• 제목/요약/키워드: free gas

검색결과 1,027건 처리시간 0.029초

촉매연소를 이용한 무 산소 가스 생성에 관한 연구 (A Study on the Generation of Oxygen-Free Gas Using Catalytic Combustion for Industrial Applications)

  • 정남조;강성규;송광섭;조성준;유상필;유인수
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2001년도 제22회 KOSCI SYMPOSIUM 논문집
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    • pp.46-52
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    • 2001
  • In this study, the generation of oxygen-free gas using catalytic combustion for industrial applications is explained ; heat treatment and copper annealing. For the experiment, Pd catalysts were determined by testing their catalytic activities over LPG in a micro-reactor. Combustion characteristics for the generation of oxygen-free atmospheric gas and the effect of flue gas upon surface oxidation were estimated form this experiment. As a result of the experimental investigation, we can state that the catalytic combustion could generate oxygen-free atmospheric gas suitable for industrial applications, but vapor produced by combustion process must be carefully considered as a new factor of surface oxidation.

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Improvements of the luminous efficiency of mercury-free fluorescent lamps via structural and complex gas mixture changes

  • Oh, Byung-Joo;Jung, Jae-Chul;Seo, In-Woo;Kim, Hyuk;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.809-812
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    • 2008
  • Structural parameter variation effects (changing the coplanar gap under different discharge dimensions) and use of complex gas mixtures (He, Ne, Ar and Xe) in mercury-free fluorescent lamps are studied in this paper. Pure Neon gas is the best buffer gas for obtaining high luminous efficiency in mercury-free fluorescent lamps. It is shown that with a shorter coplanar gap (30mm), a high luminous efficiency can be obtained at low operating voltage, as well as high luminance uniformity and stable discharge with a Ne-Xe 20% gas mixture.

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비황분계 부취제를 혼합한 LPG 연료의 차량 배출가스 특성에 관한 연구 (A Study on the Exhaust Emissions Characteristics of LPG Vehicle using LPG Fuel with Sulfur Free Odorant)

  • 김재곤;이호길;임의순;정충섭
    • 한국대기환경학회지
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    • 제30권6호
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    • pp.545-554
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    • 2014
  • In general, odorant was added to fuel gases, such as LPG, LNG and city gas, to prevent gas poisoning, ignition, explosion, or other accident caused by fuel gases, and to enable immediate and easy detection of fuel-gas leakage by emitting an offensive smell. This study describes a study on the exhaust emissions characteristics and fuel economy of liquefied petroleum gas (LPG) vehicle using LPG fuel with new sulfur free odorant. New sulfur free odorant was added to LPG to reduce sulfur content of the LPG. Its performance and exhaust emission were compared to those of LPG with sulfur containing odorant (EM, ethyl mercaptan). Engine performance using LPG with sulfur free odorant was similar to that with sulfur-containing odorant. Exhaust emissions from the LPG vehicle with LPG including sulfur free odorant were also similar to those with LPG including sulfur containing odorant in the FTP 75 and NEDC mode. There experimental results suggest that the sulfur free odorant may substitute for the sulfur containing odorant in LPG fuel.

KALIMER 고온풀 자유액면 거동 해석 (Analysis of free surface motions in the hoot Pool of KALIMER)

  • 김성오;어재혁;최훈기
    • 한국전산유체공학회지
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    • 제7권3호
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    • pp.44-52
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    • 2002
  • An analytic methodology was developed for free surface motions between liquid metal coolant and cover gas in order to calculate the phenomena of gas entrainment in hot pool surface through IHX EMP and reactor core. The methodology was setup by applying the first order VOF convection model to CFX4 general purpose fluid dynamics analysis code. The methodology was validated by applying it to an experimental apparatus designed for free surface motions of KALIMER reactor. The distributions of free surface calculated by the present methodology were almost coincident with the experimental data. The developed methodology was applied to the KALIMER reactor of full power operating condition. The shapes of the free surface were nearly uniform. From the results, it was found that the altitude of the free surface from the IHX inlet nozzle of KALIMER reactor is high enough not to affect to free surface motions of generating gas bubbles from the turbulent shear flows such as hydraulic jump and water falls.

