• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.88.2-88.2
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• 2011

Proton exchange memb rane fuel cell has been considered one of the next generation power source for electric vehicles due to high power density and low emissions. $TiO_2$/Nafion composite was prepared by the in-situ sol-gel method. The electrochemical characteristics of the $TiO_2$-Nafion composite membrane were evaluated by current-voltage and impedance of the membrane eletrode assembly in a single Proton exchange membrane fuel cell (PEMFC).

• 한국표면공학회지
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• 제50권1호
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• pp.1-9
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• 2017

Design of novel materials in renewable energy systems plays a key role in powering transportation vehicles and portable electronics. This review introduces the research work of first principles-based computational design for the materials over the last decade to accomplish the goal with less financial and temporal cost beyond the conventional approach, especially, focusing on electrocatalyst toward a proton exchange membrane fuel cell (PEMFC). It is proposed that the new method combined with experimental validation, can provide fundamental descriptors and mechanical understanding for optimal efficiency control of a whole system. Advancing these methods can even realize a computational platform of the materials genome, which can substantially reduce the time period from discovery to commercialization into markets of new materials.

• 한국태양에너지학회 논문집
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• 제31권5호
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• pp.91-98
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• 2011

연료전지 차랑용에 있어서 공기 가습 및 감습의 중요성은 매우 크다. 특히 PEM(Proton Exchange Membrane)연료전지에서 수분평형은 총괄시스템성능에 큰 영향을 미치는 요소인데, 이에 관한 중요한 연구가 지금까지 광범위하게 수행되고 있다. 또한 차량과 같이 동적부하 연료전지를 활용하는 분야에 있어서, 전류의 흐름은 차량용 파워 부하에 크게 영향을 받는다. 따라서 전기적 흐름이 발생하면, 이에 따라 수분이 발생하게 되는데, 이러한 응축 수분은 예측이 되며, 수관리 시스템에서 이를 중요한 제어 기준으로 활용한다. 그러므로 적절한 제어방법을 선택하면 유입공기의 온도와 습도의 최적값을 얻을 수 있다. 따라서, 본 논문에서는 PEM 연료전지의 수관리를 위하여 수분전달 모델과 유전알고리즘(genetic algorithm)을 사용하는 제어방법에 초점을 두고 있다.

• 한국인터넷방송통신학회논문지
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• 제20권4호
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• pp.195-200
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• 2020

화석연료 고갈과 환경오염에 관한 관심이 고조되면서 국내에서 운행되고 있는 철도차량이 디젤 차량에서 전기 차량으로 전환이 확대되면서 진행되고 있다. 전기 차량의 전환의 한 예로 적용되고 있는 태양광발전 시스템은 무한정하고 무공해 하며 대기오염, 소음, 발열, 진동 등과 같은 위해요소들을 발생시키지 않고 에너지 생산이 가능하며, 연료 수송, 발전설비에 대한 유지보수가 거의 필요하지 않은 장점이 있다. 그러나 전력생산량이 지역별 일사량에 의존하고, 약 25㎡/kWp 발전량으로 에너지밀도가 낮아 큰 설치 면적이 필요하며, 설치장소가 제한적인 문제점을 가지고 있다. 이러한 문제점을 고려하여 철도 분야에서도 연료전지를 적용한 연구들이 많이 증가하고 있다. 특히 연료전지 발전시스템 철도 급전계통 연계방안은 태양광 및 풍력과는 다르게 철도차량에 전력을 공급해주는 급전계통에 연계해야 한다. 따라서 철도차량과 밀접한 관계를 가지는 시스템 토폴로지 (topology)에 따라 연계방식은 크게 달라질 수 있으므로 본 논문에서는 시스템 토폴로지에 따른 연계분석과 관련된 시뮬레이션 모델링을 통한 타당성을 연구하고자 한다.

• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.274-282
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• 2004

This study focused on the development of high performance catalyst for autothermal reforming (ATR) of gasoline to produce hydrogen. The ATR was carried out over MgO/Al2O3 supported metal catalysts prepared under various experimental conditions. The catalysts before and after reaction were characterized by N2-physisorption, CO-chemisorption, SEM and XRD. The performance of supported multi-metal catalysts were better than that of supported mono-metal catalysts. Especially, it was observed that the conversion of iso-octane over prepared Ni/Fe/MgO/Al2O3 catalyst was 99.9 % comparable with commercial catalyst (ICI) and the selectivity of hydrogen over the prepared catalyst was 65% higher than ICI catalyst. Furthermore, it was identified that the sulfur tolerance of prepared catalyst was much better than ICI catalyst based on the ATR reaction of iso-octane containing sulfur of 100 ppm. Therefore, Ni/Fe/MgO/Al2O3 catalyst can be applied for a fuel reformer, hydrogen station and on-board reformer in furl cell powered vehicles.

