• 제목/요약/키워드: gas diffusion

검색결과 1,046건 처리시간 0.031초

산화막을 입힌 지르코늄 합금의 수소화 반응에 관한 연구 (A Study on the Hydriding Reaction of Pre-oxidized Zr Alloys)

  • 김선기;방제건;김대호;임익성;양용식;송근우
    • 한국세라믹학회지
    • /
    • 제47권2호
    • /
    • pp.106-112
    • /
    • 2010
  • This paper presents some experimental results on incubation time for massive hydriding of Zr alloys with oxide thickness. Oxide effects experiments on massive hydriding reaction of commercial Zr alloy claddings and pre-oxidized Zr alloys with hydrogen gas were carried out in the temperature range from 300 to $400^{\circ}C$ with thermo-gravimetric apparatus. Experimental results for oxide effects on massive hydriding kinetics show that incubation time is not proportional to oxide thickness and that the massive hydriding kinetics of pre-filmed Zr alloys follows linear kinetic law and the hydriding rate are similar to that of oxide-free Zr alloys once massive hydriding is initiated. There was a difference in micro-structures between oxide during incubation time and oxide after incubation time. Physical defects such as micro-cracks and pores were observed in only oxide after incubation time. Therefore, the massive hydriding of Zr alloys seems to be ascribed to short circuit path, mechacical or physical defects, such as micro-cracks and pores in the oxide rather than hydrogen diffusion through the oxide resulting from the increase of oxygen vacancies in the hypostoichiometric oxide.

$N_2O$ 가스에서 열산화막의 재산화에 의해 형성된 oxynitride막의 특성 (Properties of the oxynitride films prepared by reoxidation of thermal oxide in $N_2O$)

  • 배성식;이철인;최현식;서용진;김태형;김창일;장의구
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1993년도 춘계학술대회 논문집
    • /
    • pp.39-43
    • /
    • 1993
  • Electricial characteristics of gate dielectrics prepared by reoxidation of thermal $SiO_2$ in nitrous oxide gas have been investigated. 10 and 19nm-thick oxides were reoxidized at temperatures of $900-1000^{\circ}C$ for 10-60 min in $N_2O$ ambient. As reoxidation proceeds, it is shown that nitrogen concentration at $Si/SiO_2$ interface increases gradually through the AES analysis. Nitrogen pile-up at $Si/SiO_2$ interface acts as a oxidant diffusion barrier that reduces the oxidation rate significantly. And it not only strengthen oxynitride structure at the interface but improve the gate dielectric qualities. Reliabilities of oxynitride films are conformed by the breakdown distributions and constant current stress technique. Therefore, the oxynitride films made by this process show a good promise for future ULSI applications.

  • PDF

초소형 촉매 이상 분해 반응기 해석 모델 개발 (Development of Analysis Model for Down Scaled Two Phase Catalytic Reactor)

  • 이대훈;권세진
    • 대한기계학회논문집B
    • /
    • 제28권1호
    • /
    • pp.24-30
    • /
    • 2004
  • Analysis model for the two-phase catalytic reactor is presented. With the progress in development of micro thermofluidic devices, needs fur understanding of the phenomena in two phase reaction in cm scale has been arisen. To investigate thermal and reactive performance of down scaled two phase reactor simple analysis model that is a kind of lumped flow model is proposed. Analysis model presented is based on the experiment on mm scale model reactor. Target experiment is catalytic decomposition of 70wt% hydrogen peroxide with existence of perovskite L $a_{0.8}$S $r_{0.2}$Co $O_3$ catalyst. It is composed of balance equations of mass and energy. Each phase is considered to be a species fur the simplicity. Axial diffusion and transversal distribution of properties are neglected. Two phase catalytic reaction is modeled as successive gasification of liquid lump around catalyst and reaction in gas phase. Heat transfer is modeled by model function ofNu number. Modeled Nu is expressed as Nu=N $u_{0}$ (1+ $a_1$( $a_2$ $T^{-}$ $a_3$)exp( $a_4$ $T^{-1}$)exp( $a_{5}$ z). Transfer coefficients are determined by the comparison of experimental results. With the model, heat transfer characteristics are investigated. Also by the mass transfer coefficient, characteristics in mass transfer is investigated. With the result basic understanding on design and analysis of mm scale two-phase reactive device is obtained. Also it can be further applied to micro scale reactive device fabricated by micromachining.ing..

