• Title/Summary/Keyword: fuel properties

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The Effect of Proton Conductivity of SPEEK Composite Membrane with Organic Compounds for DMFC

  • You, S.K.;Kim, H.J.;Shin, H.S.;Kim, J.S.;Choi, W.K.;Park, S.G.
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.167-172
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    • 2009
  • Direct methanol fuel cells(DMFCs) are receiving significant attention in the portable power source and electric vehicular transportation because of its high energy efficiency as liquid fuel, low cost, and no requirement of fuel reforming process. In this study, we synthesized the Sulfonated poly(ether ether ketone) (SPEEK) to evaluate the possibility of use as a proton exchange membrane for DMFC. And poly(vinylidienedifluoride) (PVDF) was used to increase proton conductivity in SPEEK and simultaneously to prevent methanol transport through the cross linked membrane. Furthermore, in order to improve the electrical composite properties for DMFC applications.

A Study on the Mechanical Properties of Nuclear Fuel Cladding Materials (원자로용 핵연료 피복재의 인장특성에 관한 연구)

  • Bae, Bong-Kook;Song, Chun-Ho;Seok, Chang-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.2
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    • pp.231-238
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    • 2003
  • The fuel of light water reactor is used for several years under high temperature and pressure, so it needs to be clad with high corrosion resistance material. The cladding materials must have the characteristics of low absorption of a neutron and high corrosion resistance. Zircaloy-2 in Boiling Water Reactor, Zircaloy-4 in Pressurized Water Reactor have been used as cladding materials and Zirlo has been developed as the material for preventing the corrosion. If the fracture of the cladding tube occurs during operation, it will cause the economic loss to shut down and replace the system. So it is needed to evaluate the integrity of the cladding materials. In this paper, the tensile characteristics of the cladding materials were investigated for the basic research of fracture characteristics. Also the residual stress was analyzed to compare the tube type(original type) specimen and the flattened type specimen.

Seismic Analysis of Spent Fuel Storage Structures for PHWR Plant (중수로형 핵연료 저장대의 내진해석 방법)

  • 신태명
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2003.11a
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    • pp.338-344
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    • 2003
  • The seismic analysis method of spent fuel storage structures for PHWR plant is introduced in comparison with the method for PWR plant. Investigating the structural characteristics of the storage structures, the former is vertically stacked fuel storage trays, while the latter is welded honeycomb type structure. However, as both structures are submerged and free standing, the analysis methods to anticipate the seismic response of both structures are complicated. For the better estimation of actual seismic response, how to model the dynamic properties and the structural behaviour is the key issue. In this paper, the overall procedures of the seismic modelling and stability check for seismic sliding and overturning of the two different storage structures are discussed in the viewpoint of analysis reliability

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Synthesis and Properties of New Type of Proton Conducting Polymer Membrane for High Temperature Fuel Cells (고온 연료전지용 새로운 형태의 고분자 전해질막의 합성과 특성연구)

  • Lee, Joong-Hee;Sambhu, Bhadra;Kim, Nam-Hoon;Lee, Hong-Ki;Kim, Hong-Gun
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.166-169
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    • 2009
  • Poly(benzimidazole-co-aniline) (PBIANI), a self-crosslinked, net-structured, proton conducting polymer has been synthesized for the membrane of high temperature proton exchange membrane fuel cells (HT-PEMFC) with improved proton conductivity and mechanical strength. The stress at break (26$\pm$3MPa)and proton conductivity (167 mS cm-1)of the phosphoric acid doped PBIANI (DPBIANI)membrane is much higher than those of other doped polybenzimidazole(PBI) type membranes.

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A Study on Mechanical Properties of Fuel Cladding Materials (원자로용 핵연료 피복재의 인장특성에 관한 연구)

  • Bae, Bong-Kook;Song, Chun-Ho;Seok, Chang-Sung
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.489-494
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    • 2001
  • The fuel of light water reactor used far several years at high temperature and pressure, so it needs to clad with high corrosion resistance material. The cladding materials need low absorption of a neutron and high corrosion resistance. Cladding materials used Zircaloy-2 in Boiling Water Reactor, Zircaloy-4 in Pressurized Water Reactor and Zirlo has good for long term corrosion. If fracture of cladding tube occured during operation, it caused disaster. So it is needed to estimate of integrity fur cladding materials. In this paper, tension characteristics of cladding materials are investigate which is basic research far fracture characteristic. Also analysis of residual stress effect between tube type(original type) specimen and flattened type specimen.

