• Title/Summary/Keyword: gas diffusion

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Humidity Dependence Removal Technology in Oxide Semiconductor Gas Sensors (산화물 반도체 가스 센서의 습도 의존성 제거 기술)

  • Jiho Park;Ji-Wook Yoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.347-357
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    • 2024
  • Oxide semiconductor gas sensors are widely used for detecting toxic, explosive, and flammable gases due to their simple structure, cost-effectiveness, and potential integration into compact devices. However, their reliable gas detection is hindered by a longstanding issue known as humidity dependence, wherein the sensor resistance and gas response change significantly in the presence of moisture. This problem has persisted since the inception of oxide semiconductor gas sensors in the 1960s. This paper explores the root causes of humidity dependence in oxide semiconductor gas sensors and presents strategies to address this challenge. Mitigation strategies include functionalizing the gas-sensing material with noble metal/transition metal oxides and rare-earth/rare-earth oxides, as well as implementing a moisture barrier layer to prevent moisture diffusion into the gas-sensing film. Developing oxide semiconductor gas sensors immune to humidity dependence is expected to yield substantial socioeconomic benefits by enabling medical diagnosis, food quality assessment, environmental monitoring, and sensor network establishment.

Effect of Hydrogen(H2) Addition on Flame Shape and Combustion Products in Mixed Coflow Diffusion Flames of Methane(CH4), Ethane(C2H6) and Propane(C3H8) (동축류 메탄(CH4), 에탄(C2H6), 프로판(C3H8) 혼합 확산화염내의 수소(H2) 첨가가 화염 형상 및 연소 생성물에 미치는 영향)

  • Park, Ho-Yong;Yoon, Sung-Hwan;Rho, Beom-Seok;Lee, Won-Ju;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.6
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    • pp.780-787
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    • 2019
  • As a carbon-free, green growth alternative, internal and external interest in hydrogen energy and technology is growing. Hydrogen was added to co-axial methane, methane-propane, and methane-propane-ethane diffusion flames, which are the main ingredients of LNG, to evaluate its effect on flame formation and combustion products. The variation in combustion products produced by adding hydrogen gradually to diffusion pyrolysis at room temperature and normal pressure conditions was observed experimentally by using a gas analyzer, and the shape of diffusion pyrolysis was observed step by step using a digital camera. The experimental results showed that the production volume of nitrogen oxides tended to increase and became close to linear as hydrogen was added to the diffusion pyrotechnic. This is because the relatively high temperature of heat insulation and fast combustion speed of hydrogen facilitated the production of thermal NOx. On the other hand, CO2 production tended to decrease as hydrogen was added to reduce the overall carbon ratio contained in the mixed diffusion flame of methane, methane-propane, and methane-ethane-propane. This means that the mixed fuel use of LNG-hydrogen in ships may potentially reduce emissions of CO2, a greenhouse gas.

The added carbon effect on residual stress in ion-nitriding (ION질화에 있어 첨가 탄소량이 잔류응력에 미치는 영향)

  • 김희송;강명순
    • Journal of the korean Society of Automotive Engineers
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    • v.4 no.2
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    • pp.35-46
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    • 1982
  • This paper deals with residual stress characteristics of ion-nitrided metal which is primarilly concerned with the effects of added carbon content in gas atmosphere. A small optimal amount of carbon content in gas atmosphere increase compound layer thickness, as well as to increase diffusion layer thickness and hardness. The residual stress and deflection of the specimens was measured in various elevated temperature at the surface of ion-nitrided metal and the internal stress distribution was calculated. It is found that compressive residual stress at the compound layer is largest at the compound layer, and decreases as the depth from the surface increases.

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Numerical modeling for pressure uniformity improvement of a large area sputtering system by change of gas distribution configuration (대면적 스퍼터링 장치에서 Gas 분배 구조 변화에 따른 압력 균일도 개선 모델링)

  • Kim, Yeong-Uk;Yang, Won-Gyun;Gu, Jeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.175-176
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    • 2007
  • 대면적 플라즈마 스퍼터링 시스템에서 가스 분배 구조의 변화가 시스템의 압력 균일도에 미치는 영향을 3차원 수치 모델을 통하여 연구하였으며 2 line parallel internal antenna의 경우에 대해서 플라즈마 균일도를 drift diffusion approximation을 이용하여 계산 하였다.