• 대한기계학회논문집B
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• 제32권6호
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• pp.446-454
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• 2008

The purpose of this paper is to analyze two-phase flows of the hydrogen recirculation system. Two-phase flow modeling is one of the great challenges in the classical sciences. As with most problems in engineering, the interest in two-phase flow is due to its extreme importance in various industrial applications. In hydrogen recirculation systems of fuel cell, the changes in pressure and temperature affect the phase change of mixture. Therefore, two-phase flow analysis of the hydrogen recirculation system is very important. Two-phase computation fluid dynamics (CFD) calculations, using a commercial CFD package FLUENT 6.2, were employed to calculate the gas-liquid flow. A two-phase flow calculation was conducted to solve continuity, momentum, energy equation for each phase. Then, the mass transfer between water vapor and liquid water was calculated. Through an experiment to measure production of liquid water with change of pressure, the analysis model was verified. The predictions of rate of condensed liquid water with change of pressure were within an average error of about 5%. A comparison of experimental and computed data was found to be in good agreement. The variations of performance, properties, mass fraction and two-phase flow characteristic of mixture with resepct to the fuel cell power were investigated.

• 한국자동차공학회논문집
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• 제25권2호
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• pp.157-166
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• 2017

The Fuel Cell Electric Vehicle(FCEV) is recently evolving into a new trend in the automobile industry due to its relatively higher efficiency and zero greenhouse gas(GHG) emission in the tailpipe, as compared to that of the conventional internal combustion engine vehicles. However, it is important to analyze the whole process of the hydrogen's life cycle(from extraction of feedstock to vehicle operation) in order to evaluate the environmental impact of introducing FCEV upon recognizing that the hydrogen fuel, which is used in the fuel cell stack, is not directly available from nature, but instead, it should be produced from naturally available resources. Among the various hydrogen production methods, ${\sim}54.1%^{8)}$ of marketed hydrogen in Korea is produced from naphtha cracking process in the petrochemical industry. Therefore, in this study, we performed a well-to-wheels(WTW) analysis on the hydrogen fuel cycle for the FCEV application by using the GREET program from the US Argonne National Laboratory with Korean specific data. As a result, the well-to-tank and well-to-wheel GHG emissions of the FCEV are calculated as 45,638-51,472 g $CO_2eq/GJ$ and 65.0-73.4 g $CO_2eq/km$, respectively

• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.493-499
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• 2010

Steam reforming (SR) of glycerol, a main by-product of manufacturing process of bio-diesel, for the production of hydrogen was investigated over the Ni-based catalysts. The Ni-based catalysts were prepared by an impregnation method, and characterized by $N_2$ physisorption, CO chemisorption, XRD and TEM techniques. It was found that the Ni/${\gamma}-Al_2O_3$ catalyst showed higher conversion and catalytic stability for the carbon formation than the other catalysts in the steam reforming of glycerol under the tested conditions. The results suggest that the steam reforming of glycerol over modified Ni/${\gamma}-Al_2O_3$ catalyst minimized carbon formation can be applied in hydrogen station for fuel-cell powered vehicles and fuel processor for stationary and portable fuel cells.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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• pp.217-221
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• 2012

Over the last decade, performances of low temperature fuel cells are substantially improved by developing highly active Pt-M alloy catalysts. The electrochemical stability of those catalysts, however, still does not meet the commercial grade for fuel cells to be long-term power sources of electrical vehicles. To unveil a major mechanism causing such weak durability, we extensively utilize ab-initio computations on nano-scale Pt-Co alloy catalysts and analyze thermodynamically the most stable structure as a function of compositional variation. Our results indicate that there is a certain feature governing the particle distribution of a specific alloy element on the nano-scale catalysts, which aggravates the electrochemical degradation.

• 한국수소및신에너지학회논문집
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• 제28권5호
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• pp.492-501
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• 2017

A 900 W scale direct methanol fuel cell (DMFC) stack is designed and fabricated for unmanned aerial vehicle (UAV) applications. To meet the volume and weight requirements, metallic bipolar plates are applied to the DMFC stack for the first time wherein POS470FC was chosen as bipolar plate material. To ensure good robustness of the metallic bipolar plate based DMFC stack, finite element method based simulations are conducted using a commercial ANSYS Fluent software. The stress buildup and deformation characteristics on bipolar plates and end plates are analyzed in details. The present DMFC stack exhibits the performance of 1,130 W at 32 V and 35.3 A, clearly demonstrating that it could successfully operate for UAVs requiring around 1,000 W of power.