Biological Monitoring of Human Exposure to Volatile Halogenated Hydrocarbons Using Urinalysis with Capillary GC-ECD

  • Jung, Won-Tae;Sohn, Dong-Hun
    • Archives of Pharmacal Research
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    • 제15권2호
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    • pp.109-114
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    • 1992
  • For the risk assessment of human exposure to volatile halogenated hydrocarbons, a dynamic purge trap/on-column cryofocusing method using capillary gas chromatograph-$^{63}Ni$ electron capture detector and thermal desorption unit was applied to analyze the free forms, metabolites of 1, 1, 2-trichloroethylene and 1, 1, 2, 2-tetrachloroethylene. The urine sample was diluted with distilled water, hydrolyzed and sealed. Then the inert gas was infused to purge out free 1, 1, 2-trichloroethylene, free 1, 1, 2, 2-tetrachloroethylene and urichloroethanol. These compounds were trapped to $Tenax^R$ / GC-gas trap device throughout clean up tube. Being undertectable to gas chromatograph directly, trichloroacetic acid was methyl esterificated and trapped in the manner above mentioned. The optimal incubation time to get best recovery of methyl ester was 4 hours at $60^circ$C. The concentrations of free volatile halogenated hydrocarbons and their metabolites in urine were obtained of free volatile halogenated hydrocarbons and their metabolites in urine were obtained from 5 healthy volunteers. This analytical method is expected to make the biological monitoring more precise and convenient.

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고체입자가 부상된 자유 횡분류 유동에 대한 전산모사 연구 (I) -2상 분류궤적과 운동량 전달기구- (Numerical Simulation Study on Gas-Particle Two-Phase Jets in a Crossflow (I) -Two-Phase Jet Trajectory and Momentum Transfer Mechanism-)

  • 한기수;정명균
    • 대한기계학회논문집
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    • 제15권1호
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    • pp.252-261
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    • 1991
  • 본 연구에서는 2상 횡분류의 평균 유동특성을 비교적 정확히 예측할 수 있는 방법을 제시하는데 있다. 이를 위하여 2상 기체 분류속에 유입되는 자유흐름의 질량 유입을 Keffer와 Baines의 유입함수를 이용하기로 하며, 입자와 기체분류사이의 궤적 이탈을 고려하기로 한다. 이런 모델을 이용하여 2상 횡분류의 분출초기의 입자와 기 체분류의 속도비(particle to gas velocity ratio at the jet exit)가 유동에 미치는 영향을 알아보고자 한다.

ELECTROMAGNETIC MEANING OF GIBB'S FREE ENERGY, ELECTOLYSIS, CELL REACTION AND BROWN GAS

  • Oh, Hung-Kuk
    • 한국감성과학회:학술대회논문집
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    • 한국감성과학회 2001년도 춘계학술대회 논문집
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    • pp.10-14
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    • 2001
  • Physical chemistry states that electric potential is due to Gibb's free energy from chemical reaction of the electric cell. However we have not the electromagnetic meaning of Gibb's free energy. the free energy is discovered to be a kinetic energy part of the rotating electromagnetic wave ($\pi$-ray), which is different from conventional Coulomb attraction energy and can anticipate that there is a current difference between before and after the electric load. This paper manipulates the relationship between $\pi$-rays (Gibb's free energy) and electrolysis, cell reaction and brown gas reaction.

