• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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• pp.46-49
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• 1992

Cadmium sulfide thin films were deposited on glass substrate by Chemical Mist Deposition from solutions containing equimolar (0.1M) cadmium chloride and thiourea [(NH$_2$)$_2$CS] at a mist velocity of 1.6m/sec. Substrate temperatures were ranged between 200$^{\circ}C$ and 400$^{\circ}C$. The microstructure and semiconducting property of the films were investigated using SEM, X-ray diffraction, UV transmittance measurement and four point probe method. All the films have hexagonal structure and diffraction patterns indicate that the intensity of (112) and (101) reflections increase with increasing substrate temperature, whereas (002) reflection substrate temperature, whereas(002) reflection decrease for substrate temperatures between 250$^{\circ}C$ and 350$^{\circ}C$. The films prepared at lower temperature have a significant number of pinholes due probably to entrapped gaseous reaction. Optical transmittance of the films deposited at 350$^{\circ}C$ was about 75%. Optical bandgap of the films were 2.43eV regardless of substrate temperature. The dark resistivity of the films decreased with increasing substrate temperature up to 300$^{\circ}C$ and increased with further increasing substrate temperature. The films were photosensitive and had dark-to-light resistivity ratios of about 10 at room temperature for a white-light photoexcitation intensity of 50mw/$\textrm{cm}^2$.

• 대한핵의학회지
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• 제34권6호
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• pp.478-486
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• 2000

목적: 조직 검사에서 유방암으로 확진된 환자 15명 (평균 연령 50.4세)을 대상으로 수술 전에 시행한 유방림프신티그라피(lymphoscintigraphy)와 수술 중 감마프로우브를 이용하여, 림프관 유입형태 및 전초림프절(sentinel lymph node)을 찾아, 전초 및 액와림프절을 각각 절제, 생검하여, 전초 림프절의 림프신티그라피 발현율, 전초림프절 전이와 액와림프절 전이의 상관 관계 등을 보고자 하였다. 대상 및 방법: 환자의 임상병기는 병기 I-II 이었고, 4례에서 액와림프절이 촉지되었다. 침습성 관암 13명, 수질암 및 포도당 풍부암이 각각 1명씩이었다. 유방림프신티그라피는 다음과 같이 시행하였다. 방사성의약품 Tc-99m antimony sulfide colloid $30{\sim}37MBq$을 총 0.4 ml 용량으로 만들어, 원발 종괴에서 $2{\sim}3mm$ 떨어진 위치의 12, 3, 6, 9시 방향에 각각 0.1 ml를 피내 주사하고 약 2분 동안 마사지하였다. 저에너지, 고해상도 평행 조준기를 이용하여 초기 동적 영상(10 sec/frame)을 10분간 시행하였으며, 이어서 5분 간격으로 $30{\sim}60$분에 걸쳐 초기 정적영상을 얻었고, 주사 후 2시간에 지연영상을 획득하였으며, 각각의 영상을 비교하여 전초림프절과 유입 림프관을 확인하였다. 유방림프신티그라피검사가 끝나면 즉시 수술실로 옮겨 전초림프절이라고 판독된 부위를 감마프로우브로 찾아 림프절의 계수와 배후 방사능을 측정하였고, 이 부위를 절개하여 조직을 떼어내 표지하고 생검하였으며, 그 외에 배후 방사능보다 높은 계수를 보인 부위가 있으면 따로 표지하여 조직 검사를 하였다. 모든 환자에서 원발 종양의 절제술과 액와림프절 절제술을 시행하였다. 결과: 전체 환자 15명 가운데 14명에서 유방림프신티그라피 및 수술 중 감마 프로우브로 전초림프절이 발견되었다(전초 림프절 검출율: 93.3%). 유방림프신티그라피로 발견된 평균 전초림프절수는 $2.47{\pm}2.00$개였으며, 감마프로우브를 이용하여 수술로 절제된 평균 전초림프절 수는 $2.36{\pm}1.96$개였다. 초기 동적 유방림프신티그라피에서 전초림프절로 유입되는 림프관이 총 15명 중 3명에서 관찰 할 수 있었으며(20%), 3명에서는 전초림프절이 2시간 지연 영상에서만 발견되었다(20%). 유방림프신티그라피에서 전초림프절이 나타난 시간은 평균 $33.4{\pm}48.4$분이었다. 전초림프절의 조직 생검 결과 14명 가운데 7명의 전초림프절에서 전이 소견이 관찰되었고(50%), 이 중 5명 환자의 액외림프절에서 전이가 보였다(예민도: 71.2%). 그러나 전초림프절에 전이가 있었던 7명 가운데 2명은 액와림프절에서 전이 소견은 관찰되지 않았다. 전초림프절에 전이가 없었던 7명 환자에서는 모두 액와림프절에서도 전이 소견을 관찰 할 수 없었다(특이도: 100%). 유방림프신티그라피 및 수술 중 감마프로우브로 전초림프절을 발견 할 수 없었던 1명에서 액와절제술 후 액와림프절 조직에서 림프절에 전이가 관찰되었다. 결론: 따라서 유방암 환자에서 유방림프신티그라피와 수술 중 감마프로우브를 이용한 전초림프절 생검은 액와림프절 전이 평가에 있어 높은 예민도와 특이도를 나타내므로 불필요한 액와림프절 절제술을 줄이는데 도움이 될 것이다.