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A Study on the Performance of the MPI Gasoline Engine with Gasoline-Ethanol Blends (가솔린-에탄을 혼합연료 사용시의 MPI 가솔린 기관의 성능에 관한 연구)

  • 윤건식;신승한
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.92-102
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    • 2001
  • The effect of ethanol-blending on the performances of the MPI gasoline engine was examined. The experiments were carried out for the stoichiometric conditions under MBT spark timing over various operating conditions. The blending rate of ethanol were determined as 10 to 30 percent according to the analysis of the properties of blended fuels. The engine with ethanol-blended fuels showed improved performances such as brake torque, brake power, brake thermal efficiency and exhaust emissions compared with those of pure gasoline over most operating conditions. Though the brake specific fuel consumption was increased by ethanol-blending due to their lower heating values, the increasing rates of the brake specific fuel consumption were limited to the half of the blending rates owing to the increase in the thermal efficiency.

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Effects of Ru Co-Sputtering on the Properties of Porous Ni Thin Films

  • Kim, Woo-Sik;Choi, Sun-Hee;Lee, Hae-Weon;Kim, Joo-Sun
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.746-750
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    • 2006
  • NiO films and Ru co-sputtered NiO films were deposited by reactive magnetron sputtering for micro-solid oxide fuel cell anode applications. The deposited films were reduced to form porous films. The reduction kinetics of the Ru doped NiO film was more sluggish than that of the NiO film, and the resulting microstructure of the former exhibited finer pore networks. The possibility of using the films for the anodes of single chamber micro-SOFCs was investigated using an air/fuel mixed environment. It was found that the abrupt increase in the resistance is suppressed in the Ru co-sputtered film, as compared to undoped film.

Microwave-treated Expandable Graphite Granule for Enhancing the Bioelectricity Generation of Microbial Fuel Cells

  • Kim, Minsoo;Song, Young Eun;Li, Shuwei;Kim, Jung Rae
    • Journal of Electrochemical Science and Technology
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    • v.12 no.3
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    • pp.297-301
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    • 2021
  • Microbial fuel cells (MFCs) convert chemical energy to electrical energy via electrochemically active microorganisms. The interactions between microbes and the surface of a carbon electrode play a vital role in capturing the respiratory electrons from bacteria. Therefore, improvements in the electrochemical and physicochemical properties of carbon materials are essential for increasing performance. In this study, a microwave and sulfuric acid treatment was used to modify the surface structure of graphite granules. The prepared expandable graphite granules (EGG) exhibited a 1.5 times higher power density than the unmodified graphite granules (1400 vs. 900 mW/m3). Scanning electron microscopy and Fourier transform infrared spectroscopy revealed improved physical and chemical characteristics of the EGG surface. These results suggest that physical and chemical surface modification using sulfuric acid and microwave heating improves the performance of electrode-based bioprocesses, such as MFCs.

Properties and coating technology of metallic bipolar plate for polymer electrolyte fuel cells (고분자전해질 연료전지용 금속분리판의 특성 및 코팅 기술)

  • Moon, Sungmo;Lee, Suyeon;Kwon, Duyoung
    • Journal of Surface Science and Engineering
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    • v.55 no.3
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    • pp.133-142
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    • 2022
  • This paper reviews bipolar plate materials and coatings for polymer electrolyte fuel cell. First, six roles and 10 requirements of the bipolar plate are described in detail. Secondly, type of materials for the bipolar plate and their advantages and disadvantages are mentioned. Thirdly, different metallic materials are introduced in terms of electrical and thermal conductivities, corrosion resistance, weight, strength and cost. Finally, various types of coating materials and methods were briefly reviewed.

Two new relationships for slip velocity and characteristic velocity in a non-center rotating column

  • Torkaman, Rezvan;Heydari, Mehran;Cheshmeh, Javad Najafi;Heydari, Ali;Asadollahzadeh, Mehdi
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2809-2818
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    • 2022
  • In this investigation work, liquid-liquid extraction (L.L.E) through three distinctive frameworks have been examined for assurance of slip velocity (S.V), and characteristic velocity (C.V) in a non-center rotating column (N.C.R.C) with a wide extend of factors. Three double frameworks with distinctive interfacial tension comprising of toluene-water (high interfacial tension), n-butyl acetate-water (medium interfacial tension), and n-butanol-water (low interfacial tension) were investigated for tests. Two common relationships for the expectation of S.V and C.V, including phase stream rates, rotor speed, column geometry additionally physical properties, are displayed. The recommended relationships were compared with test information gotten from the writing and the display examination. Findings of this study, the present proposed correlations are more accurate than those previously reported.