• Title/Summary/Keyword: formaldehyde release

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Development of New Fibers Related Sensitivity and comfortability -Preparation of Melamine Microcapsules Containing Fragrant oil and the Their Application- (감성기능 섬유신소재의 개발(I) - 방향성 멜라민 마이크로캡슐의 제조와 응용 -)

  • Hong, Ki Jeong;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.8 no.5
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    • pp.76-83
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    • 1996
  • Fragrant microcapsules were prepared by in situ polymerization using urea-formaldehyde prepolymer. Lemon oil and migrin oil as susceptible materials were used. The diameter and distribution of the microcapsule were controlled by several factors, such as wall material, core material content, emulsion agent and stirring speed, respectively. Susceptible cotton fabrics with fragrant release functionality were successfully produced by using microcapsule containing fragrant materials.

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Comparative Study on the Control and Removal of Formaldehyde for the Urea-formaldehyde Resin Bonded Plywood -Adhesive control- (요소수지접착합판(尿素樹脂接着合板)의 유리(遊離)포름알데히드 방산(放散)제거 및 조절방법에 대한 비교연구(比較硏究))

  • Lee, Hwa-Hyoung
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.3
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    • pp.16-23
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    • 1981
  • This study has been carried out to make a comparative study for the adhesive control methods specifically developed for application to formaldehyde. The method for formaldehyde determination used in this report is the improved chromo tropic acid determination. The results are summarized as follows: 1. The soaking treatment in aqueous solution of urea wok the most scavenging effect on the formaldehyde release from a plywood sample glued with a urea formaldehyde adhesive, and other removal treatment such as resorcinol, albumine-, and hardener-treatment gave significant reduction too. 2. In glue shear strength of dry test, 2% of resorcinol treatment and soaking treatment showed the highest strength and all the other treatment met the standard, but in hot water soaking test, 2% of resorcinol treatment gave the best results, on the other hand, adding the hardener showed the lowest strength and failed in meeting the standard. 3. Air dried moisture content of all treated plywood met the standard which calls for 13% or bellow. 4. In this comparative study, we can make a strong combination each other or go into the details of one treatment for the best result through the more study.

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Preparation and Characterization of Functional Microcapsules Containing Suspensions of Conducting Materials (전도성 물질 서스펜션을 함유한 마이크로캡슐)

  • Ihm, DaeWoo;Kwon, Won Ho
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.40-46
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    • 2015
  • Microcapsules containing the suspension of conducting materials such as carbon nanotube (CNT) or polyaniline (PANI) were prepared by in-situ polymerization of melamine and formaldehyde. Stable microcapsules were prepared and the mean diameter of the observed microcapsules was in the range of $10-20{\mu}m$. The surface morphology and chemical structure of microcapsules were investigated using optical microscope (OM), scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). The thermal properties of samples were investigated by thermogravimetric analysis (TGA). The conductivity of ruptured microcapsule containing the suspension of CNTs or PANIs in tetrachloroethylene and Isopar-G was measured. As the amount of CNTs and PANIs in the core of microcapsules increased, the measured current increased. Conductivity measurement results suggest that poly (melamine-formaldehyde) based core-shell microcapsules could be applied to self-healing electronic materials systems, where CNTs or PANIs bridge a broken circuit upon release.

Emission Characteristics of Carbonyl Compounds from Major Industrial Sectors in the Ban-Wall Industrial Complex, Korea (카보닐 계열의 배출 특성과 그에 따른 악취 발생 기여도 비교 연구: 반월공단내 주요 산업시설물들을 중심으로)

