• Title/Summary/Keyword: gas quantity

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A NUMERICAL STUDY ON THE FLOW CHARACTERISTICS OF GAS CHROMATOGRAPHIC COLUMN (가스 크로마토그래픽 컬럼의 유동특성에 대한 수치적 연구)

  • Kim T.-A.;Kim Youn J.
    • 한국전산유체공학회:학술대회논문집
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    • 2005.10a
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    • pp.21-26
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    • 2005
  • Gas Chromatography (GC) is a wisely technique used for the separation and analysis of liquid and gas sample. Separation of the sample vapors is achieved via their differential migration through a capillary column with an insert carrier gas. The identity and quantity of each vapor in the mixer can be determined from its retention time in the column and a particular property of the gas, such as thermal conductivity, which can be related to the concentration of sample vapor in the carrier gas. Therefore, the flow characteristics in the spiral gas chromatographic column are numerically investigated in this study. Especially, different pressure drop between the front and the rear of GC column with various flow rates is estimated the governing equations are derived from making using of three-dimensional Naver-Stokes equation with incompressible and laminar model due to the nature of low Reynolds number flow. Using a commercial code, FLUENT, the pressure and flow fields in GC column are calculated with various flow rates. The characteristics of thermal cycling which is one of the most important factors affecting the column efficiency and analysis time is also estimated. Furthermore, numerical analyses are also carried out by using commercial code, ANSYS, with various values of power, which is applied to the heating element located at lower GC column.

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Effect of Oxidation Multi-Walled Carbon Nanotubes for Methane Hydrate Formation (산화탄소나노튜브를 이용한 메탄 하이드레이트 형성)

  • Park, Sung-Seek;Kim, Nam-Jin
    • Journal of the Korean Solar Energy Society
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    • v.30 no.5
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    • pp.11-16
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    • 2010
  • Methane hydrate is crystalline ice-like compounds which formed methane gas enters within water molecules composed cavity and each other from physically-bond at specially temperature and pressure condition. $1m^3$ of methane hydrate can be decomposed into the maximum of $216m^3$ of methane gas under standard condition. If these characteristics of hydrate are utilized in the opposite sense, natural gas can be fixed into water in the form of a hydrate solid. Therefore the use of hydrate is considered to be a great way to transport and store natural gas in large quantity. However, when methane hydrate is formed artificially, the amount of gas that is consumed is relatively low, due to the slow reaction rate between water and methane gas. Therefore for practical purposes in the application, the present investigation focuses on increasing the amount of gas consumed by adding chemically oxidized OMWCNTs to pure water. The results show that when 0.003 wt% of oxidation multi-walled carbon nanotubes was added to pure water, the amount of gas consumed was almost four times more than that of pure water indicating its effect in hydrate formation and the hydrate formation time decreased at alow subcooling temperature.

Estimation of Economic Effects on Overseas Oil and Gas E&P by Macroeconomic Model of Korea (거시경제모형을 이용한 해외석유가스개발사업의 경제적 효과 추정 연구)

  • Kim, Ji-Whan;Chung, Woo Jin;Kim, Yoon Kyung
    • Environmental and Resource Economics Review
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    • v.23 no.1
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    • pp.133-156
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    • 2014
  • In general, quantity results of empirical analysis using model shows how much big performance policy has. Therefore this is useful to evaluate a policy. This paper composed macro economic model based on Bank of Korea's quarterly model and annual model, that estimates performance of overseas oil and gas development project to Korean economy in aspect of quantity. In this model, we estimated each effect in real GDP, current account, unemployment rate, CPI and exchange rate carried by recovered amount from overseas oil and gas development project. The recovered amount was evaluated in currency coming from oil and gas acquired from overseas oil and gas development project. Macro economic model of this paper benchmarked macro model composed by Bank of Korea(1997, 2004, 2012). We reviewed model robustness using statistical suitability of each equation and historical simulation for from 1994 to 2011. The recovered amount of overseas oil and gas development project has positive effect in every macro economic index except CPI and exchange rate. Economic effect to macro economic index become bigger with time because the recovered amount of overseas oil and gas development project are increasing until now. Although empirical results of economic effects in every year from the recovered amount of overseas oil and gas development project are different, as of 2011, empirical results showed that the recovered amount of overseas oil and gas development project increase 2.226% and 0.401% in current account and real GDP respectively. And it also decrease 0.489%p in unemployment rate. Exchange rate to US dollars also decrease in amount of 0.379%.

A Study on the Measurement of Gas Discharge from the Gas Vent of Sanitary Landfill(1)- analysis for minimizing the measurement error of flow meter - (쓰레기 매립지 가스포집관에서 유출가스 계측에 관한 연구(1) -유량계 계측오차의 최소화를 위한 해석 -)

  • 이해승;이찬기
    • Journal of Korea Soil Environment Society
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    • v.3 no.1
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    • pp.83-92
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    • 1998
  • This study presents a relationship between gas quantity and measurement resistance using the bubble meter, the water head indicator and the rotor meter from the gas vent sanitary landfill. From the one-dimensional analyses and experiments, the below results have been obtained. The gas volume sourcing from the gas vent depends on the permeability of final cover soil, its cover depth and distance between the gas vents. The total gas volume producing in the interested domain may be accurately measured by the bubble meter, the water head indicator and the rotor meter if the clay is used for the final cover soil. The required times approaching to the steady-state are different with respect to the flow meters, one day is for the bubble meter and the water head indicator and one hour for the rotor meter.

