• Title/Summary/Keyword: gas toxicity

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Study on the Treatment of Hydrogen Chloride Gas used in Semiconductor Process by using Gas Adsorption Agents such as Zeolite Resins, ZnO, and AgMnO3 (제올라이트 수지 및 ZnO, AgMnO3 등의 무기흡착제를 이용한 반도체 공정에서 사용되는 염산가스의 처리 및 측정에 관한 연구)

  • Park, Jeong-Jun;Lim, H.B.;Hwang, Cheong-Soo
    • Analytical Science and Technology
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    • v.16 no.3
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    • pp.218-225
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    • 2003
  • Hydrogen Chloride is among the most problematic gases used in semiconductor process. It raises serious environmental and health problems due to its extreme toxicity. This study is to develop a method to effectively remove hydrogen chloride gas during the process by using various types of inorganic gas adsorption agents, which have not been attempted in the conventional methods. The removal efficiency of the gas was both qualitatively and quantitatively measured by a FT-IR spectrophotometer. The whole device for the measurement has been designed and built in our lab. The removal efficiencies of hydrogen chloride gas were compared between those tested resins; zeolite A, modified AgA zeolite, ZnO, and $AgMnO_3$. The experimental result revealed that ZnO showed the best efficiency that had removed 0.067 g of HCl per 1 g of the resin used.

A Study on the Fire Safety Performance of Interior Surface Materials in a Building (건축물의 실내건축 재료에 관한 화재안전성 연구)

  • Seo, Su-Eun;Shin, Seung-Woo
    • Proceedings of the Safety Management and Science Conference
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    • 2013.11a
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    • pp.275-290
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    • 2013
  • The main cause of building fire fatalities occur in the combustible material heat, smoke and toxic gases are. Building interior decoration, etc., especially as much of the harmful substances generated during combustion, and, used in domestic architecture wallpaper, ceiling, and other plastics, built-in foam insulation also analyzed recognition of fire hazards approach to test the conkalrorimiteo test, choedaeyeolbangchulryul through, chongbal heat, mass loss rate, generates carbon monoxide gas hazard ratio tests, analysis and evaluation rigid foam index testing the toxicity of hazardous material generated by performing a gas clean up and assess the material test results, the minimum order to provide data to quantify the risk of fire. Ensure fire safety of building materials, composite materials in order to test the various risk factors could be considered organic to the introduction of testing and evaluation is needed urgently.

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COMBUSTION TOXICITY ANALYSIS: ADVANCES USING A SPECIALIZED SAMPLING TECHNIQUE FOR FOURIER TRANSFORM INFRARED (FTIR) ANALYSIS

  • Talandis, Jonas;Innes, J.D.;Cox, A.W.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.178-184
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    • 1997
  • The cone calorimeter as defined by ISO 5660, ASTM 1354, and NFPA 264A is used to assess the reaction to fire of almost any material that must be evaluated in the fire science field. Typical combustion gas analyses include oxygen, CO and CO2. Oxygen consumption is used to determine rate of heat release. Analysis of combustion gases other than oxygen, CO and CO2 has been attempted using filters to remove the solid smoke particles before analysis. This method has generated unreliable results due to the adsorption of many gas components on the active carbon . particles deposited on the filters. A technique using fourier Transform Infrared (FTIB) analysis without filtration will be disclosed and a discussion will be presented of the analytical results of toxic gases produced from various flame retarded polymeric materials. Use of such data in lethal toxic potency determinations is also reviewed.

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Injury Symptom of Egg Plant Grown in a High pH Rockwool Amended with Ammonium Phosphate (인산암모늄 처리 고산도 암면에서 자란 가지생육장해증상)

  • Kim, Yoo-Hak;Lee, Hyeong-Yong;Kim, Myung-Sook;Kang, Seong-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.975-977
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    • 2010
  • Ammonium nitrogen is volatilized as ammonia at high pH soil. This study was conducted to observe an injury cause of egg plant grown in a high pH rockwool amended with ammonium phosphate. The etiolation symptom (yellowing) was appeared on veins of a leaf but not in healthy root when nutrient solution containing ammonium phosphate in addition to essential elements was applied in a top soil of which pH was 7.8. However, the same symptom did not appeared in the egg plant from the top soil in which the nutrition solution containing potassium phosphate instead of ammonium phosphate was applied. pHs were similar between these two different solutions. This revealed that the injury was caused by ammonia gas.

A implementation of system which checks the vehicle oil identification and quantitative gas (자동차 석유 및 정량주유 체크 시스템의 구현)

  • Jeong, Da-Woon;Baek, Sung-Hyun;Jang, Jong-Wook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.15 no.6
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    • pp.1277-1282
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    • 2011
  • Recently, many car drivers were damaged by gas station which support similar oil product and not quantitative gas. It were expected to increase above-mentioned damages. By using similar oil products, caused damage are working of lubrication in the fuel line, elf-cleaning function, the part of the early deterioration, impure accumulation in the fuel line, toxicity material in exhaust emissions and unidentified chemical reaction. To prevent these damages, proposed system use in-vehicle state data with OBD-II protocol, measure quantitative gas and similar oil. In this paper, there have implemented similar oil identification and quantitative gas system through OBD-II scanner to provide WiFi communcation by using WinCe development Board.

