• 한국주조공학회지
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• 제14권1호
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• pp.28-34
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• 1994

Metallurgical-grade polycrystalline silicon was directionally solidified at growth rates of $0.2{\sim}1.0mm/min$ by using split type, reusable graphite molds which were coated with $Si_3N_4$ powder. The resultant grain sizes of the silicon ingots and the shapes of the solid/liquid(S/L) interfaces were investigated. X-ray diffraction was used to determine the preferred orientation in each of the silicon ingots. The impurity content of the silicon was analyzed and the resistivities of the ingots were measured. During the growth of an ingot, the shape of the S/L interface was concave to the silicon melt, and the resistivity decreased. The presence of Al which can be acting as a carrier, is thought to be the main factor causing such a decrease in resistivity. When a growth rate of 0.2㎜/min was used, the preferred orientation was found to be (111).

• Bulletin of the Korean Chemical Society
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• 제35권4호
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• pp.1067-1072
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• 2014

In this study, we report a new approach for $Mn_3O_4$-graphene nanocomposite by ex situ method. This nanocomposite shows two-dimensional aggregation of nanoparticle, and doping effect by decorated manganese oxide ($Mn_3O_4$), as well. The graphene film was made through micromechanical cleavage of graphite on the $SiO_2/Si$ wafer. Manganese oxide ($Mn_3O_4$) nanoparticle with uniform cubic shape and size (about $5.47{\pm}0.61$ nm sized) was synthesized through the thermal decomposition of manganese(II) acetate, in the presence of oleic acid and oleylamine. The nanocomposite was obtained by self-assembly of nanoparticles on graphene film, using hydrophobic interaction. After heat treatment, the decorated nanoparticles have island structure, with one-layer thickness by two-dimensional aggregations of particles, to minimize the surface potential of each particle. The doping effect of $Mn_3O_4$ nanoparticle was investigated with Raman spectra. Given the upshift in positions of G and 2D in raman peaks, we suggest that $Mn_3O_4$ nanoparticles induce p-doping of graphene film.

• 한국주조공학회지
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• 제17권4호
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• pp.393-401
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• 1997

Commercial flake graphite cast iron substrate was coated with titanium powder by low pressure plasma spraying and was irradiated with a $CO_2$ laser to produce the wear resistant composite layer. From the experimental results of this study, it was possible to composite TiC particles on the surface layer by direct reaction between carbon existed in the cast iron matrix and titanium with thermal sprayed coating by remelting and alloying them using laser irradiation. The cooling rate of laser remelted cast iron substrate without titanium coating was about $1{\times}10^4$ K/s to $1{\times}10^5$ K/s in the order under the condition used in this study. The microstructure of alloyed layer consisted of three zones, that is, TiC particule crystallized zone (MHV $400{\sim}500$), the mixed zone of TiC particule+ledebulite (MHV $650{\sim}900$) and the ledebulite zone (MHV $500{\sim}700$). TiC particules were crystallized as a typical dendritic morphology. The secondary TiC dendrite arms were grown to the polygonized shape and were necking. And then the separated arms became cubic crystal of TiC at the slowly solidified zone. But in the rapidly solidified zone of fusion boundry, the fine granular TiC particules were grouped like grape.

• 한국군사과학기술학회지
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• 제13권5호
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• pp.717-724
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• 2010

The initial trajectory of a spheroid configuration bobbin for precision guidance has been investigated by analyzing its aerodynamic load and six-degree-of-freedom motion. The effects of changes in the spheroidal head configuration, flow angle and lateral center-of-gravity offset are numerically studied using the commercial software "FLUENT". A wind tunnel test is also conducted to validate the numerical scheme and to examine effect of the Reynolds number on the flow around the bobbin. It is shown that the size of the separation bubble formed on the surface decreases significantly when the Reynolds number is varied between 110,000 and 140,000. At a zero flow angle, an oblate spheroidal head shows relatively moderate rotation while a prolate spheroidal head shows rapid rotation. The bobbin with a spherical head shape has little effect on the flow direction; however, the oblate bobbin is sensitive to the flow angle. The roll motion of the bobbin is greatly influenced by the lateral center-of-gravity offset and maximum dispersion is observed at half of the radius.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.38-38
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• 2010