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A Case Study and Investigation on the Resource Assesment of Gas Hydrate (가스하이드레이트 부존량 평가 기술분석 및 적용사례)

  • Shin, Chang-Hoon;Han, Jeong-Min;Lee, Jeong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.682-685
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    • 2009
  • Several studies are being carried out to develop the reliable methods for the gas hydrate resource evaluation around the world. In this study, some case studies and investigations on the resource assesment of several advanced research teams were tried and then detail information on the evaluation scheme and technology of each team and nation are explained and analyzed for the future study and development. On top of that, main concepts and major parameters which can affect the quantity of assessment are examined and arranged for applying to our Donghae gas hydrate field case. Finally, the major concepts and methodology for this evaluation are brought forth and a schematic diagram for the main steps are come up with as well.

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A Development of the electronic controlled vaporizer for low flow anesthesia (저유량 마취를 위한 전자제어식 기화기 개발)

  • Oh, Yeong-Taek;Park, Jae-Hoon;Chang, In-Bae
    • Journal of Industrial Technology
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    • v.29 no.B
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    • pp.107-113
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    • 2009
  • For the environmental safety of the operating room and patient healthcare, the closed type rebreathing system is widely adopted. In order to reduce the anesthesia gas during surgery, the mixing ratio of anesthesia gas with breathing air should be precisely controlled. Generally, the breathing air passes through the vaporizer to mix the anesthesia gas, but there is a difficulty in controlling the mixing ratio precisely. In this paper, the stand-alone style vaporizer is designed and the operating characteristics are investigated. The vaporizer measures the temperature and pressure in the vaporizing chamber and chamber temperature is precisely controlled by proportional controlled heater. Exact quantity of anesthesia media is feeded by PID controlled peristaltic pump and vaporized gas is mixed with breathing air flow by PWM controlled solenoid valve. The experimental result shows that the vaporizer has an excellent command following performances that it can be applied to the low flow anesthesia system.

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Gas Permeation Characteristics of Porous Alumina Membrane Prepared by Anodic Oxidation (양극산화에 의한 다공성 알루미나 막의 기체투과 특성)

  • 함영민
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.72-78
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    • 1998
  • For investigation into gas permeation characteristics, the porous alumina membrane with asymmetrical structure, having upper layer with 10 nanometer under of pore diameter and lower layer with 36 nanometer of pore diameter, was prepared by anodic oxidation using DC power supply of constant current mode in an aqueous solution of sulfuric acid. The aluminium plate was pre-treated with thermal oxidation, chemical polishing and electrochemical polishing before anodic oxidation. Because the pore size depended upon the electrolyte, electrolyte concentration, temperature, current density, and so on, the the membranes were prepared by controling the current density, as a very low current density for upper layer of membrane and a high current density for lower layer of membrane. By control of current quantity, the thicknesses of upper layer of membranes were about $6{\;}{\mu}m$ and the total thicknesses of membranes were about $80-90{\;}{\mu}m$. We found that the mechanism of gas permeation depended on model of the Knudsen flow for the membrane prepared at each condition.

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On the Pyrolysis of Polymers IV. Pyrolysis of Polythylene and Polypropylene (高分子物質의 熱分解에 關한 硏究 (第4報) Polyethylene 및 Polypropylene의 熱分解에 關하여)

  • Chwa-Kyung Sung;Icksam Noh;Jung Yup Kim;Sung Bong Chang
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.122-127
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    • 1963
  • Pyrolysis fo polyethylene and polypropylene has been studied in order to clarify the mechanism of chain scission and effect of oxygen on degradation. Rate of weight decrease was measured under nitrogen and air atmosphere at constant temperature for the samples of high density polyethylene, low density polyethylene and isotactic polypropylene, and then gaseous hydrocarbons produced from pyrolysis were analysed by gas chromatography. Although there is little substantial difference between composition of hydrocarbon gases from pyrolysis of high density polyethylene and low density polyethylene except some difference in quantity of total gas produced, gas composition from polypropylene pyrolysis differs from that of polyethylene pyrolysis. Gases from pyrolysis under air contain much more unsaturated hydrocarbons than those from pyrolysis under inert gas.

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Implementation of a Residual Quantity Monitoring System in a Liquefied Gas Storage Tank based on Wireless Sensor Network Technology (무선센서 네트워크 기술 기반 액화가스 저장탱크 내 잔량 모니터링 시스템 구현)

  • Kim, Min-Kyu;Han, Hae-Jin;Han, Jaehwan
    • Journal of Sensor Science and Technology
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    • v.27 no.5
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    • pp.352-356
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    • 2018
  • This paper relates to a technology for monitoring a liquefied gas storage tank in the special gas field where demand is increasing owing to the continuous growth of related fields such as the semiconductor, display, and ICT convergence electronics industries. We have proposed a system for real - time monitoring using wireless sensor network technology, and implemented a system consisting of a sensor unit, transmitter module, and receiver module to be attached to a liquefied gas storage tank. The system was applied to LCO2 tanks among various liquefied gas storage tanks to verify the feasibility. The storage tanks employed in the experiments has capacities of 16,179 l and was 1,920 mm in inner diameter. Furthermore, the density was 1.03 g/l. The measured data were compared with reference data on the remaining gas level versus the $CO_2$ height of the surface, expressed using a conventional water meter, provided by an existing storage tank supplier. The experimental results show that the data is similar to the standard data provided by the tank supplier, and has a high accuracy and reliability within an error range of 0.03%.