Analysis of Flame Shape in Flare Stack (플레어스택의 화염 형상 분석)

  • Lee, Heon-Seok;Kim, Bum-Su;Jung, Sang-Yong;Yoo, Jin-Hwan;Park, Chul-Hwan;Ko, Jae-Wook
    • Journal of the Korean Institute of Gas
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    • v.13 no.3
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    • pp.49-53
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    • 2009
  • Relief systems can improve the process safety because it has the function for the prevention of overpressure. Flare stacks is necessary to avoid explosion, radiation, or toxicity by waste-gas emitted from relief system. Safe combustion is one of the important factors to improve safety and the quantity and velocity emitted is ruled in the API code 521. Due to the pressure of released gas and mass flow, a flame from flare stack is similar to jet fire. In this study, we have investigated the effect of flame form on complete combustion and heat emission. API code was similar to jet fire model in flame length, the flame had an effect on the ground.

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A Study on the Degradation of PAH in Organic and Aqueous Phases by Ozone (다환방향족탄화수소에 대한 오존처리의 방법에 관한 연구)

  • Choi, Young Ik;Son, Hee-Jong;Jung, Chul-Woo
    • Journal of Korean Society on Water Environment
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    • v.22 no.6
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    • pp.1123-1129
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    • 2006
  • Pyrene of natural and anthropogenic sources is one of the toxic, mutagenic polycyclic aromatic hydrocarbons (PAHs) listed as priority pollutants. The objectives of this research are to break down pyrene by using ozonation, identify the intermediates and byproducts of pyrene, and test the biodegradability of intermediates and byproducts of pyrene in the aqueous phase. Since pyrene is non-polar, hexane was chosen as a solvent to effectively dissolve pyrene. Pyrene solutions were treated with ozone, as it has high oxidation capacity and electrophilic characteristic. After different ozonation pretreatment times (2, 3, and 10 minutes), intermediates of pyrene in the form of yellowish solid were collected from the hexane solution using a centrifuge. They were identified by gas chromatography/mass spectrometer (GC/MS). $BOD_5$, COD, and E-coli toxicity tests have been performed to assess the ozonation products.

A Comparative Study on the Toxicity Evaluation for Fire Smoke by FDS (FDS를 이용한 화재시 연소가스의 독성평가에 관한 비교 연구)

  • Jeong, Beom Jin;Lee, Keun Won
    • Journal of the Korean Institute of Gas
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    • v.19 no.1
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    • pp.38-44
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    • 2015
  • FDS (Fire Dynamics Simulator) is the most widely used computational fluid dynamics software in the fire safety engineering community, and it is applicable to various evaluations of fire growth and its effects. This study made use of a range of outputs from FDS simulation to predict FED (Fractional Effective Concentration) and FEC (Fractional Effective Concentration) levels which are often adopted to evaluate toxicity of fire smoke. As it is not possible to calculate these values directly from outputs of FDS, it was necessary to produce them by means of additional calculation procedures incorporating results of evacuation simulation. In this study, the latest version of FDS, which was recently updated in November 2013, was utilized for the purpose of quantitative comparison with the old version of FDS. As a result, it was found that they make about 10 percent difference on average in predicting FED and FEC levels for the cable fire case study.

A Research of Grain Size Analysis of Particulate Matter in Fire Effluent (연소 생성물 내 입자상 물질의 입도에 관한 연구)

  • Kim, Sung-Soo;Choi, Seo-Yeon;Rie, Dong-Ho
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.8-12
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    • 2014
  • Interior finishing materials using noncombustible were regulated by the building codes to prevent the spread of fire and protect occupants. The average deed of stopping time of experimental mouse exposing combustion gas were measured by KS F 2271 gas toxicity test. At that time, The average deed of stopping time under 9 minutes were judged a inconsistence. This experiment method has limit to find out a cause of toxicity effect factor. In this study, particle size analysis were performed for investigate a major factor.

Effect of nitrogen compounds on the chemical composition and biological activity of mainstream smoke (질소 화합물이 담배연기성분 및 안전성에 미치는 영향)

  • Shin, Han-Jae;Park, Chul-Hoon;Sohn, Hyung-Ok;Lee, Hyeong-Seok;Kim, Yong-Ha;Hyun, Hak-Chul
    • Journal of the Korean Society of Tobacco Science
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    • v.31 no.2
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    • pp.75-84
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    • 2009
  • The objective of this study was to investigate the effect of nitrogen compounds such as protein on the chemical composition and toxicity of cigarette mainstream smoke. BSA protein was treated into the tobacco leaf of original 2R4F cigarette at 1~4 % level. The studies were performed which included a bacterial mutagenicity assay and a mammalian cell cytotoxicity assay for total particulate matter(TPM), and glutathione(GSH) consumption assay for gas/vapor phase(GVP) and determination of smoke chemical constitute. Cigarettes treated with protein were observed dose-dependent increase in yield of volatiles, semi-volatiles and aromatic amines compared with control cigarette. However, carbonyl compounds such as acrolein was lower than that of control cigarette when calculated on an equal TPM basis. The cytotoxicity of TPM obtained from the protein-added cigarettes was not different from that of control cigarette. However, the mutagenicity of the TPM from protein-treated cigarettes(1~4 %) was up to 10-27 % higher than that of control. On the other hand, toxicity of GVP from protein-treated cigarette(4 %) was significantly decreased compared with control cigarette. An overall assessment of our data suggests that nitrogen compounds such as protein should be important for the chemical composition and biological activity of cigarette mainstream smoke.