• Title/Summary/Keyword: formation temperature

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Effects of Transition Temperature and Atomic Ratio on Glass Formation Tendency in the PbO-B$_2$O$_3$-TiO$_2$-BaO System (PbO-B$_2$O$_3$-TiO$_2$-BaO계의 유리화에 대한 전이온도 및 성분 원소비의 영향)

  • 이선우;심광보;오근호
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1274-1279
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    • 1998
  • The glass forming ability of the PbO-B2O3-TiO3-BaO system was investigated in relation to transitieon tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-peratures and the atomic ratio between constituents. Glass forming tendency was improved as the tem-perature differences between liquidus temperature and crystallization(or glass transition) temperature de-creased and the temperature difference between crystallization and glass transition temperature increases. The atomic ratio could be used as a criterion to deign glass systems. The interposition of B and Ba atoms between Pb and Ti atoms was one of important factors in glass formation.

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Pyrolysis Paths of Polybutadiene Depending on Pyrolysis Temperature

  • Choi Sung-Seen;Han Dong-Hun
    • Macromolecular Research
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    • v.14 no.3
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    • pp.354-358
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    • 2006
  • Polybutadiene (BR) was pyrolyzed at $540-860^{\circ}C$ and the effect of pyrolysis temperature on variations in the relative abundance of the major pyrolysis products (C4-, C5-, C6-, C7-, and C8-species) was investigated. Formation of the C4-, C5-, C6-, and C7-species competed with that of the C8-species. Relative intensity of the C8-species decreased with increasing pyrolysis temperature, while that of the C5-, C6-, and C7-species increased. Pyrolysis paths were became more complicated with increasing pyrolysis temperature. We suggested the operation of double bond migration and succeeding rearrangements for the formation of the C5- and C7-species and various rearrangements, including a double bond, for the formation of the C6-species at high temperature. The activation energies for the pyrolysis product ratios of(C5+C6+C7)/C4 and C8/C4 were used to explain the competition reactions to form the pyrolysis products.

A Study on the Characteristics of Soot Formation and Oxidation in Free Fuel Droplet Array

  • Lee, Myung-Jun;Kim, Jong-Youl;Yeom, Jeong-Kuk;Ha, Jong-Yul;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • v.16 no.6
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    • pp.851-860
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    • 2002
  • In this study, it was attempted to obtain the fundamental data for the formation and oxidation of soot from a diesel engine. Combustion of spray injected into a cylinder is complex phenomenon having physical and chemical processes, and these processes affect each other. There are many factors in the mechanism of the formation and oxidization of soot and it is necessary to observe spray combustion microscopically. In order to observe with that view, free fuel droplet array was used as an experimental object and the droplet array was injected into an atmospheric combustion chamber with high temperature. Ambient temperature of the combustion chamber, interdroplet spacing, and droplet diameter were selected as parameters, which affect the formation and oxidation of soot. In this study, it was found that the parameters also affect ignition delay of droplet. The ambient temperature especially affected the ignition delay of droplet as well as the flame temperature after self-ignition. As the interdroplet spacing that means the local equivalence ratio in a combustion chamber was narrow, formation of soot was increased. As diameter of droplet was large, surface area of the droplet was also broad, and hence evaporation of the droplet was more active than that of a droplet with relative small diameter.

The Effect of Environmental Parameters on Frost Formation on a Horizontal Cylinder (수평 실린더에서의 서리 생성에 대한 환경 변수들의 영향)

  • Lee, Yun-Bin;Ryu, In-Sang;No, Seung-Tak
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.2
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    • pp.253-260
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    • 2002
  • It is known that frost formation on surfaces of the heat exchanger seriously affects the performance of the refrigeration system. Accordingly, defrosting should follow, and effective defrosting is possible only when both analytic tools and comprehensive experimental data on frost formation are assailable. An experimental investigation was undertaken to characterize the effect of environmental parameters on frost formation on a horizontal cylinder in cross uniform flow. Several experiments were carried out with various environmental parameters such as inlet air temperature, inlet air humidity, air velocity and cooling surface temperature. Frost thickness, mass, surface temperature and cylinder inner and outer temperature were measured at front and rear positions of the cylinder. Thickness, mass, density, and effective thermal conductivity of the frost layer were obtained from measured data and effects of environmental parameters on the frost formation were analyzed. Data from experiments were correlated using dimensionless variables.

Low temperature deposition of carbon nanofilaments using vacuum-sublimated $Fe(CO)_5$ catalyst with thermal chemical vapor deposition

  • Kim, Nam-Seok;Kim, Kwang-Duk;Kim, Sung-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.1
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    • pp.18-22
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    • 2007
  • Carbon nanofilaments were deposited on silicon oxide substrate by thermal chemical vapor deposition method. We used $Fe(CO)_5$ as the catalyst for the carbon nanofilaments formation. Around $800^{\circ}C$ substrate temperature, the formation density of carbon nanofilaments could be enhanced by the vacuum sublimation technique of $Fe(CO)_5$, compared with the conventional spin coating technique. Finally, we could achieve the low temperature, as low as $350^{\circ}C$, formation of carbon nanofilaments using the sublimated Fe-complex nanograins with thermal chemical vapor deposition. Detailed morphologies and characteristics of the carbon nanofilaments were investigated. Based on these results, the role of the vacuum sublimation technique for the low temperature deposition of carbon nanofilaments was discussed.

