mean particle size: $0.26\mu{m}$) were used as starting powders. With decreasing the starting particle size, the growth of elongated grains was enhanced, which resulted in the whisker -like microstructure with elongated grains. These results were discussed in relation to the two-dimensional nucleation and growth theory. In the specimen heat treated at $1600^{\circ}C$ for 10h before sintering at $1950^{\circ}C$for 1h under 40atm(2-step sintering), the grain size was smaller than of the 1-step sintering at 195$0^{\circ}C$ for 1h. However, bimodal microstructure evolution were not not remarkable in both sample, which is ascribed to the $\alpha$-phase contents existing in ${\beta}-Si_3N_4$ starting powder.

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Effect of Simetryne on Chloroplast-Mediated Electron Transport and Photoacoustic Signal (엽록체의 전자전달과 광음향 신호에 미치는 Simetryne의 영향)

  • 김현식
    • Journal of Plant Biology
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    • v.31 no.3
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    • pp.205-215
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    • 1988
  • The effects of simetryne on light induced electron transport and phosphorylation in isolated spinach (Spinacia oleracea L.) chloroplasts were investigated in comparison with sencor and DCMU. Simetryne, like sencor and DCMU, completely, inhibited PSII electron transport and phosphoryltion with 10-6 M treatment but did not inhibit PSI electron transport. Interference with the electron transport pathway was evidenced by the greater sensitivity of oxygen evolution and uptake than phosphorylation. The following order of decreasing inhibitory effectiveness was exihibited; DCMU>simetryne>sencor. The photoacoustic technique was also used to monitor the relative photosynthetic activity in the leaves treated with the herbicides (simetryne, sencor or DCMU) in vivo and in vitro. Photoacoustic measurements on intact leaves provide quantitative information on two related aspects of the photosynthetic process, namely, photochemical energy storage and oxygen evolution. The relative photoacoustic signal of leaves treated with the herbicides showed low level in 21 Hz, but high level in 380 Hz and on isolated chloroplasts (both 21 Hz and 380 Hz) in comparison with that of the untreated leaves. These results suggest that some of photochemical energy is converted into the heat owing to the inhibition of electorn transport pathway by the herbicides.

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Fabrication of Carbon Nanofiber/Cu Composite Powder by Electroless Plating and Microstructural Evolution during Thermal Exposure (무전해 도금에 의한 탄소나노섬유/Cu 복합 분말 제조 및 열적 안정성)

  • Kim In-soo;Lee Sang-Kwan
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.39-42
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    • 2004
  • Carbon nanofiber/Cu composite powder has been fabricated by electroless plating process. Microstructural evolution of the composite powder after heat treatment under vacuum, hydrogen and air environment was investigated. A dispersed carbon nanofiber coated by copper was produced at the as-plated condition. Carbon nanofiber is coated uniformly and densely with the plate shaped copper particles. The copper plates on the carbon nanofiber aggregate during the thermal exposure at elevated temperature in vacuum and hydrogen in order to reduce surface energy. The thermal exposure of the composite powder in air at $400^{\circ}C$ for 3 hours leads to the spherodization of the composite powder owing to oxidation of copper.

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A study of low-power density laser welding process with evolution of free surface (자유표면변형을 고려한 저에너지밀도 레이저 용접공정 해석)

  • Ha, Eung-Ji;Kim, Woo-Seung
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.133-138
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    • 2003
  • In this study, numerical investigation has been performed on the evolution of weld pool geometry with moving free surface during low-energy density laser welding process. The free surface elevates near the weld pool edge if ${\partial}{\sigma}/dT$ is dominantly negative. On the contrary, the free surface rise at the center of weld pool in case of mainly positive ${\partial}{\sigma}/dT$. The predicted weld pool width and depth with moving free surface are 5∼15%$5{\sim}15%$ greater than those with flat weld pool surface. It is considered that weld pool surface oscillation during melting process augments convective heat transfer rate in the weld pool.

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