• 한국진공학회지
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• 제17권2호
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• pp.102-108
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• 2008

대향 타겟식 스퍼터링법 (Facing Targets Sputtering)을 이용하여 유리기판위에 증착한 Ag/ZnO 다층 박막의 특성을 연구하였다. Ag 박막의 높은 전도도와 투과율을 나타내는 공정조건을 찾기 위하여, 증착시간, 기판온도 변화에 따른 Ag박막의 특성을 살펴보았으며, ZnO 박막의 두께 변화에 따른 Ag/ZnO 다층박막의 특성을 살펴보았다, 10초간 증착한 Ag 박막은 연속된 막구조를 가지지 못하여, 30초간 증착된 막에 비해 전기적, 광학적 특성이 저하되는 것을 확인할 수 있었다. ZnO 박막의 AFM 측정 결과 박막의 거칠기(Rrms) 값의 변화에 따라 Ag/ZnO박막의 특성에 영향을 미쳤으며, 거칠지 않은 표면을 지닌 박막에서 Ag 박막 증착 시 좋은 특성을 나타냈다. 제작된 박막은 four point probe, UV/VIS spectrometer, AFM을 사용하여 전기적, 광학적, 구조적 특성을 조사하였다. 제작결과 Ag/ZnO 다층박막의 면저항은 9.25 $[\Omega/sq.]$을 나타내었으며, 가시광영역에서 광투과율은 80%이상을 나타내었다.

• 한국초전도ㆍ저온공학회논문지
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• 제16권2호
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• pp.29-32
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• 2014

The critical current, $I_c$ of HTS superconducting tapes can be measured by transport or contactless method. Practically, the transport method using the four-probe method is the most common. In this study, a simple test procedure by clipping the voltage lead taps have been introduced instead of soldering which reduces time and effort and thereby achieving a much faster measurement of $I_c$. When using a pair of iron clips, $I_c$ value decreased as compared with the measured one by standard method using soldered voltage taps and varies with the width of the clipped specimen part. However, when using a pure Cu clip, both by clipping and by soldering voltage taps give a comparable result and $I_c$ measured are equal and close to the samples specification. As a result, material to be used as voltage clip should be considered and should not influence the potential voltage between the leads during $I_c$ measurement. Furthermore, the simulation result of magnetic flux during $I_c$ measurement test showed that the decrease of $I_c$ observed in the experiment is due to the magnetic flux density, $B_y$ produced at the clipped part of the sample by the operating current with iron clips attached to the sample.

• Transactions on Electrical and Electronic Materials
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• 제13권4호
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• pp.208-211
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• 2012

In the present study, a ZnO thin film, as a buffer layer of ITO (indium tin oxide) film was deposited on glass substrates by RF magnetron sputtering at low temperature of $150^{\circ}C$. In order to estimate the optical characteristics and compare with the experimental results in Glass/ZnO(100 nm)/ITO(35 nm) multilayered film, the simulation program, EMP (Essential Macleod Program) was adopted. The sheet resistance and optical transmittance of the films were measured using the four-point probe method and spectrophotometer, respectively. From X-ray diffraction patterns, all the films deposited at $150^{\circ}C$ demonstrated only the amorphous phase. Optical transmittance was the highest at a ZnO thickness of 100 nm. The ITO(35 nm)/ZnO(100 nm) film exhibits an optical transmittance of >92% at 550 nm. The multilayered film showed an electrical sheet resistance of 407 ${\Omega}/sq.$, which is significantly better than that of a single-layer ITO film without a ZnO buffer layer (815 ${\Omega}/sq.$).

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1630-1634
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• 2011

Electroless plating of metallic nickel on carbon fiber surfaces was carried out to control specific electric resistivity of the fibers, and the effects of the nickel content and coating thickness on the electric properties were studied. The structural and surface properties of the carbon fibers were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The specific resistivity of the fibers was measured using a four-point probe testing method. From the XPS results, the oxygen and Ni atomic ratio of the fibers was greatly enhanced as the plating time increased. Additionally, it was observed that the specific electric resistivity decreased considerably in the presence of metallic nickel particles and with the formation of nickel layers on carbon fibers.

