• Title/Summary/Keyword: frequency synthesis

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Experimental and ab initio Computational Studies on Dimethyl-(4-{4-{3-methyl-3-phenyl-cyclobutyl)-thiazol-2-yl]-hydrazonomethyl}-phenyl)-amine

  • Yuksektepe, Cigdem;Saracoglu, Hanife;Caliskan, Nezihe;Yilmaz, Ibrahim;Cukurovali, Alaaddin
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3553-3560
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    • 2010
  • A new hydrazone derivative compound has been synthesized and characterized by IR, $^1H$-NMR, $^{13}C$-NMR and UV-vis. spectroscopy techniques, elemental analysis and single-crystal X-ray diffraction (XRD). The new compound crystallizes in monoclinic space group C2/c. In addition to the crystal structure from X-ray experiment, the molecular geometry, vibrational frequencies and frontier molecular orbitals analysis of the title compound in the ground state have been calculated by using the HF/6-31G(d, p), B3LYP/6-311G(d, p) and B3LYP/6-31G(d, p) methods. The computed vibrational frequencies are used to determine the types of molecular motions associated with each of the observed experimental bands. To determine conformational flexibility, molecular energy profile of (1) was obtained by semi-empirical (AM1) calculation with respect to a selected degree of torsional freedom, which was varied from $-180^{\circ}$ to $+180^{\circ}$ in steps of $10^{\circ}$. Molecular electrostatic potential of the compound was also performed by the theoretical method.

A Novel UV-Sensitivity Mutation Induces Nucleotide Excision Repair Phenotype and Shows Epistatic Relationships with UvsF and UvsB Groups in Aspergillus nidulans

  • Baptista, F.;Castro-Prado, M.A.A.
    • Journal of Microbiology
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    • v.39 no.2
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    • pp.102-108
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    • 2001
  • DNA damage response has a central role in the maintenance of genomic integrity while mutations in related genes may result in a range of disorders including neoplasic formations. The uvsZl characterized in this report is a navel uvs mutation in Aspergillus nidulans, resulting in a nucleotide excision repair (NER) phenotype: UV-sensitivity before DNA synthesis (quiescent cells), high UV-induced mutation frequency and probable absence of involvement with mitotic and meiotic recombinations. The mutation is recessive and nan-allelic to the previously characterized uvsA101 mutation, also located on the paba-y interval on chromosome I. uvsZl skewed wild-type sensitivity to MMS, which suggests non-involvement of this mutation with BER. Epitasis tests showed that the uvsZ gene product is probably involved in the same repair pathways as UVSB or UVSH proteins. Although mutations in these proteins result in an NER phenotype, UVSB is related with cell cycle control and UVSH is associated with the post-replicational repair pathway. The epistatic interaction among uvsZl and uvsB413 and uvsH77 mutations indicates that different repair systems may be related with the common steps of DNA damage response in Aspergillus nidulans.

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Synthesis of Diamond Thin Film on WC-Co by RF PACVD (RF PACVD에 의한 초경합금상에 다이아몬드 박막의 합성)

  • Kim, Dae-Il;Lee, Sang-Hee;Park, Gu-Bum;Park, Sang-Hyun;Lee, Yong-Geun;Kim, Bo-Youl;Kim, Young-Bong;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.11
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    • pp.596-602
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    • 2000
  • Diamond thin films were synthesized on WC-Co substrate at various experimental parameters using 13.56MHz RF PACVD)radio frequency plasma-assisted chemical vapor deposition). In order to increased the nucleation density, the WC-Co substrate was polished with 3${\mu}m$ diamond paste. And the WC-Co substrate was preatreated in $HNO_3\;:\;H_2O$ = 1:1 and $O_2$ plasma. In $H_2-CH_4$ gas mixture, the crystallinity of thin film increased with decreasing $CH_4$ concentration at 800W discharge power and 20torr reaction pressure. In $H_2-CH_4-O_2$ gas mixture, the crystallinity of thin film increased with increasing $O_2$ concentration at 800W discharge power, 200torr reaction pressure and 4% $CH_4$ concentration.