미분쇄 탄소섬유가 첨가된 피치계 탄소섬유기반 기체확산층용 탄소종이 특성 (Characterization of Milled Carbon Fibers-filled Pitch-based Carbon Paper for Gas Diffusion Layer)

  • 함은광;윤동호;김병석;서민강
    • Composites Research
    • /
    • 제29권5호
    • /
    • pp.262-268
    • /
    • 2016
  • 본 연구에서는 피치계 탄소섬유기반 탄소종이에 바인더 피치와 PAN계 미분쇄 탄소섬유를 첨가하여 저온탄화를 통해 재함침된 탄소종이를 제작하였으며, 미분쇄 탄소섬유의 첨가가 탄소종이의 기계적 및 전기적 특성과 열전도도에 미치는 영향을 알아보았다. 실험 결과, 인장강도는 미분쇄 탄소섬유 함량 10 wt.%부터 20 wt.%까지 첨가하였을 때 크게 증가하였다. 또한, 미분쇄 탄소섬유 함량이 증가함에 따라 계면접촉저항은 감소하였으며, 전기전도도 및 열전도도는 증가하였다. 이러한 결과는 미분쇄된 탄소섬유의 첨가가 탄소종이의 밀도를 증가시킴에 따라 전기적 및 열적 전달 경로가 형성되었기 때문이라고 판단된다.

3가지 니들구동방식별 CRDi 디젤엔진용 고압 인젝터의 거시적 분무특성 비교해석 (Analysis of Macroscopic Spray Characteristics of Diesel Injectors with Three Different Needle Driving Type in Common Rail Direct Injection System)

  • 이진욱;민경덕
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제30권3호
    • /
    • pp.351-358
    • /
    • 2006
  • The capability of high pressure injection with small fuel quantify at all engine operating conditions is one of the main feature in common rail fuel injection system, which is used in small and light-duty Diesel engine. The key parameter for the better atomized fuel sprays and multiple injections of this common rail fuel injection control, that can be freely selected irrespective of the engine speed and load is the mechanism controlling the needle energizing and movement in high pressure Diesel injector. In the electro-hydraulic injector, the injection nozzle is being opened and closed by movement of the injector's needle which is balanced by pressure between the nozzle seat and the needle control chamber. This study describes the macroscopic spray structure characteristics of the common rail Diesel injectors with different electric driving method i.e. the solenoid-driven and piezo-driven type. The macroscopic spray characteristics such as spray tip speed. spray tip penetration and spray cone angle were investigated by the high speed spray, which is measured by the back diffusion light illumination method with optical system for the high speed temporal photography in a constant volume chamber pressurized by nitrogen gas. As the results, the prototype piezo-driven injector system was designed and fabricated for the first time in domestic case and the effect of injector's needle response driven by different drive type was compared between the solenoid and piezo-driven injector It was found therefore. that the piezo-driven injector showed faster needle response and had better needle control capability by altering the electric input value than the solenoid-driven injector.

