• Title/Summary/Keyword: green cement

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The Influence of Inorganic Pigments on the Compressive Strength and Absorption of Cement Mortars (무기안료가 시멘트모르타르의 압축강도와 흡수율에 미치는 영향)

  • Shon, Hyuk;Lee, Jae-Yong;Go, Seong-Seok
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.104-111
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    • 2004
  • The aim of this study was to investigate the influence of inorganic pigments on the physical properties of cement mortar. For this purpose, the compressive strength and absorption test were carried out on cement mortar imxed with inorganic pigments by changing the proportion of cement mortar, water-cement ratio, and ratio of pigment. The result of this study can be summarized as follows: the compressive strength of colored mortar rapidely increased in red and yellow mortar, as the mix ratio of pigment increased. In case of green and black mortar, however, the compressive strength decresed as the mix ratio incresed. In case of red and yellow mortar, the absorption of colored mortar increased as the mixing ratio increased, if the mean particle diameter of the pigment is small. In case of green and black mortar, the absorption ratio decreased as the mix ratio increased. After investigating the overall physical properties of colored mortar, it was confirmed that the proper mix ratio of pigment securing the properties of colored mortar was below 6% of the weight of the cement to be used.

Identification of Active Agents for Reductive Dechlorination in Cement/Fe(II) Systems (시멘트와 Fe(II)을 이용한 환원성 탈염소화반응의 유효반응성분 규명)

  • Kim, Hong-Seok;Lee, Yu-Jung;Kim, Ha-Yan;Hwang, In-Seong
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.35-42
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    • 2006
  • Experimental study was conducted to identify the active agent for reductive dechlorination of TCE in cement/Fe(II) systems. Several potential materials-hematite (${\alpha}-Fe_2O_3$), lepidocrocite (${\gamma}$-FeOOH), akaganeite (${\beta}$-FeOOH), ettringite ($Ca_6Al_2(SO_4)_3(OH)_{12}$)-that are cement components or parts of cement hydrates were tested if they could act as reducing agents by conducting TCE degradation experiments. From the initial degradation experiments, hematite was selected as a potential active agent. The pseudo-first-order degradation rate constant ($k\;=\;0.637\;day^{-1}$) for the system containing 200 mM Fe(II), hematite and CaO was close to that ($k\;=\;0.645\;day^{-1}$) obtained from the system containing cement and 200 mM Fe(II). CaO, which was originally added to simulate pH of the cement/Fe(II) system, was found to play an important role in degradation reactions. The reactivity of the hematite/CaO/Fe(II) system initially increased with increase of CaO dosage. However, the tendency declined in the higher CaO dosage region, implying a saturation type of behavior. The SEM analysis revealed that the hexagonal plane-shaped crystals were formed during the reaction with increasing degradation efficiency, which was brought about by increasing the CaO dosage. It was suspected that the crystals could be portlandite or green rust ($SO_4$) or Friedel's salt. The XRD analysis of the same sample identified the peaks of hematite, magnetite/maghemite, green rust ($SO_4$). Either instrumental analysis predicted the presence of the green rust ($SO_4$). Therefore, the green rust ($SO_4$) would potentially be a reactive agent for reductive dechlorination in cement/Fe(II) systems.

Novel approach to improve nano green mortar behaviour using nano-paper waste with nano-metakaolin

  • Radwa Defalla Abdel, Hafez;Bassam A., Tayeh;Raghda Osama Abd-Al, Ftah;Khaled, Abdelsamie
    • Advances in concrete construction
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    • v.14 no.5
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    • pp.341-354
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    • 2022
  • Treatment of solid waste building materials is a crucial method of disposal and an area of ongoing research. New standards for the treatment of solid waste building materials are necessary due to multisource features, huge quantities, and complicated compositions of solid waste. In this research, sustainable nanomaterial mixtures containing nano-paper waste (NPW) and nano-metakaolin (NMK) were used as a substitute for Portland cement. Portland cement was replaced with different ratios of NPW and NMK (0%, 4%, 8%, and 12% by weight of cement) while the cement-to-water ratio remained constant at 0.4 in all mortar mixtures. The fresh properties had a positive effect on them, and with the increase in the percentage of replacement, the fresh properties decreased. The results of compressive strength at 7 and 28 days and flexural strength at 28 days show that the nanomaterials improved the strength, but the results of NMK were better than those of NPW. The best replacement rate was 8%, followed by 4%, and finally 12% for both materials. The combination of NMK and NPW as a replacement (12% NMK + 12% NPW) showed less shrinkage than the others because of the high pozzolanic reactivity of the nanomaterials. The combination of NMK and NPW improved the microstructure by increasing the hydration volume and lowering the water in the cement matrix, as clearly observed in the C-S-H decomposition.

