This study was carried out to classify vegetation structure of the southern and northern slopes in the Deogyusan National Park using TWINSPAN classification and DCCA ordination analysis. The vegetation on the southern slope was classified into Quercus mongolica community, Q. serrata community, Q. variabillis community, Pinus densiflora community, Carpinus laxiflora community, Cornus controversa community and Fraxinus mandshurica community. The vegetation on the northern slope was classified into Q. mongolica community, Q. serrata community, P. densiflora community, C. laxiflora community, Betula davurica community, C. controversa community, F. mandshurica community, B. costata community, Abies koreana community and Taxus cuspidata community. To find out important value in each slope, we took 103 districts on the southern slope and 137 districts on the northern slope. As the result, Q. mongolica was highest value in the southern and northern slopes, followed by P. densiflora, Q. serrata, Q. variabillis, Styrax obassia, Acer pseudosieboldianum in the southern slope, F. mandshurica, A. pseudosieboldianum, Q. serrata, C. laxiflora, C. controversa, C. cordata, Rhododendron schlippenbachii in the northern slope. Species distribution and ecological features had differences between the southern and northern slopes communities. As the result of DCCA ordination analysis, sea level and water availability had high correlation with community distribution. Besides, T-N, O.M., exchangeable Ca and pH did in the southern slope. And exchangeable Ca, pH also did in the northern slope.