• 한국연소학회:학술대회논문집
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• 2001.06a
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• pp.46-52
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• 2001

In this study, the generation of oxygen-free gas using catalytic combustion for industrial applications is explained ; heat treatment and copper annealing. For the experiment, Pd catalysts were determined by testing their catalytic activities over LPG in a micro-reactor. Combustion characteristics for the generation of oxygen-free atmospheric gas and the effect of flue gas upon surface oxidation were estimated form this experiment. As a result of the experimental investigation, we can state that the catalytic combustion could generate oxygen-free atmospheric gas suitable for industrial applications, but vapor produced by combustion process must be carefully considered as a new factor of surface oxidation.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.809-812
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• 2008

Structural parameter variation effects (changing the coplanar gap under different discharge dimensions) and use of complex gas mixtures (He, Ne, Ar and Xe) in mercury-free fluorescent lamps are studied in this paper. Pure Neon gas is the best buffer gas for obtaining high luminous efficiency in mercury-free fluorescent lamps. It is shown that with a shorter coplanar gap (30mm), a high luminous efficiency can be obtained at low operating voltage, as well as high luminance uniformity and stable discharge with a Ne-Xe 20% gas mixture.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.6
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• pp.545-554
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• 2014

In general, odorant was added to fuel gases, such as LPG, LNG and city gas, to prevent gas poisoning, ignition, explosion, or other accident caused by fuel gases, and to enable immediate and easy detection of fuel-gas leakage by emitting an offensive smell. This study describes a study on the exhaust emissions characteristics and fuel economy of liquefied petroleum gas (LPG) vehicle using LPG fuel with new sulfur free odorant. New sulfur free odorant was added to LPG to reduce sulfur content of the LPG. Its performance and exhaust emission were compared to those of LPG with sulfur containing odorant (EM, ethyl mercaptan). Engine performance using LPG with sulfur free odorant was similar to that with sulfur-containing odorant. Exhaust emissions from the LPG vehicle with LPG including sulfur free odorant were also similar to those with LPG including sulfur containing odorant in the FTP 75 and NEDC mode. There experimental results suggest that the sulfur free odorant may substitute for the sulfur containing odorant in LPG fuel.

• Journal of computational fluids engineering
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• v.7 no.3
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• pp.44-52
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• 2002

An analytic methodology was developed for free surface motions between liquid metal coolant and cover gas in order to calculate the phenomena of gas entrainment in hot pool surface through IHX EMP and reactor core. The methodology was setup by applying the first order VOF convection model to CFX4 general purpose fluid dynamics analysis code. The methodology was validated by applying it to an experimental apparatus designed for free surface motions of KALIMER reactor. The distributions of free surface calculated by the present methodology were almost coincident with the experimental data. The developed methodology was applied to the KALIMER reactor of full power operating condition. The shapes of the free surface were nearly uniform. From the results, it was found that the altitude of the free surface from the IHX inlet nozzle of KALIMER reactor is high enough not to affect to free surface motions of generating gas bubbles from the turbulent shear flows such as hydraulic jump and water falls.

• Archives of Pharmacal Research
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• v.15 no.2
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• pp.109-114
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• 1992

For the risk assessment of human exposure to volatile halogenated hydrocarbons, a dynamic purge trap/on-column cryofocusing method using capillary gas chromatograph-$^{63}Ni$ electron capture detector and thermal desorption unit was applied to analyze the free forms, metabolites of 1, 1, 2-trichloroethylene and 1, 1, 2, 2-tetrachloroethylene. The urine sample was diluted with distilled water, hydrolyzed and sealed. Then the inert gas was infused to purge out free 1, 1, 2-trichloroethylene, free 1, 1, 2, 2-tetrachloroethylene and urichloroethanol. These compounds were trapped to $Tenax^R$ / GC-gas trap device throughout clean up tube. Being undertectable to gas chromatograph directly, trichloroacetic acid was methyl esterificated and trapped in the manner above mentioned. The optimal incubation time to get best recovery of methyl ester was 4 hours at $60^circ$C. The concentrations of free volatile halogenated hydrocarbons and their metabolites in urine were obtained of free volatile halogenated hydrocarbons and their metabolites in urine were obtained from 5 healthy volunteers. This analytical method is expected to make the biological monitoring more precise and convenient.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.1
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• pp.252-261
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• 1991