Ever since the experimental discovery of graphene exfoiliated from the graphite flakes by Geim et at., this area has drawn a lot of attention for its possible application in IT industry. For the growth of graphene, chemical vapor deposition (CVD) has been widely used to fabricate the large area graphene. The lateral size of this graphene can be easily controlled by the size of the metal substrate though the chemical etching to remove this substrate is somewhat troublesome. Another problem which is hard to avoid is the folding at the grain boundary. We will discuss the origin of the folding first and introduce the way to avoid this folding. To solve this problem, we have used the various types of micro-thin metal foils. The precise control of hydro-carbon and the carrier gas results in the formation of the graphene on top of substrate. The thickness of graphene layers can be controlled with the control of gas flow on top of Cu substrate in contrast to the previously reported self-limiting growth $behavior^1$. Uniformity of this graphene layer has been checked by micro-raman spectroscopy and SEM. The size of grain can be enhanced by thermal treatment or use of other metal substrate. The dependence of grain size on the lattice size of the substrate will be discussed. By selecting the shape of substrate, we can grow various types of graphene. We will introduce the micron size graphene tube and its application.

• 한국산업융합학회 논문집
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• 제20권2호
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• pp.141-148
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• 2017

A process comprising a hot extrusion process and a warm forging process was designed to form a T-shaped aluminum structural component with a high degree of difficulty by the plastic forming method. A circular cylindrical part was extruded with a hot extrusion process, and then an embossing part was formed with a warm forging process. The formability and the maximum load required for forming were then determined using a forming analysis program. The hot extrusion process was executed at $450^{\circ}C$ under the extrusion speed at 6 mm/s, while the warm forging process was executed at $260^{\circ}C$ under the forging speed at 150 mm/s. For both the processes, a condition by which friction would not be generated between the mold and the material was implemented. The analysis results showed that the load required for hot extrusion was 1,019 tons, while the load required for the warm forging was 534 tons. The T-shaped part was manufactured by using a 1,600 tons capacity press. The graphite lubricant was coated on the mold as well as the material. A forming experiment was performed under the same condition with the analysis condition. The measured values from the load cell were 1,210 tons in the hot extrusion process and 600 tons in the warm forging process.

• 한국표면공학회지
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• 제54권6호
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• pp.348-356
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• 2021

In this study, optical diagnosis of plasma was performed for nitrogen doping in graphene using a horizontal inductively coupled plasma (ICP) system. Graphene was prepared by mechanical exfoliation and the ICP system using nitrogen gas was ignited for plasma-induced and defect-suppressed nitrogen doping. In order to derive the optimum condition for the doping, plasma power, working pressure, and treatment time were changed. Optical emission spectroscopy (OES) was used as plasma diagnosis method. The Boltzmann plot method was adopted to estimate the electron excitation temperature using obtained OES spectra. Ar ion peaks were interpreted as a reference peak. As a result, the change in the concentration of nitrogen active species and electron excitation temperature depending on process parameters were confirmed. Doping characteristics of graphene were quantitatively evaluated by comparison of intensity ratio of graphite (G)-band to 2-D band, peak position, and shape of G-band in Raman profiles. X-ray photoelectron spectroscopy also revealed the nitrogen doping in graphene.

