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A Study on the Exhaust Emissions Characteristics of LPG Vehicle using LPG Fuel with Sulfur Free Odorant

비황분계 부취제를 혼합한 LPG 연료의 차량 배출가스 특성에 관한 연구

  • Kim, Jae-Kon (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority (K-Petro)) ;
  • Lee, Ho-Kil (Gas Engine System R&D Center, Korea Automotive Technology Institute) ;
  • Yim, Eui Soon (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority (K-Petro)) ;
  • Jung, Choong-Sub (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority (K-Petro))
  • 김재곤 (한국석유관리원 석유기술연구소) ;
  • 이호길 (자동차부품연구원 가스엔진 시스템 R&D센터) ;
  • 임의순 (한국석유관리원 석유기술연구소) ;
  • 정충섭 (한국석유관리원 석유기술연구소)
  • Received : 2014.08.31
  • Accepted : 2014.11.24
  • Published : 2014.12.31

Abstract

In general, odorant was added to fuel gases, such as LPG, LNG and city gas, to prevent gas poisoning, ignition, explosion, or other accident caused by fuel gases, and to enable immediate and easy detection of fuel-gas leakage by emitting an offensive smell. This study describes a study on the exhaust emissions characteristics and fuel economy of liquefied petroleum gas (LPG) vehicle using LPG fuel with new sulfur free odorant. New sulfur free odorant was added to LPG to reduce sulfur content of the LPG. Its performance and exhaust emission were compared to those of LPG with sulfur containing odorant (EM, ethyl mercaptan). Engine performance using LPG with sulfur free odorant was similar to that with sulfur-containing odorant. Exhaust emissions from the LPG vehicle with LPG including sulfur free odorant were also similar to those with LPG including sulfur containing odorant in the FTP 75 and NEDC mode. There experimental results suggest that the sulfur free odorant may substitute for the sulfur containing odorant in LPG fuel.

Keywords

References

  1. Arthur, R.K. and V. Arun (1976) Measurement of Odorant Levels in Natural Gas, Ind. Eng. Chem., Prod. Res. Dev., 15(1), 59-63. https://doi.org/10.1021/i360057a011
  2. Cui, H., S.Q. Tum, and M.A. Reese (2009) Removal of Sulfur Compounds form Utility Pipelined Synthetic Natural Gas using Modified Activated Carbons, Catalysis Today, 139, 274-279. https://doi.org/10.1016/j.cattod.2008.03.024
  3. De Wild, P.J., R.G. Nyqvist, F.A. De Bruiji, and E.R. Stobbe (2006) Removal of Sulphur-containing Odorants from Fuel Gases for Fuel Cell-based Combined Heat and Power Applications, Journal of Power Sources, 159, 995-1004. https://doi.org/10.1016/j.jpowsour.2005.11.100
  4. Frank, G., K. Kerstin, and R. Rainer, R (2007) Sulfur-Free Odorization with Gasodor S-Free-a Aeview of the Accompanying Research and Development Activities, Energy & Fules, 21, 3322-3333. https://doi.org/10.1021/ef700406x
  5. Han, S.B., Y. Kim, H.K. Lee, J.H. Kang, and Y.J. Chung (2009) Characteristics Analysis of Exhaust Emission according to Fuels at CVS-75 Mode, Journal of Energy Engineering, 18(1), 69-73.
  6. Imamura, D., M. Akai, and S. Watanabe (2005) Exploration of Hydrogen Odorants for Fuel Cell Vehicles, Journal of Power Sources, 152, 226-232. https://doi.org/10.1016/j.jpowsour.2005.01.007
  7. KATECH (Korea Automotive Technology Institute) and K-Petro (Korea Petroleum Quality & Distribution Authority) (2009) Study on the LPG Fuel Characteristics of LPG : Devlelopment of Sulfur Free Odorant.
  8. Kim, J.-K., C.K. Park, E.S. Yim, and D.K. Kim (2009) The Compositions of Sulfur Free Odorant, Korea Patent, Patent No.100933493.
  9. Kim, J.-K., E.S. Yim, K.I. Min, and C.-S. Jung (2014a) A Study on the Performance and Exhaust Emissions Characteristics of LPG Engine using LPG Fuel with New Sulfur Free Odorant, Journal of Energy Engineering, 23(3), 88-95. (in Korean with English abstract) https://doi.org/10.5855/ENERGY.2014.23.3.088
  10. Kim, J.-K., E.S. Yim, and C.-S. Jung (2014b) A Study on the Application of Sulfur-Free Odorant for LPG Fuel, KIGAS, 18(5), 52-59. (in Korean with English abstract)
  11. K-Petro (2014) Fuel quality standard of LPG in Korea, http://www.kpetro.or.kr/sub.jsp?MenuID=m2as402.
  12. Lee, H.K., Y. Kim, and J. Ryu (2008) $CO_2$ Emit and Fuel Economy Characteristics for Propane Mixing Rate of the LPG Vehicle, The Korean Society of Automotive Engineers, 2008 Annual conference, 839-845. (in Korean with English abstract)
  13. Lee, S.H., T.Y. Song, and Y.S. Baek (2001) Optimization of Odor Concentration by Operation of Small Station Odorizer, KIGAS, 5(3), 36-44. (in Korean with English abstract)
  14. Marvin, L.W., W.G. John, O.C. Faye, and W.B. Dennis (1978) Odorant Evaluation : A Study Ethanthiol and Tetrahydrothiophene as Waring agents in Propane, Environmental Science & Technology, 12(12), 1285-1288. https://doi.org/10.1021/es60147a003
  15. Park, J., J. Lee, S. Kim, J. Kim, and K. Ahn (2013) A Study on the Emission Characteristics of Korean Light-duty Vehicles in Real-road Driving Conditions, Transactions of KSAE, 21(6), 123-134. (in Korean with English abstract) https://doi.org/10.7467/KSAE.2013.21.6.123
  16. Park, J., J. Lee, S. Kim, J. Kim, D. Kang, Y. Lim, and B. Han (2012) Estimation on the Reduction of SULEV LPG Vehicles, J. KOSAE, 28(1), 68-76. (in Korean with English abstract) https://doi.org/10.5572/KOSAE.2012.28.1.068
  17. Ruzsanyi, V., S. Sielemann, and J.I. Baumbach (2007) Detection of sulfur-free odorants in natural gas using ion mobility spectrometry, Journal of Environmental Monitoring, 9, 61-65. https://doi.org/10.1039/B613951E
  18. Therese, S. and L. Elena (2008) Overcoming barriers to the implementation of alternative fuels for road transport in Europe, Journal of Cleaner Production, 16, 577-590. https://doi.org/10.1016/j.jclepro.2006.12.001