• Korean Chemical Engineering Research
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• v.53 no.2
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• pp.253-261
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• 2015

The kinetics of the transesterification of dimethyl terephthalate (DMT) with diethylene glycol (DEG) was studied in a batch reactor. bis-hydroxyethoxytethyl-terephthalate (BHEET), which is polyester polyol monomer, can be produced by the transesterification reaction. Zinc acetate was used as a catalyst. Previous kinetic studies was carried out in a semi-batch reactor where generated methanol was removed so that reverse reactions were not considered in the kinetic expressions, resulting in inaccuracy of the kinetic model. Mathematical models of a batch reactor for the tranesterification reaction, which took the reverse reaction into account, were developed and used to characterize the reaction kinetics and the composition distribution of the reaction products. More accurate models than previous ones were obtained and found to have a good agreement between model predictions and experimental data. Effect of process variables on the esterification reaction was investigated based on the experimental and simulation results.

• Fire Science and Engineering
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• v.33 no.4
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• pp.1-8
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• 2019

Reaction-to-fire performance of pipe insulation materials should be approved in accordance with KS standards prior to installing water-based suppression systems because several fire accidents are initiated from insulation materials around ceilings or concealed space. A small room test to evaluate the reaction-to-fire performance of the polyethylene foam and elastomeric pipe insulation materials was conducted according to ISO 20632. Different fire growth rate and heat release rate are observed depending on the materials and construction methods. In order to improve a fire safety, the reaction-to-fire performance of pipe insulation material needs to be subdivided with regard to the heat release rate and smoke generation. Furthermore, the characteristics of the applying space are also required to be considered. Subsidiary materials for installation process such as tape and adhesive are found to provide an adverse effect to maintain a fire safety.

• Journal of Microbiology and Biotechnology
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• v.21 no.9
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• pp.960-967
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• 2011

Tannin acyl hydrolase, also known as tannase, is an enzyme with important applications in the food, feed, pharmaceutical, and chemical industries. However, despite a growing interest in the catalytic properties of tannase, its practical use is very limited owing to high production costs. Several studies have already demonstrated the advantages of solid-state fermentation (SSF) for the production of fungal tannase, yet the optimal conditions for enzyme production strongly depend on the microbial strain utilized. Therefore, the aim of this study was to improve the tannase production by a locally isolated A. niger strain in an SSF system. The SSF was carried out in packed-bed bioreactors using polyurethane foam as an inert support impregnated with defined culture media. The process parameters influencing the enzyme production were identified using a Plackett-Burman design, where the substrate concentration, initial pH, and incubation temperature were determined as the most significant. These parameters were then further optimized using a Box-Behnken design. The maximum tannase production was obtained with a high tannic acid concentration (50 g/l), relatively low incubation temperature ($30^{\circ}C$), and unique low initial pH (4.0). The statistical strategy aided in increasing the enzyme activity nearly 1.97-fold, from 4,030 to 7,955 U/l. Consequently, these findings can lead to the development of a fermentation system that is able to produce large amounts of tannase in economical, compact, and scalable reactors.

• Journal of the Society of Naval Architects of Korea
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• v.55 no.5
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• pp.448-455
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• 2018

Glass wool is an eco-friendly materials that is manufactured through a continuous process by processing waste glass. This materials is low cost compared with another materials and has excellent thermal conductivity. For this reason, glass wool is installed as insulation system for LNG carriers and as insulation of building wall as well as various industries. The mechanism of insulation of glass wool is the conduction of the wool itself and convection by space between fibers. Therefore, in order to develop the enhanced thermal conductivity of glass wool is necessary to reduce its own conduction or to insert additional material after manufacturing as well as prevent convection. In this respect, many researchers have been actively studying to decrease thermal conductivity of polyurethane foam using by inserted glass wool or change the chemical component of glass wool. However, many research are aiming reduction of glass wool itself. This study focus on post-processing and inserted different materials; silica-aerogel, kevlar fiber 1mm, 6mm and glass bubble. Experimental results show that the thermal conductivity almost decreases with the addiction of glass bubble and silica aerogel.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.31 no.4
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• pp.209-220
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• 2019

Even though the scale of hard structures for beach stabilization should carefully be determined such that these structures do not interrupt the great yearly circulation process of beach sediment in which the self-healing ability of natural beach takes places, massive hard structures such as the submerged breakwater of wide-width are frequently deployed as the beach stabilization measures. On this rationale, asymmetric ripple mat by Irie et al. (1994) can be the alternatives for beach stabilization due to its small scale to replace the preferred submerged breaker of wide-width. The effectiveness of asymmetric ripple mat is determined by how effectively the vortices enforced at the contraction part of flow area over the mat traps the sediment moving toward the offshore by the run-down. In order to verify this hypothesis, we carry out the numerical simulations based on the Navier-Stokes equation and the physically-based morphology model. Numerical results show that the asymmetric ripple mat effectively capture the sediment by forced vortex enforced at the apex of asymmetric ripple mat, and bring these trapped sediments back to the beach, which has been regarded to be the driving mechanism of beach stabilization effect of asymmetric ripple mat.