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Understanding of unsteady pressure fields on prisms based on covariance and spectral proper orthogonal decompositions

  • Hoa, Le Thai;Tamura, Yukio;Matsumoto, Masaru;Shirato, Hiromichi
    • Wind and Structures
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    • v.16 no.5
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    • pp.517-540
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    • 2013
  • This paper presents applications of proper orthogonal decomposition in both the time and frequency domains based on both cross spectral matrix and covariance matrix branches to analyze multi-variate unsteady pressure fields on prisms and to study spanwise and chordwise pressure distribution. Furthermore, modification of proper orthogonal decomposition is applied to a rectangular spanwise coherence matrix in order to investigate the spanwise correlation and coherence of the unsteady pressure fields. The unsteady pressure fields have been directly measured in wind tunnel tests on some typical prisms with slenderness ratios B/D=1, B/D=1 with a splitter plate in the wake, and B/D=5. Significance and contribution of the first covariance mode associated with the first principal coordinates as well as those of the first spectral eigenvalue and associated spectral mode are clarified by synthesis of the unsteady pressure fields and identification of intrinsic events inside the unsteady pressure fields. Spanwise coherence of the unsteady pressure fields has been mapped the first time ever for better understanding of their intrinsic characteristics.

An Optimized Design of RS(23,17) Decoder for UWB (UWB 시스템을 위한 RS(23,17) 복호기 최적 설계)

  • Kang, Sung-Jin;Kim, Han-Jong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.33 no.8A
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    • pp.821-828
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    • 2008
  • In this paper, we present an optimized design of RS(23,17) decoder for UWB, which uses the pipeline structured-modified Euclidean(PS-ME) algorithm. Firstly, the modified processing element(PE) block is presented in order to get rid of degree comparison circuits, registers and MUX at the final PE stage. Also, a degree computationless decoding algorithm is proposed, so that the hardware complexity of the decoder can be reduced and high-speed decoder can be implemented. Additionally, we optimize Chien search algorithm, Forney algorithm, and FIFO size for UWB specification. Using Verilog HDL, the proposed decoder is implemented and synthesized with Samsung 65nm library. From synthesis results, it can operate at clock frequency of 250MHz, and gate count is 17,628.

A Study on Pitch Period Detection Algorithm Based on Rotation Transform of AMDF and Threshold

  • Seo, Hyun-Soo;Kim, Nam-Ho
    • Journal of the Institute of Convergence Signal Processing
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    • v.7 no.4
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    • pp.178-183
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    • 2006
  • As a lot of researches on the speech signal processing are performed due to the recent rapid development of the information-communication technology. the pitch period is used as an important element to various speech signal application fields such as the speech recognition. speaker identification. speech analysis. or speech synthesis. A variety of algorithms for the time and the frequency domains related with such pitch period detection have been suggested. One of the pitch detection algorithms for the time domain. AMDF (average magnitude difference function) uses distance between two valley points as the calculated pitch period. However, it has a problem that the algorithm becomes complex in selecting the valley points for the pitch period detection. Therefore, in this paper we proposed the modified AMDF(M-AMDF) algorithm which recognizes the entire minimum valley points as the pitch period of the speech signal by using the rotation transform of AMDF. In addition, a threshold is set to the beginning portion of speech so that it can be used as the selection criteria for the pitch period. Moreover the proposed algorithm is compared with the conventional ones by means of the simulation, and presents better properties than others.

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Vibration Analysis of Gearbox for Agricultural UTV using a Reduced-Order Model (축소 모델 기법을 이용한 농업용 전동식 동력운반차 감속기의 진동 분석)

  • Kim, Beom-Soo;Cho, Seung-Je;Shin, In-Kyung;Chung, Woo-Jin;Han, Hyun-Woo;Kim, Ji-Tae;Park, Young-Jun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.8
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    • pp.8-17
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    • 2019
  • In this study, a model reduction technique was used to develop a precise noise and vibration prediction model for the individual components of a driveline system. The dynamic reduced-order model generated by the Craig-Bampton method was applied to perform dynamic analysis of an electric agricultural power cart. The natural frequency and acceleration response results were analyzed according to the different number of dominant sub-structural modes contained in the reduced-order models. Through the analysis results, it was confirmed that a sufficient number of dominant sub-structures to satisfy the operating conditions should be selected to construct an optimal reduced-order model.

