• 제목/요약/키워드: gold-silver

검색결과 404건 처리시간 0.027초

미륵사지 출토 고대 금동유물의도금기법에 관한 연구 (Study for the Film Coating Techniqur of Gilt Bronze Artifacts from Mir ksa Temple)

  • 임선기;강대일;김선덕;박동규;강성군
    • 보존과학연구
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    • 통권14호
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    • pp.45-76
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    • 1993
  • Au-Cu alloyed coating layer were found by Hg-amalgam process and it seemed to be used Cu-amalgam process similar to Au-amalgam. Coated layer is dense and unique, Thickness of layer was 1.5 to $18.0\mum$ which had 95.3 to 99.8% purity of gold Matrix metal mostly cosists of forged copper alloy which had high purity and ferrite ($\alpha$) strusture. It showed excellent refining technical level at that time. Aowever, the nail, ferrous matrix used for strength needed, composed of silver foil packed and gold layer for adherence between ferrous matrix and gold layer

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On-Channel Micro-Solid Phase Extraction Bed Based on 1-Dodecanethiol Self-Assembly on Gold-Deposited Colloidal Silica Packing on a Capillary Electrochromatographic Microchip

  • Park, Jongman;Kim, Shinseon
    • Bulletin of the Korean Chemical Society
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    • 제35권1호
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    • pp.45-50
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    • 2014
  • A fully packed capillary electrochromatographic (CEC) microchip with an on-column micro-solid phase extraction (SPE) bed for the preconcentration and separation of organic analytes was prepared. A linear microchannel with monodisperse colloidal silica packing was formed on a cyclic olefinic copolymer microchip with two reservoirs on both ends. Silver-cemented silica packing frit structure was formed at the entrance of the microchannel by electroless plating treatment as a base layer. A gold coating was formed on it by reducing $Au^{3+}$ to gold with hydroxylamine. Finally micro-SPE bed was formed by self-assembly adsorption of 1-dodecanethiol on it. Micro-SPE beds were about 100-150 ${\mu}m$ long. Approximately $10^3$ fold sensitivity enhancements for Sulforhodamine B, and Fluorescein in nM concentration levels were possible with 80 s preconcentration. Basic extraction characteristics were studied.

Sediment-hosted gold mineralization of the Kyaukpahto mine, Kawlin Township, Myanmar

  • Swe, Ye-Myint;Min, A-Ung;Lee, In-Sung
    • 대한자원환경지질학회:학술대회논문집
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    • 대한자원환경지질학회 2003년도 춘계 학술발표회 논문집
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    • pp.315-315
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    • 2003
  • Gold mineralization at Kyaukpahto occurs as stockworks/disseminations and locally as breccia zones in silicified sandstones of Lower to Middle Eocene Male Formation of Myanmar. The mineralization is spatially related with NNE -trending fracture zones_probably tensional open fractures caused by the right-lateral Sagaing fault system. Intensive silicification, sericitization, argillic alteration, sulfidation, and decalcification are recognized in the Kyaukpahto mine area. (omitted)

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통영광산산(統營鑛山産) 섬아연석(閃亞鉛石)의 화학조성(化學組成) (Chemical Composition of Sphalerite Relating to Mineralization at the Tongyoung mine, Korea)

  • 김문영;신홍자
    • 자원환경지질
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    • 제22권2호
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    • pp.103-115
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    • 1989
  • The Tongyoung deposits are epithermal gold and silver bearing quartz-rhodochrosite vein type deposits of late Cretaceous. They occurs in the andesite and tuff breccia member called Gyeongsang basin. Four mineralizations can be distinguished at the mine based on macrostructures. From earlist stage to lastest stage they are: stage I, base-metal quartz vein; stage II, rhodochrosite vein (IIA) and Pb-Zn vein (IIB); stage III, barren quartz vein; stage IV, calcite-ankeritic rhodochrosite veins. Gold and silver mineralizations occur predominantly in the stage I and IIB. Electrum is closely associated with galena, sphalerite and pyrite, and has chemical compositions of 50.98-64.05 atom % Ag. Sphalerite contains 2.09-5.05 mol % FeS and 0.34-2.01 mol % MnS in the stage I, and 2.01-3.41 mol % FeS and 0.21-2.80 mol % MnS in the stage IIB. The FeS and MnS contents are in general correlated, and shows a characteristic zonal arrangement of electrum. It reveals rhat FeS contents of sphalerite which precipitated before electrum, gradually decreases in a grain during its deposition ranging from about 3.3 to 2 mol %. It may be considered from the above data that an increase of $fs_2$ caused by the oxidation of ore forming fluid is more important that the decrease of temperature.

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Poly(ethylenimine)-Stabilized Hollow Gold-Silver Bimetallic Nanoparticles: Fabrication and Catalytic Application

  • Shin, Kuan-Soo;Kim, Ji-Hoon;Kim, In-Hyun;Kim, Kwan
    • Bulletin of the Korean Chemical Society
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    • 제33권3호
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    • pp.906-910
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    • 2012
  • Hollow gold-silver bimetallic nanoparticles (AuAg-HNPs) have been synthesized and their optical and structural properties were characterized. Initially Ag nanoparticles (Ag-NPs) were prepared using poly(ethylenimine) (PEI) as a reducing and a stabilizing agent simultaneously. AuAg-HNPs could then be synthesized via galvanic replacement reaction in a PEI aqueous solution by reacting sacrificial Ag template with a precursor compound of Au, i.e., $HAuCl_4$. Due to the presence of abundant amine functional groups in PEI, which could act as the dissolving ligand for AgCl, the precipitation problem of $Ag^+$ in the presence of Cl from $HAuCl_4$ salt was avoided. On this basis, the relatively high concentrations of $HAuCl_4$ and PEI-stabilized Ag nanoparticles could be used for the fabrication of AuAg-HNPs. Because of their increased surface areas and reduced densities, the AuAg-HNPs were expected and confirmed to outperform their solid counterparts in applications such as catalysis for the reduction of 4-nitrophenol in the presence of $NaBH_4$.

