• Bulletin of the Korean Chemical Society
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• v.23 no.12
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• pp.1778-1784
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• 2002

Novel membrane lipids containing the unusual very long chain fatty $acid{\alpha}{\omega}-1316-dimethyloctacosanedioate$, dimethyl. Ester (DME C30) was isolated and purified from thermophilic anaerobic eubacterium, Thermoanaerobacter ethanolicus. Structures of the lipids containing the bifunctional fatty acyl components were proposed by various analyses such as $^1H,\;^{13}C,\;^{31}P$ nuclear magnetic resonance (NMR), Fourier transform infrared(FTIR) spectroscopy, gas chromatography/mass spectrometry (GC/MS) and fast atom bombardment mass spectrometry (FAB/MS). Combined with the GC/MS, $^1H,\;and\;^{13}C$NMR data, we confirmed that the head groups of the lipids contained the glycerol and/or glucosamine molecules. $^{31}P$ NMR spectrum also showed that the lipids contained phosphate in a phosphodiester linkage. The proposed structures of these novel lipid components were the ones in which two head groups were linked by the membrane spanning fatty acyl component(DME C30)and regular chain fatty acids on glycerol moiety of each head group.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.1
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• pp.201-204
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• 2011

For efficient noise reduction in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrum, a new algorithm was proposed. The suggested algorithm reduces white and electrical noise, and it improves signal-to-noise ratio. This algorithm has been optimized to reduce the noise more efficiently using the traces of signal level. The algorithm has been efficiently combined with derivative window to improve the resolution as well S/N. Time domain data was corrected for DC voltage interference. $t^n$ window was applied in time domain data to improved the resolution. However, $t^n$ window can improve the signal resolution, it will also increase the noise level in frequency domain. Therefore, newly developed noise reduction algorithm will be applied to make a balance between resolving power and S/N ratio for magnitude mode. The trace algorithm can determine the current data point with several data points (mean, past data, calculated past data). In the current calculations, we assumed data points with S/N ratio more than 3 were considered as signal data points. After the windowing and noise reduction, both resolution and signal-to-noise ratio were improved. This algorithm is applicable more efficiently to frequency dependent noise and large size data.

• Wind and Structures
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• v.14 no.4
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• pp.337-357
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• 2011

The collection of wind speed time series by means of digital data loggers occurs in many domains, including civil engineering, environmental sciences and wind turbine technology. Since averaging intervals are often significantly larger than typical system time scales, the information lost has to be recovered in order to reconstruct the true dynamics of the system. In the present work we present a simple algorithm capable of generating a real-time wind speed time series from data logger records containing the average, maximum, and minimum values of the wind speed in a fixed interval, as well as the standard deviation. The signal is generated from a generalized random Fourier series. The spectrum can be matched to any desired theoretical or measured frequency distribution. Extreme values are specified through a postprocessing step based on the concept of constrained simulation. Applications of the algorithm to 10-min wind speed records logged at a test site at 60 m height above the ground show that the recorded 10-min values can be reproduced by the simulated time series to a high degree of accuracy.

• Ocean Systems Engineering
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• v.2 no.3
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• pp.189-203
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• 2012

New experiments focusing on the evolution characteristics of nonlinear wave trains were conducted in a large wave flume. A series of wave trains with added sidebands, varying initial steepness, perturbed amplitudes and frequencies, were physically generated in a long wave flume. The experimental results show that the increasing wave steepness, increases the speed of sidebands growth. To study the frequency and phase modulation, the Morlet wavelet transform is adopted to extract the instantaneous frequency of wave trains and the phase functions of each wave component. From the instantaneous frequency, there are local frequency downshifts, even an effective frequency downshift was not observed. The frequency modulation increases with an increase in amplitude modulation, and abrupt changes of instantaneous frequencies occur at the peak modulation. The wrapped phase functions show that in the early stage of the modulation, the phase of the upper sideband first diverges from that of the carrier waves. However, at the later stage, the discrepancy phase from the carrier wave transformed to the lower sideband. The phase deviations appear in the front of the envelope's peaks. Furthermore, the evolution of the instantaneous frequency exhibits an approximate recurrence-type for the experiment with large imposed sidebands, even when the corresponding recurrence is not observed in the Fourier spectrum.

• Journal of the Institute of Convergence Signal Processing
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• v.12 no.1
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• pp.33-37
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• 2011

This paper presents the frequency spectral analysis based on FFT of the infrared ray fire thermal image, it is an object to deduce the conditions for determining fire alarm through the image processing with the frequency domain. After the candidate regions are separated by using pre-defined brightness value, the fast fourier transform is performed for consecutive infrared thermal images, the frequency spectral analysis of the thermal image analyzed DC and AC frequency distribution. The fire criterion of the thermal image was presented based on the analyzed result and a practicality was confirmed through the computer simulation.

