• Title/Summary/Keyword: gas film

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The Effect Of Additive $N_2$ Gas In Pt Film Etching Using Inductively Coupled $Cl_2/Ar$ Plasmas ($Cl_2/Ar$ 유도 결합 플라즈마에서 Pt 박막 식각시 $N_2$ 가스 첨가 효과)

  • Ryu, Jae-Heung;Kim, Nam-Hoon;Chang, Eui-Goo;Kim, Chang-Il
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.7
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    • pp.1-6
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    • 2000
  • In this study, the effects of the addition of $N_2$ gas into the $Cl_2$ (90)/Ar(10) gas mixture, which has been proposed as the optimized etching gas combination, for etching of platinum was performed. The selectivity of platinum film to $SiO_2$ film etch mask increased with the addition of $N_2$ gas, and etch profile over 75 $^{\circ}$ could be obtained when 20 % additive $N_2$ gas was added. These phenomena were interpreted as the results of a formation of blocking layer such as Si-N or Si-O-N on the $SiO_2$ mask. The maximum etch rate of Pt film and selectivity of Pt to $SiO_2$ are 1425 ${\AA}$/min and 1.71, respectively. These improvements were considered to be due to the formation of more volatile compounds such as Pt-N or Pt-N-Cl.

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Effect of Intermediate Metal on the Methanol Gas Sensitivity of ITO Thin Films (층간금속층에 따른 ITO 박막의 메탄올 검출민감도 개선 효과)

  • Lee, H.M.;Heo, S.B.;Kong, Y.M.;Kim, Dae-Il
    • Journal of the Korean Vacuum Society
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    • v.20 no.3
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    • pp.195-199
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    • 2011
  • ITO thin films and gold (Au), copper (Cu) and nickel (Ni) intermediate ITO multilayer (ITO/Au/ITO, ITO/Cu/ITO, ITO/Ni/ITO) films were deposited on glass substrates with a reactive radio frequency and direct current magnetron sputtering system and then the effect of intermediate metal layer and annealing temperature on the methanol gas sensitivity of ITO films were investigated. Although both ITO and ITO/metal/ITO (IMI) film sensors have the same total thickness of 100 nm, IMI sensors have a sandwich structure of ITO 50 nm/metal 10 nm/ITO 40 nm. The change in the gas sensitivity of the film sensors caused by methanol gas ranging from 100 to 1000 ppm was measured at room temperature. The IAI film sensors showed the higher sensitivity than the other sensors. Finally, it is concluded that the ITO 50/Au 10/ITO 40 nm film sensors hasthe potential to be used as improved methanol gas sensor.

Synthesis of Diamond Thin Film by RF PACVD from $\textrm{H}_2$-$\textrm{CH}_4$ Mixed Gas (고주파 플라즈마 CVD에 의한 $\textrm{H}_2$-$\textrm{CH}_4$ 계로부터 다이아몬드 박막의 합성)

  • 임헌찬
    • Journal of the Korean Institute of Telematics and Electronics T
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    • v.36T no.3
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    • pp.13-18
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    • 1999
  • Diamond film was deposited on Si wafer using $\textrm{H}_2$ and $\textrm{CH}_4$ mixed gas by RF PACVD. Prior to deposition, mechanical scratching was done to improve density of nucleation sites with diamond paste of $1\mu\textrm{m}$ The microstructure of deposited film was studied at various methane concentrations. The deposited film was characterized by XRD(X-tay diffraction), SEM(Scanning Electron Microscopy) and Raman Spectroscopy The deposited diamond film showed that the crystallite was increased at the lower methane concentration.

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Characteristic of Tantalum Nitride Thin-films for High Precision Resistors (고정밀 저항용 질화탄탈 박막의 특성)

  • Choi, Sung-Kyu;Na, Kyung-Il;Nam, Hyo-Duk;Chung, Gwiy-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.537-540
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    • 2001
  • This paper presents the characteristics of Ta-N thin-film for high precision resistors, which were deposited on Si substrate by DC reactive magnetron sputtering in an argon-nitrogen atmosphere(Ar-(4~16 %)$N_2$). Structural properties studied using X-ray diffraction(XRD) indicate the presence of TaN, $Ta_3N_5$ or a mixture of Ta-N phases in the films depending on the amount of nitrogen in the sputtering gas. The chemical composition are investigated by auger electro spectroscopy(AES). The optimized conditions of Ta-N thin-film resistors were deposited in 4 % $N_2$ gas flow ratio. Under optimum conditions, the Ta-N thin-film resistors are obtained a high resistivity, $\rho=305.7{\mu}{\Omega}cm$, a low temperature coefficient of resistance, TCR=-36 $ppm/^{\circ}C$.

