• Korean Chemical Engineering Research
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• v.57 no.4
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• pp.525-530
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• 2019

The performance and stability of solid oxide fuel cells (SOFCs) depend on the microstructure of the electrode and electrolyte. In anode, porosity and pore distribution affect the active site and fuel gas transfer. In an electrolyte, density and thickness determine the ohmic resistance. To optimizing these conditions, using costly method cannot be a suitable research plan for aiming at commercialization. To solve these drawbacks, we made high performance unit cells with low cost and highly efficient ceramic processes. We selected the NiO-YSZ cermet that is a commercial anode material and used facile methods like die pressing and dip coating process. The porosity of anode was controlled by the amount of carbon black (CB) pore former from 10 wt% to 20 wt% and final sintering temperature from $1350^{\circ}C$ to $1450^{\circ}C$. To achieve a dense thin film electrolyte, the thickness and microstructure of electrolyte were controlled by changing the YSZ loading (vol%) of the slurry from 1 vol% to 5 vol. From results, we achieved the 40% porosity that is well known as an optimum value in Ni-YSZ anode, by adding 15wt% of CB and sintering at $1350^{\circ}C$. YSZ electrolyte thickness was controllable from $2{\mu}m$ to $28{\mu}m$ and dense microstructure is formed at 3vol% of YSZ loading via dip coating process. Finally, a unit cell composed of Ni-YSZ anode with 40% porosity, YSZ electrolyte with a $22{\mu}m$ thickness and LSM-YSZ cathode had a maximum power density of $1.426Wcm^{-2}$ at $800^{\circ}C$.

• Clean Technology
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• v.24 no.4
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• pp.323-331
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• 2018

The results of an experimental investigation on the co-firing characteristics and slagging behavior of dried and hydrothermal carbonization sewage sludge, sub-bituminous coal, and wood pellet in a fluidized bed were presented. Combustion tests were conducted in a lab-scale bubbling fluidized bed system at the uniform fuel-air equivalence ratio, air flow rate, and initial bed temperature to measure bed temperature distribution and combustion gas composition. 4 different fuel blending cases were prepared by mixing sewage sludge fuels with coal and wood pellet with the ratio of 50 : 50 by the heating value. $NO_x$ was mostly NO than $NO_2$ and measured in the range of 400 to 600 ppm in all cases. $SO_2$ was considered to be affected mostly by the sulfur content of the sewage sludge fuels. The cases of hydrothermal carbonization sewage sludge mixture showed slightly less $SO_2$ emission but higher fuel-N conversion than the dried sewage sludge mixing cases. The result of fly ash composition analysis implied that the sewage sludge fuels would increase the possibility of slagging/fouling considering the contents of alkali species, such as Na, K, P. Between the two different sewage sludge fuels, dried sewage sludge fuel was expected to have the more severe impact on slagging/fouling behavior than hydrothermal carbonization sewage sludge fuel.

• Journal of Korean Society of Forest Science
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• v.100 no.3
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• pp.466-475
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• 2011

This study purposed to analyze the spatial pattern and the amount of carbon emission at the deforestation area based on the administrative and GIS data. The total size of deforestation area in last nine years (2000-2008) was about 649 ha, and it was occurred annually about 72 ha. The occurrence rate of deforestation per administrative area in Wonju was about 0.74%. It was 0.34% higher than that of Kwangwondo, and 0.06% less than that of National rate. On the other hand, the forms of deforestation by purpose were not related to the administrative district unit. The number of deforestation forms was highest at settlements. second most frequent form is other land. Grassland showed the lowest score. In addition, the deforestations were more occurred which is closed to the existing housing and building rather than roads. The number of deforestation was 1.2 times higher based on 300m. Seventy percent of deforestation was occurred which is less than 0.5 ha in size, and it increased to 91% when the size is less than 1ha. The total size of theoretical carbon emission based on deforestation area was estimated at 23,424 tc, and average annual carbon emission was estimated by 2,603 tc. Carbon emission per ha was 36.1 tC/ha. This study results will be useful to construct the greenhouse gas statistical verification system against the Post-2012 by GIS.

• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.429-432
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• 2011

The feasibility of applications of the char obtained from a gasification process of municipal-waste refuse derived fuel (RDF) as an auxiliary fuel was evaluated by combustion experiments. The higher heating value of the RDF char was 3000~4000 kcal/kg and its chlorine content was below the standard requirement demonstrating its potential as an auxiliary fuel. In the combustion exhaust gas, the maximum $NO_x$ and $SO_2$ concentrations were 240 ppm and 223 ppm, respectively. If an aftertreatment is applied, it is possible to control their concentrations low enough to meet the air pollutant emission standard. The HCl concentration was relatively high indicating that a care should be taken for HCl emission from the combustion of RDF. Based on the temperature distribution within the reactor, the concentration change of $O_2$ and $CO_2$, and the amount and the loss on ignition of solid residue, it was inferred that the combustion reaction was the most reliable when the excess air ratio of 1.3 was used.