• Macromolecular Research
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• v.11 no.1
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• pp.14-18
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• 2003

Grafting of glycidyl methacrylate (GMA) upon coralline hydroxyapatite in conjugation with demineralized bone matrix (CHA-DBM) using equal molar ratio of potassium persulfate/sodium metabisulfite redox initiating system was investigated in aqueous medium. The optimum reaction condition was standardized by varying the concentrations of backbone, monomer, initiator, temperature and time. The results obtained imply that the percent grafting was found to increase initially and then decrease in most of the cases. The optimum temperature and time were found to be 50 $^{\circ}C$ and 180 min, respectively, to obtain higher grafting yield. Fourier transform infrared (FT-IR) spectroscopy and X-ray powder diffraction (XRD) method were employed for the proof of grafting. The FT-IR spectrum of grafted CHA-DBM showed epoxy groups at 905 and 853 $cm^{-1}$ / and ester carbonyl group at 1731 $cm^{-1}$ / of poly(glycidyl methacrylate) (PGMA) in addition to the characteristic absorptions of CHA-DBM, which provides evidence of the grafting. The XRD results clearly indicated that the crystallographic structure of the grafted CHA-DBM has not changed due to the grafting reaction. Further, no phase transformation was detected by the XRD analysis, which suggests that the PGMA is grafted only on the surface of CHA-DBM backbone. The grafted CHA-DBM will have better functionality because of their surface modification and hence they may be more useful in coupling of therapeutic agents through epoxy groups apart from being used as osteogenic material.

• Journal of the Korean Society for Nondestructive Testing
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• v.34 no.6
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• pp.457-466
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• 2014

This paper presents an analytic and numerical simulation of the generation and propagation of pico-second ultrasound with nano-scale wavelength, enabling the production of bulk waves in thin films. An analytic model of laser-matter interaction and elasto-dynamic wave propagation is introduced to calculate the elastic strain pulse in microstructures. The model includes the laser-pulse absorption on the material surface, heat transfer from a photon to the elastic energy of a phonon, and acoustic wave propagation to formulate the governing equations of ultra-short ultrasound. The excitation and propagation of acoustic pulses produced by ultra-short laser pulses are numerically simulated for an aluminum substrate using the finite-difference method and compared with the analytical solution. Furthermore, Fourier analysis was performed to investigate the frequency spectrum of the simulated elastic wave pulse. It is concluded that a pico-second bulk wave with a very high frequency of up to hundreds of gigahertz is successfully generated in metals using a 100-fs laser pulse and that it can be propagated in the direction of thickness for thickness less than 100 nm.

• Bulletin of the Korean Chemical Society
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• v.14 no.1
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• pp.21-29
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• 1993

For the study of relaxation processes in complex spin system, a general master equation, which can be used to simulate a vast range of pulse experiments, has been formulated using the Liouville representation of quantum mechanics. The state of a nonequilibrium spin system in magnetic field is described by a density vector in Liouville space and the time evolution of the system is followed by the application of a linear master operator to the density vector in this Liouville space. In this master equation the nuclear spin relaxation due to intramolecular dipolar interaction or randomly fluctuating field interaction is explicitly implemented as a relaxation supermatrix for a strong coupled two-spin (1/2) system. The whole dynamic information inherent in the spin system is thus contained in the density vector and the master operator. The radiofrequency pulses are applied in the same space by corresponding unitary rotational supertransformations of the density vector. If the resulting FID is analytically Fourier transformed, it is possible to represent the final nonstationary spectrum using a frequency dependent spectral vector and intensity determining shape vector. The overall algorithm including relaxation interactions is then translated into an ANSIFORTRAN computer program, which can simulate a variety of two dimensional spectra. Furthermore a new strategy is tested by simulation of multiple quantum signals to differentiate the two relaxation interaction types.

• Journal of the Korean Society for Railway
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• v.15 no.3
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• pp.231-236
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• 2012

In this paper, aerodynamic noise characteristics of high-speed trains were deduced from the beamforming method. First, pass-by noise of high-speed trains was measured by a microphone array system. This measurement suggested that the majority of the aerodynamic noise produced came from the bogie area, the pantograph and its cover, and inter-coach gaps. Then, beampower outputs of a position in high-speed trains were obtained from the beamforming method. By Fourier transform, sound characteristics of the position in the frequency domain were deduced from the beamforming power spectrum. From this study, aerodynamic noise characteristics from the major sources of high-speed trains were drawn.

• Advances in nano research
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• v.5 no.4
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• pp.373-392
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• 2017

Silver nanoparticles (AgNPs) were successfully synthesized through a simple green route using the Nelumbo nucifera leaf, stem and flower extracts. These nanoparticles showed characteristic UV-Vis absorption peaks between 410-450 nm which arises due to the plasmon resonance of silver nanoparticles. The Fourier transform infrared spectroscopy (FT-IR) confirmed the presence of amides and which acted as the stabilizing agent. X-ray diffraction spectrum of the nanoparticles confirmed the Face centered cubic (FCC) structure of the formed AgNPs. Dynamic light scattering technique was used to measure hydrodynamic diameter (68.6 nm to 88.1 nm) and zeta potential (-55.4 mV, -57.9 mV and 98.9 mV) of prepared AgNPs. The scanning electron micrographs of dislodged nanoparticles in aqueous solution showed the production of reasonably monodispersed silver nanoparticles (1-100 nm). The antimicrobial activity of prepared AgNPs was evaluated against fungi, Gram-positive and Gram-negative bacteria using disc diffusion method. Anti-corrosion studies were carried out using coupon method (mild steel and iron) and dye degradation studies were carried out by assessing photo-catalytic activity of Nelumbo nucifera extracts mediated AgNPs.