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A Study on the Responsibility of Thin film instantaneous surface temperature probe of a Dual-pipe structure (이중관 구조 박막형 순간온도 프로브의 응답성에 관한 연구)

  • Choi, Seok-Ryeol;Park, Kyoung-Suk
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.237-242
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    • 2003
  • The measurement study of instantaneous temperature at combustion chamber wall and the temperature of combustion gas has been under lots of research and development to conclude the temperature process in internal combustion engine for combustion characteristics analysis. The measurement with fast responsibility should be used for temperature measurement inside combustion chamber wall since temperature of wall changes, due to the various gas temperature, irregularly during the combustion. Therefore, thin film instantaneous surface temperature probe, which characterizes the fastest and the most accurate responsibility among contact typed temperature measurement, was used for the experiments. This new thin film instantaneous surface temperature probe improved the problems of noise and durability. The optimal coating thickness of thin film instantaneous surface temperature probe was proven to be $10{\mu}m$ for the best responsibility and durability. It also allowed the stable temperature measurement be taken up to $1,200^{\circ}C$ and proven to be read possibly from the combustion chamber wall.

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Effect of nitrogen doping on properties of plasma polymerized poly (ethylene glycol) film

  • Javid, Amjed;Long, Wen;Lee, Joon S.;Kim, Jay B.;Sahu, B.B.;Jin, Su B.;Han, Jeon G.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.286-288
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    • 2014
  • This study deals with the catalyst free radio frequency plasma assisted polymerization of ethylene glycol using nitrogen as reactive gas to modify the surface chemistry and morphology. The deposited film was characterized through various analysis techniques i.e. surface profilometry, Forier transform infrared spectroscopy, water contact angle and UV-visible spectroscopy to analyze film thickness, chemical structure, surface energy and optical properties respectively. The surface topography was analyzed by Atomic force microscopy. It was observed that the ethylene oxide behaviour and optical transmittance of the film were reduced with the introduction of nitrogen gas due to higher fragmentation of monomer. However the hydrophilic behavior of the film improved due to formation of new water loving functional groups suitable for biomedical applications.

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Characteristics of Pd doped $SnO_2$ gas sensitive thin films (Pd이 도핑된 $SnO_2$ 박막 가스감지막의 특성)

  • Kim, Jin-Hae;Kim, Dae-Hyun;Lee, Yong-Sung;Kim, Jeong-Gyoo;Jeon, Choon-Bae;Park, Hyo-Derk;Park, Ki-Cheol
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1779-1781
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    • 2000
  • Pd doped $SnO_2$ thin film sensors were prepared on alumina substrate by rf magnetron sputtering method. The sensitivity of thin film was investigated by varying the heat-treatment temperature, film thickness and gas species. The thin film heat-treated at 600$^{\circ}C$ and film thickness of 5000${\AA}$ showed the highest sensitivity at an operating temperature of 400$^{\circ}C$.

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Conducting Metal Oxide Interdigitated Electrodes for Semiconducting Metal Oxide Gas Sensors

  • Shim, Young-Seok;Moon, Hi-Gyu;Kim, Do-Hong;Jang, Ho-Won;Yoon, Young-Soo;Yoon, Soek-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.65-65
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    • 2011
  • We report the application of conducting metal oxide electrodes for semiconducting metal oxide gas sensors. Pt interdigitated electrodes have been commonly used for metal oxide gas sensor because of the low resistivity, excellent thermal and chemical stability of Pt. However, the high cost of Pt is an obstacle for the wide use of metal oxide gas sensors compared with its counterpart electrochemical gas sensors. Meanwhile, relatively low-cost conducting metal oxides are widely being used for light-emitting diodes, flat panel displays, solar cell and etc. In this work, we have fabricated $WO_3$ and $SnO_2$ thin film gas sensors using interdigitated electrodes of conducting metal oxides. Thin film gas sensors based on conducting metal oxides exhibited superior gas sensing properties than those using Pt interdigitated electrodes. The result was attributed to the low contact resistance between the conducting metal oxide and the sensing material. Consequently, we demonstrated the feasibility of conducting metal oxide interdigitated electrodes for novel gas sensors.

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