급성 일산화탄소 중독환자에서 병원 전 고산소혈증이 장기 신경학적 예후에 미치는 영향 (Associations between Early Hyperoxia and Long Term Neurologic Outcome in Acute Carbon Monoxide Poisoning)

  • 김주찬;전병조;문정미;조용수
    • 대한임상독성학회지
    • /
    • 제18권1호
    • /
    • pp.18-25
    • /
    • 2020
  • Purpose: We studied the impact of arterial oxygen tension (PaO2) on the long term neurologic outcome in patients with acute carbon monoxide poisoning. Methods: The study population included 311 patients who presented to emergency department with acute CO poisoning from January 2015 to January 2018. These patients underwent arterial blood gas testing at the time of presentation. The baseline demographic, clinical, laboratory, and clinical outcome data were recorded. The primary outcome of interest was the long term neurologic status. Results: The normoxia group was significantly older and it had a higher incidence of diffusion weighted MRI abnormality, and this group needed multiple HBO sessions compared to the group with moderate or severe hyperoxia. Also, the incidence of altered mentality at discharge was higher in the normoxia group than that of the moderate hyperoxia group. The incidence of a poor long term neurologic outcome was 11.3%. The incidence of a poor long term neurologic outcome decreased as the PaO2 increased. The PaO2 was significantly lower in patients with a poor long term neurologic outcome than that of the patients with a good outcome 198 (165.2 to 231.1) mmHg in the good outcome group vs. 154 (119-162) mmHg in poor outcome, p<0.001). In multivariate logistic regression analysis, PaO2 was selected as an independent factor of the poor long-term neurologic outcome (OR 0.981 (95% CI: 0.968 to 0.995)) Conclusion: Higher PaO2 was independently associated with a lower incidence of a poor long-term neurologic outcome.

Nitrous Oxide를 이용한 흡입진정 (Inhalation Sedation with Nitrous Oxide in Dental Treatment)

  • 윤형배
    • 대한치과마취과학회지
    • /
    • 제2권1호
    • /
    • pp.1-6
    • /
    • 2002
  • The usage of nitrous oxide is increased for the anxious patient to dental treatment. There are two methods to induce the sedation during dental treatment. One is sedation with drugs the other no need of drugs. We discussed here about sedation with drugs. The methods of drug administration are oral, intramuscular, intravenous, inhalation. The method of oral administration of drugs are convenient to patient and doctor but poor controllability. Intramuscular method is a parenteral technique that maintains several advantages over the enteral technique. However its pales in comparison to other parenteral technique. Intravenous method represents most effective method of ensuring predictable and adequate sedation in all patients. But it has inability to reverse the action of drugs after they have been injected except some drugs (e.g., narcotics and benzodiazepine). A variety of gaseous agents may be administered by inhalation to produce sedation. In dental practice, the inhalation administration of gas means use of nitrous oxide. There are many advantages of nitrous oxide administration. First, very short latent period and rapid onset of drug action which lead to possible titration of drug concentration. With nitrous oxide, clinical effects may become noticeable as quickly as 15 to 30 seconds after inhalation. Recovery from inhalation sedation is also quite rapid. In out patient dental practice rapid recovery is very important because it permit to discharge the patient without escort and the patient return to their ordinary life without limit. To success the conscious sedation with nitrous oxide, the administrator should be keep the mind that always titration of nitrous oxide concentration during induction and treatment. Careful observation need during treatment to prevent oversedation because the adequate nitrous oxide concentration to patients changed by environmental stress. Always begins with 100% oxygen and ends with 100% oxygen to prevent diffusion hypoxia which rare in clinical practice.

  • PDF

차세대 고응답 분사용 피에조 인젝터의 노즐유동 및 분무특성에 관한 연구 (A Study on Nozzle Flow and Spray Characteristics of Piezo Injector for Next Generation High Response Injection)