Fillers in the Hong Kong Corpus of Spoken English (HKCSE)

  • Seto, Andy
    • Asia Pacific Journal of Corpus Research
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    • v.2 no.1
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    • pp.13-22
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    • 2021
  • The present study employed an analytical framework that is characterised by a synthesis of quantitative and qualitative analyses with a specially designed computer software SpeechActConc to examine speech acts in business communication. The naturally occurring data from the audio recordings and the prosodic transcriptions of the business sub-corpora of the HKCSE (prosodic) are manually annotated with a speech act taxonomy for finding out the frequency of fillers, the co-occurring patterns of fillers with other speech acts, and the linguistic realisations of fillers. The discoursal function of fillers to sustain the discourse or to hold the floor has diverse linguistic realisations, ranging from a sound (e.g. 'uhuh') and a word (e.g. 'well') to sounds (e.g. 'um er') and words, namely phrase ('sort of') and clause (e.g. 'you know'). Some are even combinations of sound(s) and word(s) (e.g. 'and um', 'yes er um', 'sort of erm'). Among the top five frequent linguistic realisations of fillers, 'er' and 'um' are the most common ones found in all the six genres with relatively higher percentages of occurrence. The remaining more frequent realisations consist of clause ('you know'), word ('yeah') and sound ('erm'). These common forms are syntactically simpler than the less frequent realisations found in the genres. The co-occurring patterns of fillers and other speech acts are diverse. The more common co-occurring speech acts with fillers include informing and answering. The findings show that fillers are not only frequently used by speakers in spontaneous conversation but also mostly represented in sounds or non-linguistic realisations.

High Throughput Multiplier Architecture for Elliptic Cryptographic Applications

  • Swetha, Gutti Naga;Sandi, Anuradha M.
    • International Journal of Computer Science & Network Security
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    • v.22 no.9
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    • pp.414-426
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    • 2022
  • Elliptic Curve Cryptography (ECC) is one of the finest cryptographic technique of recent time due to its lower key length and satisfactory performance with different hardware structures. In this paper, a High Throughput Multiplier architecture is introduced for Elliptic Cryptographic applications based on concurrent computations. With the aid of the concurrent computing approach, the High Throughput Concurrent Computation (HTCC) technology that was just presented improves the processing speed as well as the overall efficiency of the point-multiplier architecture. Here, first and second distinct group operation of point multiplier are combined together and synthesised concurrently. The synthesis of proposed HTCC technique is performed in Xilinx Virtex - 5 and Xilinx Virtex - 7 of Field-programmable gate array (FPGA) family. In terms of slices, flip flops, time delay, maximum frequency, and efficiency, the advantages of the proposed HTCC point multiplier architecture are outlined, and a comparison of these advantages with those of existing state-of-the-art point multiplier approaches is provided over GF(2163), GF(2233) and GF(2283). The efficiency using proposed HTCC technique is enhanced by 30.22% and 75.31% for Xilinx Virtex-5 and by 25.13% and 47.75% for Xilinx Virtex-7 in comparison according to the LC design as well as the LL design, in their respective fashions. The experimental results for Virtex - 5 and Virtex - 7 over GF(2233) and GF(2283)are also very satisfactory.

Impacts of Ultraviolet-B Radiation on Rice-Field Cyanobacteria

  • Sinha, Rajeshwar P.;Hader, Donat-P.
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.439-441
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    • 2002
  • Cyanobacteria are the dominant micro flora in rice-fields, contributing significantly to fertility as a natural biofertilizer. Recent studies show a continuous depletion of the stratospheric ozone layer, and the consequent increase in solar UV-B (280-315 nm) radiation reaching the Earth's surface. UV-B radiation causes reduction in growth, survival, protein content, heterocyst frequency and fixation of carbon and nitrogen in many cyanobacteria. UV -B induced bleaching of pigments, disassembly of phycobilisomal complexes, thymine dimer formation and alterations in membrane permeability have also been encounterd in a number of cyanobacteria. However, certain cyanobacteria produce photoprotective compounds such as water soluble colorless mycosporine-like amino acids (MAAs) and the lipid soluble yellow-brown colored sheath pigment, scytonemin, to counteract the damaging effects of UV-B. Cyanobacteria, such as Anabaena sp., Nostoc commune, Scytonema sp. and Lyngbya sp. were isolated from rice fields and other habitats in India and screened for the presence of photoprotective compounds. A circadian induction of the synthesis of MAAs by UV -B was noted in a number of cyanobacteria. Polychromatic action spectra for the induction of MAAs in Anabaena sp. and Nostoc commune also show the induction to be UV-B dependent peaking at 290 nm. Another photoprotective compound, scytonemin, with an absorption maximum at 386 nm (also absorbs at 300, 278, 252 and 212 nm), was detected in many cyanobacteria. In conclusion, a particular cyanobacterium having photoprotective compounds may be a potent candidate as biofertilizer for crop plants.

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