• Journal of the Korean Chemical Society
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• v.40 no.6
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• pp.415-419
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• 1996

Hydrogen bonding, dielectric effects and steric effects are all factors which determine the carbonyl stretching frequency, νC=O of ketones in solution. The νC=O frequency of ketones is affected by change in concentration of ketones in various solvents. The νC=O frequency shifts to lower frequency in nonpolar solvents and shifts to higher frequency in polar solvents with the increasing volume% of ketones. In acetonitrle, the νC=O frequency shifts to higher frequency as the volume% of ketones is increased except dimethyl ketone. The νC=O frequency shifts to lower frequency as the solvent system becomes increasingly polar or with the increasing extent of intermolecular hydrogen bonding, as in the case of increasing volume% chloroform in $CHCl_3$/$CCl_4$ solvent system.

• Journal of the Korean Institute of Intelligent Systems
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• v.11 no.7
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• pp.628-632
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• 2001

We propose time-frequency (TF) tools for analyzing linear time-varying (LTV) systems and nonstationary random processes. Obtained warping the narrowband Weyl symbol (WS) and spreading function (SF), the new TF tools are useful for analyzing LTV systems and random processes characterized by generalized frequency shifts, This new Weyl symbol (WS) is useful in wideband signal analysis. We also propose WS an tools for analyzing systems which produce dispersive frequency shifts on the signal. We obtain these generalized, frequency-shift covariant WS by warping conventional, narrowband WS. Using the new, generalized WS, we provide a formulation for the Weyl correspondence for linear systems with instantaneous of linear signal transformation as weighted superpositions of non-linear frequency shifts on the signal. Application examples in signal and detection demonstrate the advantages of our new results.

• Structural Engineering and Mechanics
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• v.41 no.6
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• pp.751-758
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• 2012

We study thickness-shear (TSh) free vibrations of an unbounded, laminated elastic plate with three layers of different materials. One of the two interfaces is slightly weakened as described by the shear-lag model that allows the displacement to be discontinuous across the interface. A frequency equation is obtained from the linear theory of elasticity. A perturbation solution of the frequency equation is obtained from which the frequency shifts of TSh modes due to the weakened interface can be calculated. It is shown that the frequency shifts of TSh modes of different orders are different, and they satisfy different conditions when different interfaces are weakened. These conditions are obtained which can potentially be used as criteria for determining specifically which interface is weakened.

• Bulletin of the Korean Chemical Society
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• v.28 no.5
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• pp.725-729
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• 2007

We present calculations for the acetonitrile - water clusters to examine the nature of interactions in the mixed clusters. We calculate conformers of various composition, either of σ -type (-OH and -CN binding linearly) or π -type (-OH and -CN interacting perpendicularly) structures for the acetonitrile - water clusters. We predict that the IR frequency of the proton-accepting C≡N stretching mode red-shifts in the σ -type clusters and blueshifts in π -type conformers, whereas the proton-donating ?OH stretching frequency red-shifts in all cases. We find that this intriguing pattern also applies to the acetonitrile - water clusters of various molar ratio.

• Journal of the Korean Chemical Society
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• v.17 no.4
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• pp.240-246
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• 1973

An analytic expression for the intensity of collision-induced light scattering obstained by introducing both short-range and long-range effects on the induced anisotropy. By taking argon as a specific example, it is shown that a narrow band at small frequency shifts is caused by long-range effects, while a broad band in the far wing of the spectrum is due to short-range effects. The overall intensity is a synthesis of these two bands and does not follow a simple exponential form. As temperature increases, the intensity at large frequency shifts increases makedly, while at small frequency shifts it changes little.

• YAKHAK HOEJI
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• v.33 no.3
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• pp.203-205
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• 1989

A method is presented for calculating the $^{13}C$ chemical shifts produced in liquid solution by referenced relative to RF frequency. The method is useful to get the real variations of chemical shifts in magnetic field by eliminating the affects of the variation of a reference substance.

• Journal of the Semiconductor & Display Technology
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• v.19 no.4
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• pp.88-93
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• 2020

Based on the capture-emission energy (CEE) maps of CMOS devices, a physics-informed machine learning model for the bias temperature instability (BTI)-induced threshold voltage shifts and low frequency noise is presented. In order to incorporate physics theories into the machine learning model, the integration of artificial neural network (IANN) is employed for the computation of the threshold voltage shifts and low frequency noise. The model combines the computational efficiency of IANN with the optimal estimation of Gaussian mixture model (GMM) with soft clustering. It enables full lifetime prediction of BTI under various stress and recovery conditions and provides accurate prediction of the dynamic behavior of the original measured data.

• Journal of the Korean Institute of Intelligent Systems
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• v.11 no.6
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• pp.563-567
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• 2001

We generalize the widebane P0-weyl symbol (P0WS) and the widebane spreading function (WSF) using the generalized warping function . The new generalized P0WS and WSF are useful for analyzing system and communication channels producing generalized time shifts. We also investigated the relationship between the affine Wey1 symbol(AWS) and the P0WS. By using specific warping functions, we derive new P0WS and WSF as analysis tools for systems and communication channels with non-linear group delary characteristics. The new P0WS preserves specific types of changes imposed on random processes. The new WSF provides a new interpretation of output of system and communication channel as weighted superpositions of non-linear time shifts on the input. It is compared to the conventional method obtaining output of system and communication channel as a convention integration of the input with the impulse response of the system and the communication channel. The convolution integration can be interpreted as weighted superpositions of liner time shifts on the input where the weight is the impulse response of the system and the communication channel. Application examples in analysis and detection demonstrate the advantages of our new results.

• The Proceeding of the Korean Institute of Electromagnetic Engineering and Science
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• v.4 no.2
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• pp.41-47
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• 1993

Electrical and electromagnetic wave absorbing properties of MnZn ferrite-rubber composites have been examined for varying the volume fraction of ferrite powder from 0.1 to 0.4 in the frequency range between 1-10 GHz. As the volume fraction of MnZn ferrite increased, the complex permittivity and permeability of composite increased. The peak of reflection loss at the frequency corresponding to 1/4 wavelength shifts to lower frequency, and shifts to lower frequency as the thickness of absorber increased. We show that for the ferrite-rubber composites the volume fraction of ferrite should be controled to obtain the absorbing properties required in given frequency range.

• Interdisciplinary Bio Central
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• v.6 no.1
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• pp.1.1-1.6
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• 2014

A growing body of evidence shows that most psychological traits are polygenic, that is they involve the action of many genes with small effects. However, the study of selection has disproportionately been on one or a few genes and their associated sweep signals (rapid and large changes in frequency). If our goal is to study the evolution of psychological variables, such as intelligence, we need a model that explains the evolution of phenotypes governed by many common genetic variants. This study illustrates simple statistical tools to detect signals of recent polygenic selection: a) ANOVA can be used to reveal significant deviation from random distribution of allele frequencies across racial groups. b) Principal component analysis can be used as a tool for finding a factor that represents the strength of recent selection on a phenotype and the underlying genetic variation. c) Method of correlated vectors: the correlation between genetic frequencies and the average phenotypes of different populations is computed; then, the resulting correlation coefficients are correlated with the corresponding alleles' genome-wide significance. This provides a measure of how selection acted on genes with higher signal to noise ratio. Another related test is that alleles with large frequency differences between populations should have a higher genome-wide significance value than alleles with small frequency differences. This paper fruitfully employs these tools and shows that common genetic variants exhibit subtle frequency shifts and that these shifts predict phenotypic differences across populations.