  • 이진욱;민경덕
    • 대한기계학회논문집B
    • /
    • 제30권6호
    • /
    • pp.553-559
    • /
    • 2006
  • Most diesel injector, which is currently used in high-pressure common rail fuel injection system of diesel engine, is driven by the solenoid coil energy for its needle movement. The main disadvantage of this solenoid-driven injector is a high power consumption, high power loss through solenoid coil and relatively fixed needle response's problem. In this study, a prototype piezo-driven injector, as a new injector mechanism driven by piezoelectric energy based on the concept of inverse piezo-electric effect, has been designed and fabricated to know the effect of piezo-driven injection processes on the diesel spray structure and internal nozzle flow. Firstly we investigated the spray characteristics in a constant volume chamber pressurized by nitrogen gas using the back diffusion light illumination method for high-speed temporal photography and also analyzed the inside nozzle flow by a fully transient simulation with cavitation model using VOF(volume of fraction) method. The numerical calculation has been performed to simulate the cavitating flow of 3-dimensional real size single hole nozzle along the injection duration. Results were compared between a conventional solenoid-driven injector and piezo-driven injector, both equipped with the same micro-sac multi-hole injection nozzle. The experimental results show that the piezo-driven injector has short injection delay and a faster spray development and produces higher injection velocity than the solenoid-driven injector. And the predicted simulation results with the degree of cavitation's generation inside nozzle for faster needle response In a piezo-driven injector were reflected to spray development in agreement with the experimental spray images.

비정상 소화 과정에서의 화염 온도 및 OH 라디칼의 변화 (Changes of the Flame Temperature and OH Radical in the Unsteady Extinction Process)

  • 이은도;이기호;오광철;신현동
    • 대한기계학회논문집B
    • /
    • 제28권12호
    • /
    • pp.1557-1566
    • /
    • 2004
  • A flame extinction phenomenon is a typical unsteady process in combustion. Flame extinction is characterized by various physical phenomena, such as convection, diffusion, and the production of heat and mass. Flame extinction can be achieved by either increasing the strain rate or curvature, by diluting an inert gas or inhibitor, or by increasing the thermal or radiant energy loss. Though the extinction is an inherently transient process, steady and quasi-steady approaches have been used as useful tools for understanding the flame extinction phenomenon. Recently, unsteady characteristics of flames have been studied by many researchers, and various attempts have been made to understand unsteady flame behavior, by using various extinction processes. Representative parameters for describing flame, such as flame temperature, important species related to reactions, and chemi-luminescence of the flame have been used as criterions of flame extinction. In these works, verification of each parameter and establishing the proper criterions of the extinction has been very important. In this study, a time-dependent flame temperature and an OH radical concentration were measured using optical methods, and the instantaneous change of the flame luminosity was also measured using a high-speed ICCD (HICCD) camera. We compare the unsteady extinction points obtained by three different methods, and we discuss transient characteristics of maximum flame temperature and OH radical distribution near the extinction limit.

DC magnetron sputtering법으로 제조된 Ti-Si-N코팅막의 내산화성에 관한 연구 (High-temperature oxidation resistance of Ti-Si-N coating layers prepared by DC magnetron sputtering method)

  • 최준보;류정민;조건;김광호;이미혜
    • 한국표면공학회지
    • /
    • 제35권6호
    • /
    • pp.415-421
    • /
    • 2002
  • Ti-Si-N coating layers were codeposited on silicon wafer substrates by a DC reactive magnetron sputtering technique using separate titanium and silicon targets in $N_2$/Ar gas mixtures. The oxidation behavior of Ti-Si-N coating layers containing 4.0 at.%, 10.0 at.%, and 27.3 at.% Si was investigated at temperatures ranging from 600 to $960^{\circ}C$. The coating layers containing 4.0 at.% Si became fast oxidized from $600^{\circ}C$ while the coating layers containing 10.0 at.% Si had oxidation resistance up to $800^{\circ}C$. It was concluded that an increase in Si content to a level of 10.0 at.% led to the formation of finer TiN grains and a uniformly distributed amorphous Si3N4 phase along grain boundaries, which acted as efficient diffusion barriers against oxidation. However, the coating layers containing 27.3 at.% Si showed relatively low oxidation resistance compared with those containing 10.0 at.% Si. This phenomenon would be explained by the existence of free Si which was not nitrified in the coating layers containing 27.3 at.% Si.