  • Hong, Y.J.;Jeon, E.C.;Kim, K.H.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.679-692
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    • 2006
  • The carbonyl compounds in the atmosphere belong to one of the regulatory pollutants for the malodor control designated by the Korean Ministry of Environment(KMOE). In the present study, the emission concentration levels of carbonyl compounds were measured along with a number of criteria odor pollutants from a total of 47 individual companies(June 2004 to January 2005). The results of our study showed that a number of carbonyl compounds(such as formaldehyde, acetaldehyde, acetone, and butyraldehyde) maintained significantly high mean concentrations of 298 to 372 ppb. In contrast, other carbonyl compounds were low enough with the mean valves of 0.54 to 19.1 ppb. It was found that except for such industries as metal production or leather processing, their emissions were generally quite significant. If the measured values were evaluated in terms of malodor intensity, butyraldehyde appeared to be the most significant contributor to the malodor release. According to the measurements made in strong source areas, it can be concluded that several carbonyl compounds(acetaldehyde, propionaldehyde, butyraldehyde, isovaleraldehyde, and valeraldehyde) are useful enough to diagnose malodor release from those source areas. It should also be addressed that a number of carbonyl compounds added newly as the result of malodor control legislation were not sensitive enough to diagnose malodor release from such sources.

Development of Susceptible Functional Fibers Using Microencapsulation of Susceptible Materials(III) ―Fragrant Functional Fibers― (감성물질의 마이크로캡슐화에 의한 감성기능 섬유의 개발(III) -방향 기능 섬유-)

  • Kim, Moon Sik;Park, Soo Min
    • Textile Coloration and Finishing
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    • v.8 no.4
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    • pp.11-18
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    • 1996
  • Natural functional compound in the textile finishing for health and amenity using fragrant material have been applied by microencapsulation method. The microcapsules containing fragrant materials as functional compound were produced by in situ polymerization using urea-formaldehyde prepolymer. The average diameter of microcapsules is 2.75$\mu$ and particle size ranges over 0.5~10$\mu$. Fragment material is extracted approximatly proportioned from microcapsule at room temperature. The adsorption of microcapsule was improved by pretreatment of cationic agent. Fragrant materials in microcapsule was revealed to have long release time.

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Strength properties of magnesium oxide matrix according to type of phosphate (인산염 종류에 따른 산화마그네슘 경화체의 강도 특성)

  • Lim, Jeong-Jun;Pyeon, Su-Jeong;Kim, Dae-Yeon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.79-80
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    • 2018
  • Recently, the interest in remodeling of new and old buildings is increasing worldwide. As a result, the frequency of use of architectural adhesives has increased. Currently, adhesives used in buildings are made of organic materials in most cases, and epoxy resin adhesives are most widely used. However, epoxy resin adhesives contain formaldehyde and VOCs in the room during construction, which can cause sick house syndrome. In case of building fire, it may cause damage due to carbon monoxide generated from organic materials. It is urgent to study the problem of epoxy fill adhesive made of such organic materials. Therefore, the purpose of this study is to investigate the effect of the adhesion of epoxy resin adhesive, which is a problem of epoxy resin adhesive, which is an existing organic adhesive by using inorganic materials such as magnesia and phosphate, And the inorganic adhesive which does not emit the release amount as an inorganic material.

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Development of Slow-Release Compound Fertilizer Used Urea-Resin for Upland Crop I. Manufacture of Slow-Release Compound Fertilizer (요소수지(尿素樹脂)를 이용(利用)한 전작용(田作用) 완효성(緩效性) 복비(複肥) 개발(開發) I. 제조시험(製造試驗))

  • Seong, Ki-Seog;Kim, Bok-Jin;Shin, Jae-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.3
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    • pp.193-198
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    • 1990
  • In order to develop the slow-release compound fertilizer fur upland crops, trial products were made with ammonium sulfate, diammonium phosphate, and potassium chloride with filler of calcium sulfate, and hinder of additional material of urea resin Nine trial slow-release compound fertilizers were manufactured by varying urea/formaldehyde mole ratios(U/F mole ratio : 0.5, 1.0, and 1.5 ) and the proportions of urea resin (3.3. 6.7. and 10%) and the proportions of urea resin (3.3. 6.7 and 10%). The aimed percentage of $N-P_2O_5-K_2O$ in the trial product was 12.5-10.0-14.0%, which was appropriate for Chinese cabbage. The N dissolution of the trial products in water was slower with lower U/F ratio and in creased to the proportion of urea resin. The dissolved nitrogen in water after 24hrs ranged from 69 to 83 percent of total nitrogen in the trial products.

