• Title/Summary/Keyword: fouling phenomena

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Determination of Microfiltration Membrane Fouling Characteristics by Liquid Displacement Method (액체전이법을 이용한 정밀여과막 오염의 특성 평가)

  • 장규만
    • Membrane Journal
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    • v.9 no.4
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    • pp.221-229
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    • 1999
  • The nominal pore size 0.2 ${\mu}m polytetrafluroethylene(PTFE, Satorius Co,) membrane was used for the filtration of 0.1 wt% kaolin, bentonite, yeast, and starch solution, respectively. After filtration, the membrane was cleaned and the pore size was measured by liquid displacement method(LDMl using water/iso-butanol system. The pore size for new PTFE membrane evaluated by LDM was comparable with those of which were measured by mercury porosimetry and scanning electron microscope. The membrane pores were severely fouled, and constricted to below 0.3 ${\mu}m in the cases of bentonite and starch solution which contained smaller particles than pores. However, in the case of kaolin - solution, only some parts of membrane pores above 0.35 ${\mu}m were slightly fouled. Hence, the phenomena of membrane fouling could be identified quantitatively by the evaluation of pore size using LDM.

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Characteristics of Permeation and Fouling of UF/MF Hollow Fiber Membranes for Drinking Water Treatment (정수처리 적용을 위한 UF/MF 중공사막의 투과성능과 오염현상)

  • 이주형;김정학;이용택
    • Membrane Journal
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    • v.10 no.2
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    • pp.75-82
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    • 2000
  • This study, which was tarried out to investigate the characteristics of permeation rates and fouling phenomena in drinking-water treating processes with MF membrane, showed that pressure drop was dependent on the length of membrane module and operating pressure; the pressure drop increased with the length of membrane module and operating pressure, operation at a relatively low pressure(0.5kg/$cm^2$) is better than that at a relatively (2.0kg/$cm^2$), since high operating pressure accelerates the clogging. In case of out-in permeation type, almost same flux was obtained after a certain operating time regardless of membrane length and operating pressure. In order to understand, the microbial fouling, chemical cleaning was carried out to the forced contaminated hollow-fiber membrane with chemicals($H_2O_2$, NaOCl, and NaOH). Chemical cleanings with $H_2O_2$and NaOCl, which are oxidizing agents, are better for sterilizing and desorbing the microbes than those with NaOH.

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Application of electro-coagulation for the pretreatment of membrane separation of anaerobic digestion effluents (혐기성 소화액의 막분리를 위한 전기응집 전처리 연구)

  • Kim, Shin-Young;Chang, In-Soung;Kim, Jang-Kyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4665-4674
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    • 2014
  • The aim of this study was to confirm the feasibility of the electro-coagulation process as a pre-treatment for the membrane separation of anaerobic digestion effluents to minimize membrane fouling. The reduction of membrane fouling was evaluated according to the number of electrodes (immersed surface area of electrodes), current density and contact time. In the case of the small surface area of electrodes, the increased electric field strength resulted in a soluble COD increase due to the destruction of the microbial flocs and/or cells, whereas large changes in the soluble COD were not observed in the case of the high surface area of electrodes. On the other hand, the T-P concentration decreased as a result of the precipitation of aluminum ions and phosphates. The membrane permeation flux increased and the fouling resistance (Rc+Rf) decreased with increasing electric current density. Although the particle size of the anaerobic digestion effluent increased slightly, it was not related directly to the reduced fouling phenomena. The main mechanism for the enhanced flux was attributed to the inorganic particulate produced during electrocoagulation, such as $AlPO_4$, which acted as a dynamic membrane deposited on the membrane surface.