태백산광화대 북부 낙천, 은치, 중봉 금-은광상의 안정동위원소 연구 (Stable Isotope of the Nakcheon, Eunchi and Jungbong Gold-Silver Deposits in the Northern Taebagsan Mining District)

  • 황정;박희인
    • 자원환경지질
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    • 제29권2호
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    • pp.159-170
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    • 1996
  • The gold-silver deposits of the Nakcheon, Eunchi and Jungbong mine in the northern Taebagsan mining district are composed of fissure fil1ing veins emplaced in Precambrian meta-sediments and Jungbongsan granite. Based on the changes of ore texture and mineralogy, ore mineral chemistry, fluid inclusion and mineralizing condition, a regional zoning is recognized from the Nakcheon to the Eunchi and Jungbong ore deposits, and this trend of zoning is also recognized by stable isotope compositions. Stable isotope compositions show that the source of su1fur and carbon is mainly igneous origin, and the water of ore fluid in the Nakcheon ore deposits is mainly magmatic origin but much of meteoric water is involved in ore fluid of the Eunchi and Jungbong ore deposits. The ore deposits of study area is polymetallic meso to epithermal type genetically related to the acidic igneous pluton. Due to the differntial erosion level and mineralized depth, each ore deposits has a slightly different characteristic of mineralization; The Nakcheon ore deposits belong to meso-epithermal type, but the Eunchi and Jungbong ore deposits belong to epithermal type.

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남북한 경제협력사업으로 북한 자원개발 방안 (Proposal for South-North Mining Cooperation (Natural Resources Exploitation in the Peoples Republic of Korea))

  • 유택수
    • 기술사
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    • 제38권6호
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    • pp.1-9
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    • 2005
  • The Republic of Korea (South) and the Peaples Republic of Korea (North) had agreed to exploit the North Korean rich natural resources starting from the year of 2006. Through this mutual agreement DPRK shall quarantee ROK's investment in the North Korean Mines and supply mineral products for the compasation of the financial investment supported by ROK. In the area of northern part of Korea, many kind of natural resources such as Magnesite, Iron, Gold & Silver, Copper, Lead & Zinc, and Coal are plentifully deposited. In the area of southern part of Korea, however, most kind of natural resources have been exhausted and so presently major minerals such as Gold & Silver, Copper, Lead & Zinc and Coal are being imported and relying on foreign countries in whole quantity of the requirement. On the other hand Northern Part of Korea is making very slow progress in mining and exploitation owing to the lack of investment even though there are rich deposits of natural resources. And in Southern Part of Korea, they have most advanced production facilities and technologies in the world in the fields of Mineral Floatation, Steel Manufacturing, Nonferrous Metal Smelting & Refining and those plants fabrications. A combination of Southern Technologies together with Financial Support and Northern rich natural resources & Labour Power will be a most hopeful, desirable and mutually required 'South-North economic Cooperation' as the mining industries are labour intensive.

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In Situ Single Cell Monitoring by Isocyanide-Functionalized Ag and Au Nanoprobe-Based Raman Spectroscopy

  • Lee, So-Yeong;Jang, Soo-Hwa;Cho, Myung-Haing;Kim, Young-Min;Cho, Keun-Chang;Ryu, Pan Dong;Gong, Myoung-Seon;Joo, Sang-Woo
    • Journal of Microbiology and Biotechnology
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    • 제19권9호
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    • pp.904-910
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    • 2009
  • The development of effective cellular imaging requires a specific labeling method for targeting, tracking, and monitoring cellular/molecular events in the living organism. For this purpose, we studied the cellular uptake of isocyanide-functionalized silver and gold nanoparticles by surface-enhanced Raman scattering (SERS). Inside a single mammalian cell, we could monitor the intracellular behavior of such nanoparticles by measuring the SERS spectra. The NC stretching band appeared clearly at ${\sim}2,100cm^{-1}$ in the well-isolated spectral region from many organic constituents between 300 and 1,700 or 2,800 and $3,600cm^{-1}$. The SERS marker band at ${\sim}2,100cm^{-1}$ could be used to judge the location of the isocyanide-functionalized nanoparticles inside the cell without much spectral interference from other cellular constituents. Our results demonstrate that isocyanide-modified silver or gold nanoparticle-based SERS may have high potential for monitoring and imaging the biological processes at the single cell level.

반사광 측정 모드에서 금과 은을 사용한 이층 금속 칩과 삼층 금속 칩의 특성 연구 (Characteristics of Gold and Silver Based Bi- and Tri-metallic SPR Chip in the Intensity Measurement Mode)

  • 김형진;김창득;손영수
    • 센서학회지
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    • 제25권2호
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    • pp.143-147
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    • 2016
  • Characteristics of the conventional gold (Au) surface plasmon resonance (SPR) chip, bi-metallic(Au/silver (Ag)) SPR chip, and tri-metallic(Au/Ag/Au) SPR chip were investigated and compared in the intensity measurement mode for the enhancement of SPR image sensor reactivity. Reflectance curves of the Au, bi- and tri-metallic SPR chips were acquired in phosphate-buffered saline (PBS) solution and were compared. The line width of the reflectance curve of the bi-metallic chip was the narrowest among the three different types of the chips. Also, the tangential slope of the bi-metallic chip was steeper than those of the other chips. Various concentrations of bovine serum albumin (BSA) were utilized in the SPR experiment. As a result, among the above three chips reflectance variation value of the bi-metallic chip was the largest.