• Nuclear Engineering and Technology
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• 제53권9호
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• pp.2909-2917
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• 2021

Following the launch of Rare Isotope Science Project in December 2011, a heavy ion accelerator complex in South Korea, named RAON, has since been designed. It includes a muon facility for muon spin rotation, relaxation, and resonance. The facility will be provided with 600 MeV and 100 kW (one-fourth of the maximum power) proton beam. In this study, the graphite target in RAON was designed to have a rotating disk shape and was cooled by radiative heat transfer. This cool-down process has the following advantages: a low-temperature gradient in the target and the absence of a liquid coolant cooling system. Monte Carlo simulations and ANSYS calculations were performed to optimize the target system in a thermally stable condition when the 100 kW proton beam collided with the target. A comparison between the simulation and experimental data was also included in the design process to obtain reliable results. The final design of the target system will be completed within 2020, and its manufacturing is in progress. The manufactured target system will be installed at the RAON in the Sindong area near Daejeon-city in 2021 to carry out verification experiments.

• 한국재료학회지
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• 제2권6호
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• pp.428-435
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• 1992

AISI 4600계 철 분말에 F$e_2$P 분말을 사용하여 인(P)을 0~1.0% 그리고 흑연 분말을 사용하여 탄소를 0~0.8% 첨가하여 회전혼합기를 사용하여 혼합하였다. 흔합분말을 양단압금형에서 800MPa로 가압하여 성형체를 만들었다. 성형체는 진공 또는 수소와 질소 혼합가스 분위기에서 115$0^{\circ}C$에서 30분간 소결하였다. 소결체를 연마하고 2% 질산용액으로 에칭하였다. 소결체 조직을 Image Analyzer와 금속현미경으로 관찰하였다. 밀도는 ASTM B3l2로, 경도는 미세 비커스경도기로 측정하였다. 얻어진 결과는 다음과 같다. (1) F$e_2$P 첨가량이 증가하면, 소결체 조직은 치밀화되고 입자 크기는 더 커졌다. (2) $Fe_2P량과$ 함께 기공의 형상은 둥글고, 그 숫자는 감소하였으나 평균크기는 더 커졌다. (3) 입자의 크기는 F$e_2$P와 흑연분말을 동시에 첨가한 경우가 각각 단독으로 첨가한 경우보다 커졌다. (4) 미세조직에 미치는 소결분위기의 영향은 거의 없었다. (5) 경도는 인과 탄소량이 증가하면 상승하였다.

• 한국지반공학회논문집
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• 제26권7호
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• pp.93-106
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• 2010

현장 열응답 시험을 통해 지중 유효 열전도도를 산출하여 각 보어홀의 성능을 비교하기 위해 강원도 원주 현장에 6개의 보어홀을 시험 시공하였다. 6개의 보어홀은 그라우트 종류와 첨가재 종류, 지중열교환기 파이프 단면에 따른 영향을 검토하도록 시공되었다. 그라우트 재료는 벤토나이트와 시멘트를 사용하였으며 첨가재는 천연규사와 흑연, 파이프 단면은 기존 U-tube 파이프 단면과 유입과 유출 파이프 사이에 파이프를 추가로 삽입한 새로운 3공형 파이프 단면을 적용하였다. 현장 열응답 시험으로 산정한 지중 유효 열전도도 결과는 시멘트 그라우트로 시공한 보어홀의 경우가 벤토나이트 그라우트로 시공한 경우에 비해 전열 성능이 향상됨을 보였으며 흑연을 추가로 사용한 경우가 천연규사만 사용한 경우보다 높은 효율을 보였다. 또한, 유입과 유출 파이프 사이에 물을 채워 부분적 단열 구간을 형성한 새로운 3공형 파이프 단면의 경우가 기존 U-tube 파이프 단면에 비해 높은 효율을 보였다. 가상 건물에 대한 지중열교환기 설계를 수행하여 지중열교환기 시공비를 비교한 결과, 시멘트 그라우트에 첨가재로 천연규사와 흑연을 함께 사용한 경우가 벤토나이트 그라우트에 첨가재로 천연규사를 사용한 기존의 시공방법 보다 낮은 시공비로 설계가 가능하였다. 마지막으로 본 현장 열응답 시험결과를 바탕으로 일련의 경제성 분석을 통하여 새로이 제시된 첨가제와 3공형 파이프 단면의 적용성을 평가하였다.