Fouling Mitigation for Pressurized Membrane of Side-Stream MBR Process at Abnormal Operation Condition (가압식 분리막을 이용한 Side-Stream MBR 공정의 비정상 운전조건에서 막 오염 저감)

  • Ko, Byeong-Gon;Na, Ji-Hun;Nam, Duck-Hyun;Kang, Ki-Hoon;Lee, Chae-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.6
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    • pp.323-328
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    • 2016
  • Pressurized membrane used for side-stream MBR process requires fouling control strategy both for normal and abnormal operation conditions for stable operation of the facilities. In this study, $85m^3/day$ of pilot-scale side-stream MBR process was constructed for the evaluation of fouling mitigation by air bubble injection into the membrane module. In addition, fouling phenomena at abnormal operation conditions of low influent and/or loading rate were also investigated. Injection of air bubble was found to be effective in delaying transmembrane pressure (TMP) increase mainly due to scouring effect on the membrane surface, resulting in expanded filtration cycle at a high flux of $40L/m^2{\cdot}h$ (LMH). At abnormal operation condition, injection of PACl (53 mg/L as Al) into the bioreactor showed 19% reduction of TMP increase. However, inhibition of nitrifying bacteria by continuous PACl injection was observed from batch experiments. In contrast, injection of powdered activated carbon (PAC, 0.6 g/L) was able to maintain the initial TMP of $0.2kg/cm^2$ for 5 days at the abnormal conditions. It may have been caused from the adsorption of extracellular polymeric substances (EPS), which was known to be excessively released during growth inhibition condition and act as the major foulants in MBR operations.

A Study of CaSO4 Scale Formation and Heat Transfer in a Vertical Tube Evaporator (수직 증발관에서 CaSO4 Scale 형성과 열전달에 관한 연구)

  • Hong, Choonkeun;Choi, Mansoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.11
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    • pp.1363-1370
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    • 1999
  • A study of scaling and heat transfer has been carried out for a vertical tube evaporator in which $CaSO_4$ saturated water flows upward. Experimental apparatus including vacuum chambers and heaters has been designed and manufactured to study scaling phenomena for three different pressures(1atm, 0.27atm and 0.16atm). Overall heat transfer coefficients have been measured and shown to decrease with time as scaling proceeds. After the end of experiments, the vertical tube has been cut to measure the thickness of scale at different heights. Below the height where the bulk fluid temperature does not reach saturated temperature, the thickness of scale increases, however, beyond that height occurring saturated condition, the thickness does not vary much or even decreases a little. The measured fouling resistances also support these variations of scale thickness.

Electrokinetic Characterization of the Fouled PP Membrane in the Separation of Oily Wastes

  • Hyonseung Dho;Soojung Suh;Lee, Jae-won;Lee, Kune-woo
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.459-465
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    • 2001
  • The work was initiated to investigate the electrokinetic properties of a MF membrane using streaming potential measurement when oil emulsion was separated. The original and the surface modified PP membrane were examined by using flux and streaming potentials for the characterization of fouling phenomena of the PP membrane. The membrane surface was modified by a radiation grafting technique. The streaming potentials of the PP membranes were varied the charge distribution modifying by changing the pH, ionic strength, and concentrations the surfactants in oil emulsion. The shiftness to the more positive values of isoelectric point of the PP membrane was significant especially in the presence of surfactants or the surface modification.

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Effect of Water Back-flushing Condition in Hybrid Water Treatment Process of Carbon Fiber Microfiltration Membrane and Photocatalyst (탄소섬유 정밀여과막 및 광촉매 혼성 수처리 공정에서 물 역세척 조건의 영향)

  • Park, Jin Yong;Cho, Gwang Hee
    • Membrane Journal
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    • v.22 no.3
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    • pp.216-223
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    • 2012
  • The effect of water back-flushing period (FT) was investigated in hybrid process of carbon fiber microfiltration membrane and photocatalyst for advanced drinking water treatment in this study, and compared with the previous study using alumina ultrafiltration membrane. The FT was changed in the range of 2~10 min with fixed 10 sec of BT. Then, the FT effects on resistance of membrane fouling ($R_f$), permeate flux (J) and total permeate volume ($V_T$) were observed during total filtration time of 180 min. As decreasing FT, $R_f$ decreased and J increased, which was same with the previous result using alumina ultrafiltration membrane. The treatment efficiency of turbidity was high beyond 99.2%, and the effect of FT was not shown on treatment efficiency of turbidity, which was different with the previous result. The treatment efficiency of organic matters was the lowest value of 65.6% at NBF, and it increased as decreasing FT, which was different with the previous result, too. The reason was that the membrane fouling phenomena could show a different mechanism depending on ceramic membrane materials.