• Advances in materials Research
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• 제3권4호
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• pp.233-242
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• 2014

Magnetic and conducting aniline sulfide resin cross-linked (ASC-Fe3O4) nanocomposite has been prepared in the presence of aniline sulfide resin (ASR), aniline, $Fe_3O_4$ coated by polyethylene glycol (PEG) and initiator. The magnetic properties of the resulting composites showed ferromagnetic behavior, such as high-saturated magnetization (Ms= 41 emu/g), and coercive force (Hc=1.5 Oe). The saturated magnetization was increased by increasing of $Fe_3O_4$ content and decreased by increasing aniline ratio. The transmission electron micrograph (TEM) and X-ray diffraction proved that nanometer-sized about 20-30 nm $Fe_3O_4$ in the composite. The average size of ASC-$Fe_3O_4$ nanocomposite with core-shell structure was about 50-60 nm, and polydisperse. This approach may also be extended to the synthesis and modification of other polymers. Electrical conductivity of aniline sulfide resin cross-linked (ASC) nanocomposite has been studied by four-point probe method and produced $3.3{\times}10^{-4}S/cm$ conductivity for it. The conductivity of the composites at room temperature depended on the $Fe_3O_4$, aniline ratio and doping degree. The thermogravimetry analysis (TGA) results showed that this resin is thermal resistance near of $500^{\circ}C$. So, It can be used for resistance thermal coating for military applications. $Fe_3O_4$-PASC nanocomposite has been flexible structure with electrical and magnetic properties.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.181.2-181.2
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• 2015

Sputtering is one of the most popular physical deposition methods due to their versatility and reproducibility. Synthesis of Cr thin films by DC magnetron sputtering using glancing angle deposition (GLAD) has been reported. Chromium thin films have been prepared at two different working pressure($2.0{\times}10-2$, 30, $3.3{\times}10-3torr$) on Si-wafer substrate using magnetron sputtering with glancing angle deposition (GLAD) technique. The thickness of Cr thin films on the substrate was adjusted about 1 mm. The electrical property was measured by four-point probe method. For the measurement of density in the films, an X-ray reflectivity (XRR) was carried out. The sheet resistance and column angle increased with the increase of glancing angle. However, nanohardness and density of Cr thin films decreased as the glancing angle increased. The measured density for the Cr thin films decreased from 6.1 to 3.8 g/cc as the glancing angle increased from $0^{\circ}$ to $90^{\circ}$ degree. The low density of Cr thin films is resulted from the isolated columnar structure of samples. The evolution of the isolated columnar structure was enhanced at the conditions of low sputter pressure and high glancing angle. This GLAD technique can be potentially applied to the synthesis of thin films requiring porous and uniform coating such as thin film catalysts or gas sensors.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.417-417
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• 2009

Although a transparent conductive film (TCF) belongs to essential supporting materials for many device applications such as touch screens, flat panel displays, and sensors, a conventional transparent conductive material, indium-tin oxide (ITO), suffers from considerable drawback because the price of indium has soared since 2001. Despite a recent falloff, a demand of ITO is expected to increase sharply in the future due to the trend of flat panel display technologies toward flexible, paper-like features. There have been recently extensive studies to replace ITO with new materials, in particular, carbon nanotubes (CNTs) since CNTs possess excellent properties such as flexibility, electrical conductivity, optical transparency, mechanical strength, etc., which are prerequisite to TCFs. This study fabricated TCFs with single-walled carbon nanotubes (SWCNTs) produced by arc discharge. The SWCNTs were dispersed in water with a surfactant of sodium dodecyl benzene sulfonate (NaDDBS) under sonication. Carbon black and fullerene nanoparticles were added to the SWCNT-dispersed solution to enhance contact resistance between CNTs. TCFs were manufactured by a filtration and transfer method. TCFs added with carbon black and fullerene nanoparticles were characterized by scanning electron microscopy (SEM), UV-vis spectroscopy (optical transmittance), and four-point probe measurement (sheet resistance).

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.201-202
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• 2009

ZnO:Al transparent conductive films for solar cells were deposited on the glass substrates at room temperature by facing target sputtering (FTS) method. The sputtering targets were 100 mm diameter disks of 2w.t..%. AZO and Zn metal. ZnO:Al thin films were deposited as a function film thickness. A base pressure was $2{\times}10^{-6}$torr, and a working pressure was 1mTorr. The properties of thin films on the structural, electrical and optical properties of the deposited films were investigated using a four-point probe (Chang-min), an X-ray diffraction (Rigaku), a Hall Effect measurement (Ecopia), an UV/VIS spectrometer (HP) and a $\alpha$-step (Tencor). The lowest resistivity of film was $5.67{\times}10^{-4}[{\Omega}-cm]$ at 500nm. The average transmittance of over 80% was seen in the visible range.