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Preparation and Drug-releasing Properties of Chitosan-based Thermosensitive Composite Hydrogel

  • Li, Heping;Yu, Tao;Li, Shan;Qin, Long;Ning, Jingheng
    • Journal of the Korean Chemical Society
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    • v.56 no.4
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    • pp.473-477
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    • 2012
  • The novel chitosan-based thermosensitive hydrogels were prepared as control-releasing drug carriers. N-carboxyethyl chitosan (ACS) was synthesized by microwave heating for 1 h through Michael addition of CS to acrylic acid in a grafting yield of 52.97%, which was proved to be a faster and more efficient way than ordinary methods. 5-Fu was modified with formaldehyde to synthesize N,N'-Bis(hydroxymethyl)-5-fluorouracil (5-Fu-OH). Then an esterification was performed using ACS and 5-Fu-OH to give 5-Fu-ACS. The new thermosensitive hydrogels were prepared by adding sodium glycerophosphate to the solution of compounds under a certain constant temperature. Simultaneously, the hydrogels' swelling rate, in vitro drug release rate and thermosensitive were studied, and found that the 5-Fu-ACS composite hydrogel had more excellent releasing effect, higher drug loading and better thermosensitive.

Strength enhancement of concrete incorporating alccofine and SNF based admixture

  • Reddy, Panga Narasimha;Jindal, Bharat Bhushan;Kavyateja, Bode Venkata;Reddy, A. Narender
    • Advances in concrete construction
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    • v.9 no.4
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    • pp.345-354
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    • 2020
  • Cement is the most significant component in concrete. Large scale manufacturing of cement consumes more energy and release harmful products (Carbon dioxide) into the atmosphere that adversely affect the environment and depletes the natural resources. A lot of research is going on in globally concentrating on the recycling and reuse of waste materials from many industries. A major share of research is focused on finding cementitious materials alternatives to ordinary Portland cement. Many industrial waste by-products such as quartz powder, metakaolin, ground granulated blast furnace slag, silica fume, and fly ash etc. are under investigations for replacement of cement in concrete to minimize greenhouse gases and improve the sustainable construction. In current research, the effects of a new generation, ultra-fine material i.e., alccofine which is obtained from ground granulated blast furnace slag are studied as partial replacement by 25% and with varying amounts of sulfonated naphthalene formaldehyde (i.e., 0.3%, 0.35% and 0.40%) on mechanical, water absorption, thermal and microstructural properties of concrete. The results showed moderate improvement in all concrete properties. Addition of SNF with combination of alccofine showed a significant enhancement in fresh, hardened properties and water absorption test as well as thermal and microstructural properties of concrete.

A Study on the Physical Properties and Environment Efficiency Evaluation in Activated Carbon Concrete Bricks (활성탄을 첨가한 콘크리트벽돌의 물리적 특성 및 환경 성능 평가에 관한 연구)

  • Woo, Jong-Kwon;Hong, Sang-Hee;Jun, Kyoung-Bin;Ryu, Hyun-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.47-51
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    • 2006
  • Modern residing equipment developed much quantitatively along with economic growth but improvement for agreeable residing space of indoor environment is insufficient situation yet. Also, the latest sick-building syndrome discharging room contaminant such as Formaldehyde, toluene, radon etc. built house or buildings newly human body threaten. Radon of them is real condition that raise origination of lung cancer next to smoke. So, wish to in this research by one of solution way of these problems adsorption performance and specie performance excellent activated carbon to concrete bricks for deconstipating suppository that is room finish fare mix and examine closely after grasp physical, mechanical special quality, hazardous substance and specie performance effect. According to result that estimate environment efficiency evaluation, the $CO_2$ absorption amount displayed decrease effect more than about 90% in activated carbon metathesis rate 40% and radon release amount displayed tendency that decrease about $76{\sim}96%$ in activated carbon metathesis rate 40%.

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