Evaluation of Bifacial Si Solar Module with Different Albedo Conditions (양면수광형 실리콘 태양광 모듈의 바닥면 반사조건 변화에 따른 발전성능 평가)

  • Park, Dohyun;Kim, Minsu;So, Wonshoup;Oh, Soo-Young;Park, Hyeonwook;Jang, Sungho;Park, Sang-Hwan;Kim, Woo Kyoung
    • Current Photovoltaic Research
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    • v.6 no.2
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    • pp.62-67
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    • 2018
  • Multi-wire busbar-type bifacial n-type Si solar cells have been used for the fabrication of monofacial and bifacial photovoltaic (PV) module, where bifacial module was equipped with transparent backsheet while monofacial module was prepared using white backsheet. The comparison of six-day accumulated power production obtained from outdoor test under gray cement ground conditions using 60cell monofacial and bifacial PV modules suggested the bifacial gain of over 20% could be achieved. Furthermore, the outdoor evaluation tests of bifacial modules with different ground conditions such as cement (reference), green paint, white paint and green artificial grass, were performed. It turned out white paint showed the best albedo and thus the highest power production, while green paint and artificial grass showed less power generation than cement ground.

Influence of palm oil fuel ash on behaviour of green high-performance fine-grained cement mortar

  • Sagr, Salem Giuma Ibrahim;Johari, M.A. Megat;Mijarsh, M.J.A.
    • Advances in materials Research
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    • v.11 no.2
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    • pp.121-146
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    • 2022
  • In the recent years, the use of agricultural waste in green cement mortar and concrete production has attracted considerable attention because of potential saving in the large areas of landfills and potential enhancement on the performance of mortar. In this research, microparticles of palm oil fuel ash (POFA) obtained from a multistage thermal and mechanical treatment processes of raw POFA originating from palm oil mill was utilized as a pozzolanic material to produce high-performance cement mortar (HPCM). POFA was used as a partial replacement material to ordinary Portland cement (OPC) at replacement levels of 0, 5, 10, 15, 20, 25, 30, 35, 40% by volume. Sand with particle size smaller than 300 ㎛ was used to enhance the performance of the HPCM. The HPCM mixes were tested for workability, compressive strength, ultrasonic pulse velocity (UPV), porosity and absorption. The results portray that the incorporation of micro POFA in HPCMs led to a slight reduction in the compressive strength. At 40% replacement level, the compressive strength was 87.4 MPa at 28 days which is suitable for many high strength applications. Although adding POFA to the cement mixtures harmed the absorption and porosity, those properties were very low at 3.4% and 11.5% respectively at a 40% POFA replacement ratio and after 28 days of curing. The HPCM mixtures containing POFA exhibited greater increase in strength and UPV as well as greater reduction in absorption and porosity than the control OPC mortar from 7 to 28 days of curing age, as a result of the pozzolanic reaction of POFA. Micro POFA with finely graded sand resulted in a dense and high strength cement mortar due to the pozzolanic reaction and increased packing effect. Therefore, it is demonstrated that the POFA could be used with high replacement ratios as a pozzolanic material to produce HPCM.

Thermal Characteristics of Permeable Block Pavements for Landscape Construction (조경용 투수성 블록포장의 열특성)