The Research for effect of lubricant oil aging on environmental performance (자동차 윤활유의 성상 및 열화가 환경성에 미치는 영향 연구)

  • Kim, Jeong-Hwan;Kim, Ki-Ho;Ha, Jong-Han;Jin, Dong-Young;Myung, Cha-Lee;Jang, Jin-Young
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.12-24
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    • 2017
  • The main purpose of this research is for the investigation on the impact of engine oil aging on PM and DPF. It is widely known that lubricant specifications and consumption from an ICE have significantly influenced on the regulated and unregulated harmful emissions as the engine operating conditions. Considering DPF clogging phenomena with lubricant-derived soot/ash components, simulated aging mode for the DPF was newly designed for engine dynamometer testing. PM/ash accumulation cycle were developed in reflecting real-world engine operating conditions for the increment of engine oil consumption and natural DPF regeneration for the ash accumulation. The test duration for DPF aging reached around 100hrs with high- and low-SAPS engine oils, respectively. Using high SAPs engine oil made more PM/ash accumulation compared with low SAPs engine oils and it could accelerate fouling of EGR in engine. Fouling of EGR made effects on more harmful exhaust gases emissions. The test results on engine lubricant under engines operating conditions will deliver for the establishment of regulated and unregulated toxic emissions policy, lubricant quality standard.

A Study on the Formation Mechanism of the Fly Ash from Coal Particles in the Coal Burning Boiler (석탄연소 보일러에서 생성된 석탄회의 분석과 형성 메커니즘 해석에 대한 연구)

  • Lee, Jung Eun;Lee, Jae Keun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.12
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    • pp.1691-1701
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    • 1998
  • Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A study on the formation mechanism of the fly ash from coal particles in the pulverized coal power plant is investigated with a physical, morphological, and chemical characteristic analysis of fly ash collected from the Samchonpo power plant. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, fouling phenomena and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution. Morphological characteristic of fly ash is performed using a scanning electron micrograph. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry(ICP). The distribution of fly ash size was bi-modal and ranged from 12 to $19{\mu}m$ in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, particle size and chemical components. The evolution of ash formation during pulverized coal combustion has revealed three major mechanisms by large particle formation due to break-up process, gas to particle conversion and growth by coagulation and agglomeration.

A SOFT-SENSING MODEL FOR FEEDWATER FLOW RATE USING FUZZY SUPPORT VECTOR REGRESSION

  • Na, Man-Gyun;Yang, Heon-Young;Lim, Dong-Hyuk
    • Nuclear Engineering and Technology
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    • v.40 no.1
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    • pp.69-76
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    • 2008
  • Most pressurized water reactors use Venturi flow meters to measure the feedwater flow rate. However, fouling phenomena, which allow corrosion products to accumulate and increase the differential pressure across the Venturi flow meter, can result in an overestimation of the flow rate. In this study, a soft-sensing model based on fuzzy support vector regression was developed to enable accurate on-line prediction of the feedwater flow rate. The available data was divided into two groups by fuzzy c means clustering in order to reduce the training time. The data for training the soft-sensing model was selected from each data group with the aid of a subtractive clustering scheme because informative data increases the learning effect. The proposed soft-sensing model was confirmed with the real plant data of Yonggwang Nuclear Power Plant Unit 3. The root mean square error and relative maximum error of the model were quite small. Hence, this model can be used to validate and monitor existing hardware feedwater flow meters.