• Title/Summary/Keyword: gas diffusion

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Optimization of Inner Nitriding Process for Cr-Mo-V Steel of Small Arms Barrel by using Taguchi Experimental Design Method (다구찌 실험계획법을 이용한 소구경화기 총열 내부용 Cr-Mo-V강의 질화공정 최적화)

  • Kwon, Hyuk-Rin;Kim, Dong-Eun;Son, Hyung-Dong;Shin, Jea-Won;Park, Jae-Ha;Kang, Myung-Chang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.3
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    • pp.148-154
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    • 2018
  • When shooting small arms, the inner surface temperature is heated up to about $700{\sim}1,000^{\circ}C$ by the friction of the bullet and the inner wall of the barrel and the combustion of propellant. High-temperature propellant gas and high-speed movement of the bullet cause corrosion of the inner wall, which is noticeable immediately in front of the chamber. In this study, the mechanical properties of Cr-Mo-V steel, which is the base material, were tested using Taguchi experimental design to find the best nitriding treatment conditions. For the nitriding process, the working time, salt bath temperature, and salt concentration were combined as three conditions and placed in the $L_9(3^4)$, orthogonal array table. The thicknesses of the white layer and the nitrogen diffusion layer were measured after nitriding under each condition in a salt bath furnace. Durability was evaluated by measuring the degree of dispersion through actual shooting because it was difficult to evaluate the mechanical properties of the cylinder inner structure. As a result, it was confirmed that the durability was optimal at $565^{\circ}C$, 1 hour, 0.5%. These optimal conditions were selected by the statistical analysis of the Minitab program(ver.17).

Structural analysis in Metal bipolar plate of Fuel Cell Stack (금속분리판 연료전지 스택의 구조 해석)

  • Lee, Sang-Min;Jeon, Ji-Hoon;Lee, Chang-Woo;Suh, Jung-Do;Chang, Hoon;Kim, Sae-Hoon;Lee, Sung-Ho;Hwang, Woon-Bong
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.101-104
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    • 2007
  • Mechanical behavior in metal bipolar plate of a fuel cell stack was studied using finite element analysis. The fuel stack is essentially composed of a metal bipolar plate (metal BP), a gasket, an end plate, a membrane electrolyte assembly (MEA), and a gas diffusion layer (GDL). It is important to maintain a suitable fastening force of Metal BP, because it influences the power efficiency of the fuel cell stack. After a gasket and a GDL are placed on the metal BP, the reaction force with the displacement is measured. The channel of metal bipolar plate is replaced by a simple geometrical plate. The results of FEM are similar to those of experiment. Therefore mechanical behavior in metal BP of a fuel cell stack can be estimated by using FEM.

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Ordering in InGaAsP Epitaxial Layers Grown by low Pressure metalorganic Chemical Vapor Deposition (저압 MOCVD 방법으로 성장된 InGaAsP 에피층에서의 ordering 현상)

  • 김대연;문영부;이태완;윤의준;이정용;정현식
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.187-194
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    • 1998
  • InGaAsP epitaxial layers lattice matched to InP were grown at 600 and $620^{\circ}C$ by low pressure metalorganic chemical vapor deposition. Solid phase composition of group III was controlled by the diffusion flux gas phase to the reachion surface. For the case of group V, the difference of As and P vapor pressure and pyrolysis efficiency of $PH_3$and $AsH_3$ mainly determined their in corporation into solid. An abnormal behavior of peak energy shift was observed below 75K in temperature variant photoluminescence study. This abnormal behavior was explained by the difference in order of ordering which makes spatial variation of energy gap in InGaAsP layer and this explanation was supported by the analyses of transmission electron microscopy and transmission spectroscopy.

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Growth of $In_{0.53}Ga_{0.47}As$ Iattice matched to Inp substrate by low pressure metalorganic chemical vapor deposition (저압 유기금속 화학증착법을 이용한 InP 기판에 격자 일치된 $In_{0.53}Ga_{0.47}As$ 에피층의 성장)