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가스 하이드레이트 지층 모델의 탄성파 진폭 및 주파수 특성 (Seismic Amplitude and Frequency Characteristics of Gas hydrate Bearing Geologic Model)

  • 신성렬;이상철;박근필;이호영;유동근;김영준
    • 지구물리와물리탐사
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    • 제11권2호
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    • pp.116-126
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    • 2008
  • 가스 하이드레이트의 탐사에서 탄성파 진폭과 주파수 특성은 가스 하이드레이트의 부존 여부에 대한 매우 중요한 판단 근거이다. 본 연구에서 탄성파 진폭특성은 탄성파 수치모델링 기법을 이용하여 음원 주파수 및 산란체의 크기에 따른 변화 양상을 파악하고자 하였다. 일반적으로 진폭에 큰 영향을 미치는 산란은 음원의 주파수 제곱에 비례하고 산란 이상체의 체적에 비례한다. 음원의 주파수가 높아질수록 가스 하이드레이트 지층에서의 산란이 심하여 BSR이 잘 나타나지 않는 반면 음원의 주파수가 낮아질수록 가스 하이드레이트 지층의 진폭공백대 특성이 잘 나타나고 또한 하부의 BSR이 보다 뚜렷히 보이나 해상도가 낮아지게 된다. 가스 하이드레이트 지층 하부의 Free-Gas층을 통과한 반사파는 고주파수 성분이 감쇠되어 저주파수 성분이 우세해지고, Free-Gas로 인하여 나타나는 BSR의 진폭은 극성역전현상이 발생되며 이것은 가스 하이드레이트 지층의 존재와 분포를 판단하는 중요한 인자가 된다. 탄성파 주파수 특성 분석은 Wavelet Transform을 이용하여 시간에 따른 탄성파동의 주파수 변화를 관찰하는 방법을 사용하였다. 탄성파 모형 실험 자료에 대하여 적용한 결과 Free-Gas층에 대비되는 공기층을 통과하여 반사된 탄성파의 주파수는 고주파수 성분이 상당히 감쇠되었음을 관찰할 수 있었다.

A Study on the Mixture Formation Process of Diesel Fuel Spray in Unsteady and Evaporative Field

  • Yeom, Jeong-Kuk;Park, Jong-Sang;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • 제19권12호
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    • pp.2253-2262
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    • 2005
  • The focus of this work is placed on the analysis of the mixture formation mechanism under the evaporative diesel spray of impinging and free conditions. As an experimental parameter, ambient gas density was selected. Effects of density variation of ambient gas on liquid and vapor-phase inside structure of evaporation diesel spray were investigated. Ambient gas density was changed between ${\rho}a=5.0\;kg/m^3$ and $12.3\;kg/m^3$. In the case of impinging spray, the spray spreading to the radial direction is larger due to the decrease of drag force of ambient gas in the case of the low density than that of the high density. On the other hand, in the case of free spray, in accordance with the increase in the ambient gas density, the liquid-phase length is getting short due to the increase in drag force of ambient gas. In order to examine the homogeneity of mixture consisted of vapor-phase fuel and ambient gas in the spray, image analysis was conducted with statistical thermodynamics based on the non-dimensional entropy (S) method. In the case of application of entropy analysis to diesel spray, the entropy value always increases. The entropy of higher ambient density is higher than that of lower ambient gas density during initial injection period.

전자스핀공명에 의한 담배연기 중 자유라디칼 측정 (Determination of Free Radicals in Mainstream Cigarette Smoke by Electron Spin Resonance)

  • 이정민;이존태;박진원;황건중
    • 한국연초학회지
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    • 제29권2호
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    • pp.146-151
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    • 2007
  • Gas phase and particulate phase radicals in mainstream cigarette smoke were determined Electron Spin Resonance(ESR) spectroscopy. The free radicals in particulate phase have been investigated by benzene extract of Cambridge Filter Pad containing the smoke condensate. Spin trapping method in conjunction with ESR was used to investigate free radicals in the gas phase of cigarette smoke. Several analytical experiments were conducted in order to determine the optimal conditions for maximum signal intensities and reproducibility of results. All the tests were optimized and normalized using the University of Kentucky 2R4F reference cigarette. The optimal conditions were 0.6 mL for analysis volume of ESR, $4{\sim}5\;mL$ for collection volume of spin-adducts, and PBN for quantification of free radicals in gas phase. The radical levels of Kentucky 2R4F cigarettes were found $2.18{\times}10^{14}\;spins/cig.$ and $2.10{\times}10^{15}\;spins/cig.$ in gas phase.