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LPG-DME Compression Ignition Engine with Intake Variable Valve Timing (LPG-DME 압축착화 엔진에서 흡기 가변밸브 영향)

  • Yeom, Ki-Tae;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.2
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    • pp.158-165
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    • 2008
  • The combustion and exhaust emissions characteristics of a liquefied petroleum gas-di-methyl ether compression ignition engine with a variable valve timing device were investigated under various liquefied petroleum gas injection timing conditions. Liquefied petroleum gas was used as the main fuel and was injected directly into the combustion chamber. Di-methyl ether was used as an ignition promoter and was injected into the intake port. Different liquefied petroleum gas injection timings were tested to verify the effects of the mixture homogeneity on the combustion and exhaust emission characteristics of the liquefied petroleum gas-di-methyl ether compression ignition engine. The average charge temperature was calculated to analyze the emission formation. The ringing intensity was used for analysis of knock characteristics. The combustion and exhaust emission characteristics differed significantly depending on the liquefied petroleum gas injection and intake valve open timings. The CO emission increased as the intake valve open and liquefied petroleum gas injection timings were retarded. However, the particulate matter emission decreased and the nitrogen oxide emission increased as the intake valve open timing was retarded in the diffusion combustion regime. Finally, the combustion efficiency decreased as the intake valve open and liquefied petroleum gas injection timings were retarded.

Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (II) (수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향)

  • Kim, Byeong-Ju;Lee, Chan-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.4
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    • pp.499-509
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    • 1998
  • In the absorption process of water vapor in a liquid film, the composition of the gas phase, in which a non-absorbable gas is combined with the absorbate influences the transport characteristics remarkably. In the present study, the absorption processes of water vapor into aqueous solution of lithium bromide in the presence of non-absorbable gases were investigated analytically. The continuity, momentum, energy and diffusion equations for the solution film and gas phase were formulated in integral forms and solved numerically. It was found that the mass transfer resistance in gas phase increased with the concentration of non-absorbable gas. However the primary resistance to mass transfer was in the liquid phase. As the concentration of non-absorbable gas in the absorbate increased, the liquid-vapor interfacial temperature and concentration of absorbate in solution decreased, which resulted in the reduction of absorption rate. The reduction of mass transfer rate was found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of an absorber where non-absorbable gases accumulated. At higher non-absorbable gas concentration, the decrease of absorption flux was almost linear to the volumetric concentration of non-absorbable gas.

A Study on the Flame Structure and NOx Distribution In Coaxial Diffusion Combustor (동축확산연소기 화염구조와 NOx 분포에 관한 연구)

  • Kim, K.S.;Lee, W.S.;Kang, I.G.;Lee, D.H.
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.35-41
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    • 1999
  • The purpose of this study is to establish the flame structure and NOx emission characteristics of the swirl flow coaxial diffusion combustion in the model gas turbine combustor. The mean temperature, ion currents and NOx emission measurement technique showed the effect of equivalence ratio into flame length and flame stability. As a result of this study, NOx emission was increased by increasing the equivalence ratio, and the peak value of the NOx was appeared near the flame front.

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The Study of Electron Transport coefficients in $SiH_4$-Ar Mixtures by Using Boltzmann Equation Analysis and Monte-Carlo Simulation (볼츠만방정식과 몬테칼로법에 의한 $SiH_4$-Ar 혼합가스의 전자수송계수에 관한 연구)

  • 하성철;전병훈
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.169-174
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    • 2001
  • The electron transport coefficients(the electron drift velocity, W, and the longitudinal and transverse diffusion coefficient, D$_{L}$ and D$_{T}$) in SiH$_4$-Ar mixtures containing 0.5% and 5.0% monosilane were calculated over the E/N range from 0.01 to 300 Td and over the gas pressure range 0.5, 1.0 and 1.5 Torr by the time-of-flight(TOF) method of the Boltzmann equation(BE.) and Monte-Carlo simulation(MCS). The electron energy distribution function in each SiH$_4$-Ar mixtures at E/N=10 Td and L=0.2 cm, which in equilibrium region in the mean electron enregy were compared.red.

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An Experimental Study on Flame Stability and Combustion Characteristics of Coaxial Diffusion Flame (동축분류 확산화염에서 화염안정화와 연소특성에 관한 연구)

  • 유현석;오신규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.509-518
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    • 1995
  • A study for the flame stability and the combustion characteristics of coaxial diffusion flame was conducted. The fuel employed was natural gas. The experimental variables were rim thickness of fuel tube, blockage ratio of the outer diameter of fuel tube to the inner diameter of air tube, and momentum ratio of fuel to air. It was consequently found that the stability in the neighborhood of the fuel rim depended on the rim thickness, especially in the case of above 3 mm, and that the stable region of the flame extended remarkably due to the formation of recirculation zone above rim. The effect of the blockage ratio on the flame stability was found to be minor in the case of above 3 mm of rim thickness. Between the momentum ratio 2 and 3, the stable flame zone was widely established as well good combustion. With increasing the fuel-air momentum ratio, axial velocity, turbulence intensity, and Reynolds stress increased.