  • 박형수;문영부;윤의준;조학동;강태원
    • Journal of the Korean Vacuum Society
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    • v.5 no.3
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    • pp.206-212
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    • 1996
  • $In_{1-x}Ga_xAs$ epitaxial layers were grown at 76 Torr by low pressure metalorganic chemical vapor deposition (LP-MOCVD). Growth rate did not change much with growth temperature. Surface morphology of $In_{1-x}Ga_xAs$ epitaxial layer was affected by lattice mismatch, growth temperature and $AsH_3/(TMIn+TMGa)$ ratio. A high quality epilayer showed a full width at half maximum of 2.8 meV by photoluminescence measurement at 5K. The composition of the $In_{1-x}Ga_xAs$ was determined by the relative gas phase diffusion of TMIn and TMGa. Lattice mismatch and growth temperature were the most important variables that determine the electrical properties of $In_{1-x}Ga_xAs$ epitaxial layers. At optimized growth condition, it was possible to obtain a high quality $In_{1-x}Ga_xAs$ epilayers with a electron concentration as low as $8{\times}10^{14}/cm^3$ and an electron mobility as high as 11,000$\textrm{cm}^2$/Vsec at room temperature.

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A Study on the VOCs Emission Characteristics by the Light Duty Diesel and LPG Fueled Vehicles (소형승합차량 및 RV차량의 휘발성 유기 화합물 배출특성 변화에 관한 연구)

  • Eom, Myung-Do;Ryu, Jung-Ho;Han, Jong-Su;Lyu, Young-Sook;Kim, Dae-Wook;Kim, Jong-Choon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.1
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    • pp.8-13
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    • 2008
  • Emissions from automobiles have long been considered a prime source of pollutants involved in smog formation and ozone production. Especially VOCs are associated with serious environmental problems such as photo-chemical smog as well as human health effects. Since motor vehicles are a major source of VOCs, estimating of emission from mobile source is the most important factor to control VOCs. VOCs are emitted from various pollution like motor vehicles, mobile and stationary source that has characteristics of toxicity, cancer-causing, bio-accumulation, durability in air and diffusion can exert a bad influence upon human health and environment. However we don't have any standard or regulation about VOCs emissions. This study is summarized as VOCs emission characteristics from in-use light-duty diesel and LPG fueled vehicles. The vehicle exhaust-gas test mode is CVS cycle and nier-10 cycles that developed on EPA and National Institute of Environmental Research. TO-14 method (Toxic Organic) was chosen for VOCs analysis from EPA in USA. This study results will be useful when make a emission factor and rule making of emission standard about domestic VOCs emission for the improve to air condition.

Development of Metal Loaded Activated Carbon Fiber for Eliminating Targeted VOCs Originated from Solvent (특정용제 Target 형 활성금속첨착 활성탄소섬유의 개발)

  • Choi, Kang-Yong;Kim, Kwang-Su;Kim, Tae-Won;Jun, Min-Kee;Park, Hea-Kyung
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.31-37
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    • 2013
  • To acquire enhanced adsorption capacity for especially targeted VOCs, activated carbon fiber of which surface area was $1,100m^2/g$ was selected and active metals were loaded. After screening study, Cr and Cu were selected as a base metal for improving adsorption capacity of activated carbon fiber. For acquiring better performance, metal loading, loading temperature, loading hours and kinds of loaded metals were changed as preparing variables. Properties measurement and adsorption capacity evaluation were performed. We found that the best conditions for metal loading were 5 hours loading at $100^{\circ}C$ and the adsorption capacity was enhanced almost double. Also we confirmed that more than 0.5 seconds contact time is needed for best adsorbate diffusion and adsorption over activated carbon fiber.

Analysis on a Dynamic Model with One Dimension in Water Transportation of PEM Fuel Cell (PEM연료전지의 수분전달에 있어서 1차원 해석을 수행한 동적모델에 관한 연구)

  • Bakhtiar, Agung;Hong, Boo-Pyo;You, Jin-Kwang;Kim, Young-Bok;Yoon, Jung-In;Choi, Kwang-Hwan
    • Journal of the Korean Solar Energy Society
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    • v.32 no.5
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    • pp.118-123
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    • 2012
  • Water balance has a significant impact on the overall fuel cell performance. Maintenance of proper water management should provide an adequate membrane hydration and avoidance of water flooding in the catalyst layer and gas diffusion layer. Considering the important of advanced water management in PEM fuel cell, this study proposes a simple one dimensional water transportation model of PEM fuel cell for use in a dynamic condition. The model has been created by assumption that the output is the water liquid saturation difference. The liquid saturation change is the total difference between the additional water and the removal water on the system. The water addition is obtained from fuel cell reaction and the electro osmotic drag. The water removal is obtained from capillary transport and evaporation process. The result shows that the capillary water transport of low temperature fuel cell is high because the evaporation rate is low.