• Journal of Convergence for Information Technology
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• v.11 no.5
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• pp.206-214
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• 2021

The aim of this study was to investigate the effect of face wash with ginseng cold process (CP) soap. In order to remove external environmental factors, skin changes were examined immediately after 10 minutes of face wash. The same water and towel were used at the same place. As a control group, the cases of washing with water without using cleanser and with foam cleanser (F/C), which is a popular commercial product, were set. In the case of water washing, there was a significant decrease in pores and pigmentation, but the significance was small. In the case of F/C washing, there was a very significant decrease in pores and pigmentation, but the loss of moisture was rapid. In the case of ginseng cp soap, pores and pigmentation were significantly reduced, while moisture loss was negligible. Ginseng cp soap is considered as a form of face wash that is suitable for skin care.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.27 no.2
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• pp.55-62
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• 2021

This study aims to reduce the rancid odor generated during the fermentation process of kimchi by inserting zinc oxide (ZnO) into an inorganic porous material with a high surface area to decompose or adsorb the fermentation odor. ZnO activated by the presence of moisture exhibits decomposition of rancid odors. Mixed with Titanium dioxide (TiO₂), a photocatalyst. To manufacture the packaging liner used in this study, NaOH, ZnCl₂, and TiO₂ powder were placed in a tank with diatomite and water. The sludge obtained via a hydrothermal ultrasonication synthesis was sintered in an oven. After being pin-milled and melt-blended, the powders were mixed with linear low-density polyethylene (L-LDPE) to make a masterbatch (M/B), which was further used to manufacture liners. A gas detector (GasTiger 2000) was used to investigate the total amount of sulfur compounds during fermentation and determine the reduction rate of the odor-causing compounds. The packaging liner cross-section and surface were investigated using a scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDS) to observe the adsorption of sulfur compounds. A variety of sulfur compounds associated with the perceived unpleasant odor of kimchi were analyzed using gas chromatography-mass spectrometry (GC-MS). For the analyses, kimchi was homogenized at room temperature and divided into several sample dishes. The performance of the liner was evaluated by comparing the total area of the GC-MS signals of major off-flavor sulfur compounds during the five days of fermentation at 20℃. As a result, Nano-grade inorganic compound liners reduced the sulfur content by 67 % on average, compared to ordinary polyethylene (PE) foam liners. Afterwards SEM-EDS was used to analyze the sulfur content adsorbed by the liners. The findings of this study strongly suggest that decomposition and adsorption of the odor-generating compounds occur more effectively in the newly-developed inorganic nanocomposite liners.

• Journal of the Korea Institute of Construction Safety
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• v.5 no.1
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• pp.9-16
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• 2023

Gang-foam is used in many construction projects because it is not only precise in terms of vertical, horizontal, and specifications, but also easy to install and dismantle. However, major accidents occur every year due to non-compliance with safety rules and work order, also manuals and checklists currently in use are insufficient. Thirty-seven surveys was conducted by analyzing major accident cases of domestic gang-form construction project and deriving 20 risk factors and 43 check points. Based on the survey, the importance and appropriateness of check points were evaluated. As a result of this study, a checklist was presented, check points were placed in the order of importance based on assembly, installation, dismantling, and lifting of the Gang-form process. The checklist was organized so that workers could comply with safety rules and work order. Through this, it is expected to prevent major accidents and contribute to efficient safety management.

• International conference on construction engineering and project management
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• 2017.10a
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• pp.89-98
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• 2017

The floor heating method generally uses a wet construction method including the installation of resilient material, lightweight foam concrete, heating piping, and finishing mortar. Such a wet construction method not only delays other internal finishing processes during curing period for two mortar pouring process, but also has a disadvantage that it is difficult to replace the floor heating layer when it deteriorated because it is integrated with the frame. Dry floor heating construction method can be a good alternative in that it can solve these defects. Conversely, when it applied to the wall structure that is vulnerable to the interlayer noise compared with the column-beam structure, the question about the heavy-impact sound(HIS) insulation performance is raised. Therefore, conventional dry floor heating method is hard to apply to the wall structure apartments. Therefore, for the purpose to improve the applicability of dry floor heating method in wall structure apartments, this study investigated the change of floor impact sound, especially HIS insulation performance which is one of the required performance for the floor structure. This study tried to examine whether the change of heavy-impact sound pressure level(SPL) shows a tendency at the significant level according to the shape and mass of the floor structure. Through filed experiments on wall structure apartment, this study confirmed that the form of the raised floor shows better HIS insulation performance than the fully-supported form. In addition, it was also confirmed that the HIS insulation performance increases with the mass on the upper part. Moreover, this study found the fact that a mass of about 30 kg/m² or more should be placed on the upper structure to reduce the heavy-impact SPL according to the bang machine measuring method. Although this study has a limit due to insufficient experiment samples, if the accuracy of this study is increased, it will contribute to the diffusion of dry floor heating by setting the HIS insulation performance target and designing the dry floor heating structure that meets the target.

• Journal of the Korean institute of surface engineering
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• v.56 no.5
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• pp.299-308
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• 2023

In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo₂O₄) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo₂O₄ and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo₂O₄ electrode exhibited a specific capacitance of 1,129 Fg^-1 at a current density of 1 Ag^-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg^-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo₂O₄ electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.