Effects of Temperature and Ethylene Response Inhibitors on Growth and Flowering of Passion Fruit

  • Liu, Fang-Yin;Peng, Yung-Liang;Chang, Yu-Sen
    • Horticultural Science & Technology
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    • v.33 no.3
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    • pp.356-363
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    • 2015
  • This study examined the effects of different day/night temperature regimes or silver ion on growth and flowering of passion fruit 'Tai-nung No.1'. Low temperature treatment ($20/15^{\circ}C$) caused passion fruit cultivar 'Tai-nung No.1' to fail to flower. Flowering induction occurred within a temperature range of $20-30^{\circ}C$, with no significant difference in the days to first flower bud and the total number of flower buds between plants grown at $30/25^{\circ}C$ and $25/20^{\circ}C$. However, plants grown at $30/25^{\circ}C$ exhibited their first flower buds set on the higher nodes and had higher abortion rates of flower buds than those at $25/20^{\circ}C$. Plants grown at $30/25^{\circ}C$ had the most rapid growth and the shortest plastochron. We also evaluated the effect of the ethylene response inhibitors silver nitrate ($AgNO_3$) and silver thiosulfate (STS) on growth and flowering of potted passion fruit 'Tai-nung No.1', when they were exposed to low temperature conditions ($20/15^{\circ}C$) following chemical treatments ($AgNO_3$ or STS, at 0.5 or 1.0 mM). $AgNO_3$ and STS treatments induced flower formation and initial flower bud formation within approximately two weeks at $20/15^{\circ}C$ whereas non-treated control plants exhibited no flower formation. ACC content and activity of ACC oxidase in the leaves of passion fruit 'Tai-nung No.1'exposed to low temperature conditions ($20/15^{\circ}C$) were significantly inhibited by the ethylene inhibitor treatments. These results indicate that ethylene, which is produced under low temperature conditions, plays an important role in inhibiting flower formation in passion fruit.

A Study on Soot Formation of Turbulent Premixed Propane Flames in n Constant-Volume Combustor at High Temperatures and High Pressures (고온ㆍ고압 정적 연소기내 난류 프로판 예혼합 화염의 매연생성에 관한 연구)

  • 배명환
    • Transactions of the Korean Society of Automotive Engineers
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    • v.9 no.4
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    • pp.1-9
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    • 2001
  • The soot yield has been studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effects of pressure, temperature and turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. The pressure and temperature during soot formation are changed by varying the initial charge pressure and the volume fraction of inert gas compositions, respectively. It is found that the soot yield increases with dropping temperature and rising pressure at constant equivalence ratio, and that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

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Immobilization of Metal lons Using Low-Temperature Calcination Techniques of Spinel-ferrites

  • Yen, Fu-Su;Kao, Hsiao-Chiun;Chen, Wei-Chien
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.106-110
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    • 2001
  • Formation of stoichiometric lithium-, nickel-, and zinc- ferrites by calcining organo-metallic precursors a temperature below 40$0^{\circ}C$ is examined using DTA/TG, and XRD techniques. It attempts to simulate th immobilization of metal ions in industrial liquid influents (waste) through the synthesis of stoichiometric spinel ferrites (SSF). Two steps of the SSF formation during thermal treatments are noted. The transformation of magnetite to ${\gamma}$ - Fe$_2$O$_3$and subsequent first formation of SSF were observed at temperatures ranging from 200 to 45$0^{\circ}C$. Th formation of cation-containing ${\gamma}$-Fe$_2$O$_3$and subsequent second formation of the ferrite occurred at temperature ranges of < 45$0^{\circ}C$ and 500 to $650^{\circ}C$, depending on the heating rate used. Then the temperature range of 200t 45$0^{\circ}C$ is critical to the performance of the technique, because a calcination at the range would lead to a complete formation of SSF, avoiding the occurrences of ${\gamma}$-Fe$_2$O$_3$and ion-containing ${\gamma}$-Fe$_2$O$_3$. If not, so $\alpha$-Fe$_2$O$_3$would occur. And annealing at temperature above $650^{\circ}C$ must be employed by which solid-state reactio of $\alpha$-Fe$_2$O$_3$with metal ions (possibly metal oxides) to form SSF can be conducted.

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Formation of Crystalline Copper Thin Films by a Sputtering-assisted Magnetic Field System at Room Temperature

  • Kim, Hyun Sung
    • Applied Science and Convergence Technology
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    • v.27 no.1
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    • pp.1-4
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    • 2018
  • A sputtering-assisted magnetic field system was successfully developed for depositing crystalline Cu thin films at room temperature. This system employs a plasma source and an ion-beam gun with two magnetic field generators, which is covered with sputtering target and the ion-beam gun, simultaneously serving as sputtering plasma and a magnetic field generator. The formation of crystalline Cu thin films at room temperature was dominated by magnetic fields, which was revealed by preliminary experiments. This system can be employed for producing crystalline metal thin films at room temperature.

Critical review of pseudo-gap in high Tc superconductors : Experiments and theories

  • Choi, Han-Yong
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.8-8
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    • 2000
  • Recently the study of the pseudo-gap in high temperature superconductivity become critical issue because it contains key information of the pair formation of the high temperature superconductivity. Specially angle resolved photoemission study shows the various information of the gap formation. In this talk, I will review the recent theories as will as experiments on the pseudo-gap in high temperature superconductors. Specially I will introduce the possible observation of the Andreeve reflection in the underdopped high temperature superconductors.

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