Electrochemical Characterization of Anodic Tin Oxides with Nano-Porous Structure (나노 구조를 가지는 다공성 주석 산화물의 전기화학적 특성)

  • Lee, Jae-Wook;Park, Su-Jin;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.21 no.1
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    • pp.21-27
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    • 2011
  • A nano-porous structure of tin oxide was prepared using an anodic oxidation process and the sample's electrochemical properties were evaluated for application as an anode in a rechargeable lithium battery. Microscopic images of the as-anodized sample indicated that it has a nano-porous structure with an average pore size of several tens of nanometers and a pore wall size of about 10 nanometers; the structural/compositional analyses proved that it is amorphous stannous oxide (SnO). The powder form of the as-anodized specimen was satisfactorily lithiated and delithiated as the anode in a lithium battery. Furthermore, it showed high initial reversible capacity and superior rate performance when compared to previous fabrication attempts. Its excellent electrode performance is probably due to the effective alleviation of strain arising from a cycling-induced large volume change and the short diffusion length of lithium through the nano-structured sample. To further enhance the rate performance, the attempt was made to create porous tin oxide film on copper substrate by anodizing the electrodeposited tin. Nevertheless, the full anodization of tin film on a copper substrate led to the mechanical disintegration of the anodic tin oxide, due most likely to the vigorous gas evolution and the surface oxidation of copper substrate. The adhesion of anodic tin oxide to the substrate, together with the initial reversibility and cycling stability, needs to be further improved for its application to high-power electrode materials in lithium batteries.

A Study on Atmospheric Dispersion Pattern of Ship Emissions - Focusing on Port of Busan (선박 배기가스의 대기확산 패턴에 관한 연구 - 부산항을 중심으로)

  • Lee, Min-Woo;Lee, Hyang-Sook
    • Journal of Korea Port Economic Association
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    • v.34 no.1
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    • pp.35-49
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    • 2018
  • Busan Port handles more than 75% of the domestic freight volume and is ranked at 6th for global shipping in the world. This paper aims to estimate ship emission in North Port that is the center of Busan Port and located near the residential area. The emission for each type of ship is calculated applying a emission model proposed by U.S. EPA and the atmospheric diffusion pattern of the exhaust gas according to the season, the weather condition and the time was identified using CALPUFF Model. As a result, the major pollutants of $NO_x$, $SO_x$ and PM10 were 30,853 tons, 36,281 tons and 6,856 tons, respectively, and the highest rate was 42% in oil tankers. On clear days, air pollution was stagnant around the harbor, spread widely on windy days, and tended to be thinner on rainy days. The research contributes to recognizing the seriousness of air pollution and can be used as basic data for policy making in the future.

Antimicrobial efficacy of endophytic Penicillium purpurogenum ED76 against clinical pathogens and its possible mode of action

  • Yenn, Tong Woei;Ibrahim, Darah;Chang, Lee Kok;Ab Rashid, Syarifah;Ring, Leong Chean;Nee, Tan Wen;Noor, Muhamad Izham bin Muhamad
    • Korean Journal of Microbiology
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    • v.53 no.3
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    • pp.193-199
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    • 2017
  • This study was aimed to evaluate the antimicrobial activity of Penicillium purpurogenum ED76 on several clinically important microorganisms. The endophytic fungus P. purpurogenum ED76 was previously isolated from Swietenia macrophylla leaf. The antimicrobial efficacy of P. purpurogenum ED76 dichloromethane extract was determined via disc diffusion and broth microdilution assay. A kill curve study was conducted and the morphology of extract treated bacterial cells were viewed under scanning electron microscope. The dichloromethane extract showed significant inhibitory activity on 4 test bacteria and 2 test yeasts. The minimal inhibitory concentration of the extract ranged from 125 to $1,000{\mu}g/ml$, which indicates the different susceptibility levels of the test microorganisms to the fungal extract. The kill curve study has revealed a concentration-dependent inhibition for all test microorganisms. With the increase of the extract concentration, the microbial growth was significantly reduced. The scanning electron micrograph of dichloromethane extract-treated Staphylococcus aureus cells showed the total damage of the cells. The cell wall invagination of the bacterial cells also indicates the loss of cellular materials and metabolic activity. The gas chromatography mass spectrometry analysis of the extract also showed that the major compound was stigmasterol, which constitutes 45.30% of the total area. The dichloromethane extract of P. purpurogenum ED76 exhibited significant inhibitory activity on several clinically important bacteria and yeasts. The study proposed a possible mode of action that the extract cause significant damage to the morphology of S. aureus cells.