• Clean Technology
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• v.27 no.1
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• pp.61-68
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• 2021

Selective catalytic reduction (SCR) is widely used as a method of removing nitrogen oxide in large-capacity thermal power generation systems. Uniform mixing of the injected ammonia and the inlet flue gas is very important to the performance of the denitrification reduction process in the catalyst bed. In the present study, a computational analysis technique was applied to the ammonia injection system design process of a denitrification facility. The applied model is the denitrification facility of an 800 MW class coal-fired power plant currently in operation. The flow field to be solved ranges from the inlet of the ammonia injection system to the end of the catalyst bed. The flow was analyzed in the two-dimensional domain assuming incompressible. The steady-state turbulent flow was solved with the commercial software named ANSYS-Fluent. The nozzle arrangement gap and injection flow rate in the ammonia injection system were chosen as the design parameters. A total of four (4) cases were simulated and compared. The root mean square of the NH3/NO molar ratio at the inlet of the catalyst layer was chosen as the optimization parameter and the design of the experiment was used as the base of the optimization algorithm. The case where the nozzle pitch and flow rate were adjusted at the same time was the best in terms of flow uniformity.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.26 no.4
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• pp.291-306
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• 2021

From the climate change scenario experiments of 21 models participating in Coupled Climate Model Inter-comparison Project Phase 6, future changes of sea surface temperature (SST) and Kuroshio in the Northwest Pacific were analyzed. The spatial feature of SST change was found to be related to the change of the current speed and spatial distribution of Kuroshio. To investigate the relationship between the change in latitude of the Kuroshio extension region, which flows along the boundary between the subtropical gyre and the subarctic gyre in the North Pacific, and the large-scale atmospheric circulation due to global warming, the zero-windstress curl line for each climate change experiment from 9 out of 21 models were compared. As the atmospheric radiative forcing increases due to the increase of greenhouse gases, it was confirmed that the zero-windstress curl line moves northward, which is consistent with the observation. These results indicate that as the Hadley Circulation expands to the north due to global warming, the warming of the mid-latitudes to which the Korean Peninsula belongs may be accelerated. The volume transport and temperature of the Tsushima Warm Current flowing into the East Sea through the Korea Strait also increased as the atmospheric radiative forcing increased.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.28 no.1
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• pp.31-38
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• 2022

Due to the increasing consumer demands for the safety, shelf life, and quality of food, the application and development of active packaging in the food and packaging industry have been improved. According to the standards and specifications of the Republic of Korea for utensils, containers, and packages, the function of active packaging is to remove or alleviate factors that degrade food quality. Although extensive reviews regarding the development and commercialization of active packaging have been conducted, the legal regulations and safety assessments concerning active packaging have rarely been examined. This review provides information regarding the definition, structure, components, operational mechanisms, and applications for active packaging that actively removes oxygen, moisture, carbon dioxide, and ethylene. Furthermore, the legal regulations and research results related to the development of test methods for safety assessments of active packaging are investigated.

• Analytical Science and Technology
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• v.22 no.3
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• pp.191-200
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• 2009

The aim of this study was to evaluate and establish of emission test method for liquid phase building materials such as paint, adhesive, sealant by emission cell. A small-scale emission chamber and emission cell were used to evaluate emission of TVOC from paint, adhesive, sealant. The quantity of TVOC emission were measured by a gas chromatography/mass spectrometry (GC/MS). Background concentration of TVOC was below $10{\mu}g/m^3$ in the emission chamber and cell. Air tightness and recovery in chamber and cell showed good results. The recovery of thermal desorber for toluene and n-dodecane were about 120%. The repeatability of response factor and retention time in GC/MS below 30%. The method detection limit of VOCs ranged 0.04~8.82 ng. The concentration of TVOC emission using emission cell was 1.35~1.41 times higher than emission chamber. The correlation of TVOC emission using chamber and cell method was significantly high (r=0.91~0.97).

• Journal of the Korean Society of Marine Environment & Safety
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• v.29 no.7
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• pp.971-979
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• 2023

Small ships (<499 GT) constitute 46% of the existing ships, therefore, it can be concluded that they produce relatively high CO₂ gas emissions. Operating in optimal trim conditions can reduce the resistance of the ship, which results in fewer greenhouse gases. An affordable way for trim optimization is to adjust the weight distribution to obtain an optimum longitudinal center of gravity (LCG). Therefore, in this study, the effect of LCG changes on the resistance of a small planing ship is studied using empirical and numerical analyses. The Savitsky method employing Maxsurf resistance and the STAR-CCM+ commercial computational fluid dynamics (CFD) software is used for the empirical and numerical analyses, respectively. Finally, the total resistance from the ship design process is compared to obtain the optimum LCG. To summarize, using numerical analysis, optimum LCG is achieved at the 46.2% length overall (LoA) at Froude Number 0.56, and 43.4% LoA at Froude Number 0.63, which provides a significant resistance reduction of 41.12 - 45.16% compared to the reference point at 29.2% LoA.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.12 no.3
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• pp.244-250
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• 2007

Membrane inlet mass spectrometer (MIMS) has been used to accurately quantify dissolved gases in liquid samples. In this study, the MIMS system was applied to measure dissolved methane in seawater and sediment porewater. To evaluate the accuracy of the measurement, liquid samples saturated with different methane partial pressure were prepared and the methane concentrations were quantified with the MIMS system. The measured values correspond well with the expected values calculated from solubility constants. The standard error of the measurements were $0.13{\sim}0.9%$ of the mean values. The distribution of dissolved methane concentration in seawater of the South Sea of Korea revealed that the physical parameters primarily control the methane concentration in sea water. The MIMS system was effective to resolve the small dissolved methane difference among water masses. The probe type inlet in MIMS system was proven to be effective to measure porewater methane concentration.