  • Han, Seung-Ho;Ryu, Nam-Hyong;Yoon, Yong-Han;Kim, Won-Tae;Kang, Jin-Hyoung
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.573-580
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    • 2008
  • This study aims to measure and to analyze the characteristics of thermal environment of the various permeable pavement materials such as a break stone pavement (Green block cubic), soil protection pavement (Soil tector), soil cement pavement and ceramic brick pavement under the summer outdoor environment. The thermal environment characteristics measured in the study includes the changes of surface temperature during the day, and long and short wave radiation of each pavement surface. The experimental condition is based on the data on the hottest temperature (August 9, 2006, $37.1^{\circ}C$) of the year. The albedo was the highest on the break stone pavement(0.8) from 12:00 to 14:00. The albedo of the ceramic brick pavement, a soil tector pavement and soil cement pavement were 0.35, 0.29 and 0.27 from 12:00 to 14:00, respectively. The peak surface temperature and long wave radiation was the highest on the soil protection pavements($56.6^{\circ}C$/627 W/$m^2$). The peak surface temperatures and long wave radiation on the ceramic brick pavement, a stone brick pavement and soil cement pavement were $51.7^{\circ}C$/627 W/$m^2$, $48.8^{\circ}C$/607 W/$m^2$ and $45.9^{\circ}C$/582 W/$m^2$, respectively. The heat environment was better on the break stone pavement than on the other pavements. This is mainly due to the high albedo of the break stone pavement(0.8) while the albedo value of a ceramic brick pavement, a soil tactor pavement and soil cement pavement were 0.35. 0.29 and 0.27. Large heat capacity($2,629kJ/m^3{\cdot}K$) of the stone brick pavements also contributes to this difference. The heat environment was better on the soil cement pavement than the soil tector pavement. This is mainly due to the evaporation of the soil cement pavement while the active evaporation of the soil tactor pavement was not continued after two days from the rainfall event. To improve the thermal environments in the urban area, it is recommended to raise the albedo of the pavements by brightening the surface color of the pavement materials. Further studies on the pavement materials and the construction methods which can enhance the continuous evapotranspiration from the pavements surface are needed.

Utilization of Waste Concrete Powder from the Viewpoint of LCA CO2 (LCA CO2 관점에서의 콘크리트 폐석분의 활용방안)

  • Song, Hun;Shin, Hyeon-Uk;Chu, Yong-Sik;Lee, Jong-Kyu;Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.209-210
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    • 2012
  • Cement is an essential material for social infrastructure. Cement production process for cement itself is energy-intensive and requires a large amount of natural resources for fuel and raw materials. This study is to development of recycled cement from waste concrete powder in manufacturing process of recycled aggregate concrete. Recycled cement is low carbon and green growth materials concept for eco friendly construction environment. From the test results, waste concrete powder is same chemical proportion regardless of manufacturing process of recycled aggregate concrete.

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Mechanical behavior of HPFRCC using limestone calcined clay cement (LC3) and oxygen plasma treated PP fibers

  • Sajjad Mirzamohammadi;Masoud Soltani
    • Structural Engineering and Mechanics
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    • v.89 no.4
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    • pp.349-362
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    • 2024
  • High-performance fiber-reinforced cement composites (HPFRCC) are new materials created and used to repair, strengthen, and improve the performance of different structural parts. When exposed to tensile tension, these materials show acceptable strain-hardening. All of the countries of the globe currently seem to have a need for these building materials. This study aims to create a low-carbon HPFRCC (high ductility) that is made from materials that are readily available locally which has the right mechanical qualities, especially an increase in tensile strain capacity and environmental compatibility. In order to do this, the effects of fiber volume percent (0%, 0.5%, 1%, and 2%), and determining the appropriate level, filler type (limestone powder and silica sand), cement type (ordinary Portland cement, and limestone calcined clay cement or LC3), matrix hardness, and fiber type (ordinary and oxygen plasma treated polypropylene fiber) were explored. Fibers were subjected to oxygen plasma treatment at several powers and periods (50 W and 200 W, 30, 120, and 300 seconds). The influence of the above listed factors on the samples' three-point bending and direct tensile strength test results has been examined. The results showed that replacing ordinary Portland cement (OPC) with limestone calcined clay cement (LC3) in mixtures reduces the compressive strength, and increases the tensile strain capacity of the samples. Furthermore, using oxygen plasma treatment method (power 200 W and time 300 seconds) enhances the bonding of fibers with the matrix surface; thus, the tensile strain capacity of samples increased on average up to 70%.

Mineral Composition and Color Properties of Molten Clinker made from Blast Furnace Slag (고로(高爐)슬래그로 부터 제조(製造)된 용융(溶融)클링커의 광물조성(鑛物組成)과 색도특성(色度特性))

  • Chu, Yong-Sik;Seo, Sung-Kwan;Im, Du-Hyuk;Song, Hun;Lee, Jong-Kyu;Lee, Seung-Ho
    • Resources Recycling
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    • v.20 no.6
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    • pp.71-77
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    • 2011
  • Raw mix of molten clinker was fabricated using blast furnace slag as starting material. Raw mix was melted at 1620 for molten clinker fabrication. Color and mineral composition of molten clinker was investigated by XRD and colorimeter. It was found that the molten clinker contains alite and belite equivalent to OPC clinker mineral and shows higher whiteness value than that of OPC. Whiteness of the molten clinker decreased with LSF and SM. Also the whiteness value of the slag cement using molten clinker was higher than that of common slag cement.