A particle trajectory model to simulate two-phase particle-laden crossjets into two-dimensional horizontal free stream has been developed to study the variations of the jet trajectories and velocity variations of the gaseous and the particulate phases. The following conclusions may be drawn from the predicted results, which are in agreement with experimental observations. The penetration of the two-phase jet in a crossflow is greater than that of the single-phase jet. The penetration of particles into the free stream increases with increasing particle size, solids-gas loading ratio and carrier gas to free stream velocity ratio at the jet exit. When the particle size is large, the solid particles separate from the carrier gas , while the particles are completely suspended in the carrier gas for the case of small size particles. As the particle to carrier gas velocity ratio at the jet exit is less than unity, the particles in the vicinity of the jet exit are accelerated by the carrier gas. As the injection angle is increased, the difference of the particle trajectory from that of the pure gas becomes larger. Therefore, it can be concluded that the velocities and trajectories of the particle-laden jets in a crossflow change depending on the solids-gas loading ratio, particle size, carrier gas to free stream velocity ratio and particle to gas velocity ratio at the jet exit.

• Proceedings of the Korean Society for Emotion and Sensibility Conference
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• 2001.05a
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• pp.10-14
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• 2001

Physical chemistry states that electric potential is due to Gibb's free energy from chemical reaction of the electric cell. However we have not the electromagnetic meaning of Gibb's free energy. the free energy is discovered to be a kinetic energy part of the rotating electromagnetic wave ($\pi$-ray), which is different from conventional Coulomb attraction energy and can anticipate that there is a current difference between before and after the electric load. This paper manipulates the relationship between $\pi$-rays (Gibb's free energy) and electrolysis, cell reaction and brown gas reaction.

• Geophysics and Geophysical Exploration
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• v.11 no.2
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• pp.116-126
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• 2008

In gas hydrate survey, seismic amplitude and frequency characteristics play a very important role in determining whether gas hydrate exists. According to the variation of source frequency and scatterer size, we study seismic amplitude characteristics using elastic modeling applied at staggered grids. Generally speaking, scattering occurs in proportion to the square of source frequency and the scatterer volume, which has an effect on seismic amplitude. The higher source frequency is, the more scattering occurs in gas hydrate bearing zone. Therefore, BSR is hardly observed in high frequencies. On the other side, amplitude blanking zone and BSR is clearly observed in lower frequencies although the resolution is poor as a whole. Seismic reflections traveling through free-gas layer below gas hydrate bearing zone decay so severely a high frequency component that a low frequency term is dominant. Amplitude anomaly of BSR result from high acoustic impedance contrast due to free-gas, which is a very crucial factor to estimate gas hydrate bearing zone. Seismic frequency analysis is carried out using wavelet transform method that frequency component could be decomposed with time variation. In application of wavelet transform to the seismic physical experiments data, we can observe that reflections traveling through air layer, which corresponds to the free-gas layer, decay a high frequency component.

• Journal of Mechanical Science and Technology
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• v.19 no.12
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• pp.2253-2262
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• 2005

The focus of this work is placed on the analysis of the mixture formation mechanism under the evaporative diesel spray of impinging and free conditions. As an experimental parameter, ambient gas density was selected. Effects of density variation of ambient gas on liquid and vapor-phase inside structure of evaporation diesel spray were investigated. Ambient gas density was changed between ${\rho}a=5.0\;kg/m^3$ and $12.3\;kg/m^3$. In the case of impinging spray, the spray spreading to the radial direction is larger due to the decrease of drag force of ambient gas in the case of the low density than that of the high density. On the other hand, in the case of free spray, in accordance with the increase in the ambient gas density, the liquid-phase length is getting short due to the increase in drag force of ambient gas. In order to examine the homogeneity of mixture consisted of vapor-phase fuel and ambient gas in the spray, image analysis was conducted with statistical thermodynamics based on the non-dimensional entropy (S) method. In the case of application of entropy analysis to diesel spray, the entropy value always increases. The entropy of higher ambient density is higher than that of lower ambient gas density during initial injection period.

• Journal of the Korean Society of Tobacco Science
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• v.29 no.2
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• pp.146-151
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• 2007

Gas phase and particulate phase radicals in mainstream cigarette smoke were determined Electron Spin Resonance(ESR) spectroscopy. The free radicals in particulate phase have been investigated by benzene extract of Cambridge Filter Pad containing the smoke condensate. Spin trapping method in conjunction with ESR was used to investigate free radicals in the gas phase of cigarette smoke. Several analytical experiments were conducted in order to determine the optimal conditions for maximum signal intensities and reproducibility of results. All the tests were optimized and normalized using the University of Kentucky 2R4F reference cigarette. The optimal conditions were 0.6 mL for analysis volume of ESR, $4{\sim}5\;mL$ for collection volume of spin-adducts, and PBN for quantification of free radicals in gas phase. The radical levels of Kentucky 2R4F cigarettes were found $2.18{\times}10^{14}\;spins/cig.$ and $2.10{\times}10^{15}\;spins/cig.$ in gas phase.